• 제목/요약/키워드: ozonization

검색결과 17건 처리시간 0.022초

Ozonization of SWCNTs on thermal/mechanical properties of basalt fiber-reinforced composites

  • Kim, Seong Hwang;Heo, Young-Jung;Park, Soo-Jin
    • Steel and Composite Structures
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    • 제31권5호
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    • pp.517-527
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    • 2019
  • To move forward in large steps rather than in small increments, the community would benefit from a systematic and comprehensive database of multi-scale composites and measured properties, driven by comprehensive studies with a full range of types of fiber-reinforced polymers. The multi-scale hierarchy is a promising chemical approach that provides superior performance in synergistically integrated microstructured fibers and nanostructured materials in composite applications. Achieving high-efficiency thermal conductivity and mechanical properties with a simple surface treatment on single-walled carbon nanotubes (SWCNTs) is important for multi-scale composites. The main purpose of the project is to introduce ozone-treated SWCNTs between an epoxy matrix and basalt fibers to improve mechanical properties and thermal conductivity by enhancing dispersion and interfacial adhesion. The obvious advantage of this approach is that it is much more effective than the conventional approach at improving the thermal conductivity and mechanical properties of materials under an equivalent load, and shows particularly significant improvement for high loads. Such an effort could accelerate the conversion of multi-scale composites into high performance materials and provide more rational guidance and fundamental understanding towards realizing the theoretical limits of thermal and mechanical properties.

섬유상활성탄소를 이용한 Humic Acid 공존시 페놀의 흡착특성에 관한 연구 (A Study on the Adsorption Characteristics of Phenol in the presence of Humic Acid Using Activated Carbon Fiber)

  • 탁성제;서성원;김성순;김진만
    • 상하수도학회지
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    • 제14권1호
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    • pp.54-61
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    • 2000
  • Recently, our circumstances are threatened by an accident that leakage of under ground storage tank and illegal dumping of synthetic organic compounds at chemical plants and many treatment methods, Activated carbon adsorption, Ozonization, Membrane filtration and Photocatalystic oxidation, are developed to remove such a synthetic organic compounds. And it has reported that Activated carbon adsorption have a great removal efficiency to nondegradable matters and organic compounds which have a high molecular weight. Comparing with other adsorbents, Activated carbon adsorption have a worse efficiency when ad desorption speed is low. Thus improved type of adsorbents was invented and one of those is Activated Carbon Filter. The purpose of this study was getting information about adsorption characteristic phenol which can be applied Activated Carbon Fiber and Granular Activated Carbon. In detail, With comparing removal characteristics of phenol in the presence Humic Acid using Activated Carbon Fiber(ACF) and Granular Activated. Carbon(GAC), it is to certify an effective application of Activated Carbon Fiber. At the range of this study, Batch test, Isotherm adsorption test and Factorial analysis, following conclusion were obtained from the results of this study. Batch test was carried to know time of adsorption equilibrium. In this study about time of adsorption equilibrium by ACF was faster than GAC's, for developed micropore of ACF. From the result of phenol adsorption test, High removal rate of adsorption is shown at pH 5. The result of lsotherm adsorption test, it has represented that the Freundlich's isotherm is most suitable one in others, that a ACF's adsorption capacity is more excellent than GAC's. Adsorption of phenol exiting humic acid is decreased getting raised humic acid concentration. Since ACF's micropore is developed at this time, an effect of high molecular humic acid is lower. Factorial analysis was carried to know about Main effect which was injection dosage of adsorbent in the range of this study.

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치즈 숙성 중의 곰팡이 오염 방제 - 현황과 전망 (Prevention of Fungal Contamination during Cheese Ripening - Current Situation and Future Prospects)

  • 정후길;최하늘;오현희;허창기;양희선;오전희;박종혁;최희영;김경희;이승구
    • Journal of Dairy Science and Biotechnology
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    • 제30권2호
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    • pp.75-81
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    • 2012
  • Molds cause severe cheese deterioration, even though some white and blue molds are used for the manufacture of Camembert and Blue cheese, respectively. The species of Geotrichum, Moniliella, Aspergillus, Penicillium, Mucor, Fusarium, Phoma, and Cladosporium are the main fungi that affect contamination during cheese ripening. Once deteriorated by fungal spoilage, cheese becomes toxic and inedible. Fungal deterioration of cheese decreases the nutritional value, flavor profiles, physicochemical and organoleptic properties, and increases toxicity and infectious disease. Fungal contamination during cheese ripening is highly damaging to cheese production in Korean farmstead milk processing companies. Therefore, these companies hesitate to develop natural and ripened cheese varieties. This article discusses the recent and ongoing developments in the removal techniques of fungal contamination during cheese ripening. There are 2 categories of antifungal agents: chemical and natural. Major chemical agents are preservatives (propionic acid, sodium propionate, and calcium propionate) and ethanol. Among the natural agents, grapefruit seed extract, phytoncide, essential oils, and garlic have been investigated as natural antifungal agents. Additionally, some studies have shown that antibiotics such as natamycin and Delvocid$^{(R)}$, have antifungal activities for cheese contaminated with fungi. Microbial resources such as probiotic lactic acid bacteria, Propionibacterium, lactic acid bacteria from Kimchi, and bacteriocin are well known as antifungal agents. In addition, ozonization treatment has been reported to inhibit the growth activity of cheese-contaminating fungi.

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오존처리에 따른 탄소나노튜브 강화 고밀도 폴리에틸렌 기지 복합재료의 PTC/NTC 특성 (Effect of Ozone Treatment of Carbon Nanotube on PTC/NTC Behaviors of High-Density Polyethylene Matrix Composites)

  • 박수진;석수자;이재락;홍성권
    • 폴리머
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    • 제29권1호
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    • pp.32-35
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    • 2005
  • 탄소나노튜브를 오존처리한 후 이를 사용하여 탄소나노튜브/고밀도 폴리에틸렌 전도성 복합재료를 제조하였고, 오존처리된 탄산나노튜브가 positive temperature coefficient(PTC) 세기에 미치는 영향을 조사하였다. 원소분석(EA)과 FT-IR 분석 결과, 오존처리된 탄소나노튜브의 표면에는 O-H, C=O 그리고 C-O와 같은 산소함유 관능기가 증가하는 것을 확인할 수 있었다. 또한, 전도성 복합재료의 온도에 따른 저항성은 디지털 멀티메타를 이용하여 측정하였다. 복합재료의 저항성은 고밀도 폴리에틸렌의 결정 용융 온도에서 증가하였으며, 이는 복합재료의 매트릭스로 사용된 고밀도 폴리에틸렌의 열팽창성에 의한 전도성 네트워크의 파괴때문인 것으로 판단된다. 그리고 탄소나노튜브에 오존처리 시간이 증가할수록 탄소나노튜브/고밀도 폴리에틸렌 복합재료의 PTC 세기는 증가했고, 이는 오존처리에 의한 탄소나노튜브 표면에 산소함유 관능기는 PTC 소자의 최대 비저항 값을 증가시키기 때문인 것으로 판단된다.

기존 정수장 이산화염소 시범도입 사례연구 (A Case Study on Chlorine Dioxide Usage at a Conventional Water Treatment Plant)

  • 이송희;이병두;김진근;석관수;이정택
    • 대한환경공학회지
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    • 제27권1호
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    • pp.115-119
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    • 2005
  • 소독부산물에 대한 수질기준이 강화됨에 따라 외국은 물론 국내 정수장에서도 강화응집(Enhanced Coagulation), 대체소독제 사용과 오존/활성탄 등의 고도정수처리공정 등을 도입하여 운영중이거나 도입을 계획하고 있다. 국내에서는 1991년도 낙동강페놀오염사고 전후로 26개 정수장에 이산화염소 발생기가 설치되었으나 실공정에서 축적된 운영자료는 거의 없는 실정이다. 본 연구는 홍수기 특정시기에만 소독부산물이 높게 검출되는 A정수장에 이산화염소 발생기를 설치하여 1년간 운영자료를 토대로 수질개선효과 운영관리상의 문제점과 향후 기존 정수장에서 이산화염소 공정도입시 고려하여야 할 내용을 정리하였다. 이산화염소에 의하 소독부산물 저감효과는 전체공정에서 $30{\sim}40%$ 정도였으나, 2-MIB, Geosmin의 제거율은 10% 이내였다. 이산화염소 부산물이 클로라이트 클로레이트 발생량은 이산화염소 투입량의 $70{\sim}100%$ 정도였으며, 접촉시간이 경과되면서 클로레이트로 전환되는 양이 많아졌다. 또한 이산화염소와 염소를 병행사용할 경우 급배수관망에서 클로라이트와 유리잔류염소가 반응하여 이산화염소가 재생성되어 강한염소냄새(락스성) 민원이 발생될 수 있다.

광어(Paralichtys olivaceus)의 스쿠치카감염증(感染症) -스쿠치카섬모충(纖毛蟲)의 배양성상(培養性状).약제감수성(藥劑感受性).병원성(病源性)-

  • 길수 수;일향진일;오 명주;생도삼내자;목촌교구;삼 립성;야촌철일;회면량남
    • 한국어병학회지
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    • 제6권2호
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    • pp.205-218
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    • 1993
  • On the development of hirame(Paratichtys olivaceus) culture, outbreak of scuticociliata infection was reported to cause severe damage in Japan. To establish effective measures for isolation and cultivation of this ciliate, we tried to culture this pathogenic ciliate using medium for bacteria and fish cell lines in vitro. Scuticociliata from the brain tissues of infected fish was aseptically inoculated to CHSE-214 cells cultured in MEM-10 without antibiotic. Scuticociliata grew well and the number of ciliate reached $10^6\;cells/ml$ at temperatures of $15^{\circ}C$ to $20^{\circ}C$ for 10d. The number of ciliate cultured in the cell lines is 10 times higher than the numbers cultured in the liquid medium alone. This ciliata could be cloned by dilution method. Scuticociliata isolated could grow well on 42 different cell lines that were established from marine fish, warm freshwater fish, and salmonids. This ciliate could be preserved in liquid nitrogen for more than 6 months. Subsequently, we observed the optimal temperature and salinity for growth, and tested the sensitivities of this organism to formaldehyde, flagyl(Metronidazole), Ekuteshin(Combination compound of sulfamonometoxin and ormethoprim), and ozonixation. Optimal temperature for growth was $25^{\circ}C$ and salinity was 1.0 to 1.5%. Washed scuticociliata was killed by formaldehyde at the concentration of 50ppm for 10min, but was not completely killed even at a high concentration of 400ppm for 20min in MEM-5. Flagyl and Ekuteshin can inhibit the growth of scuticociliata at the concentration of 1,000 and $100{\mu}g/ml$ in MEM-10, respectively. More than 99% of this scuticociliata could be killed by ozonization at a dose equivalent to $1.0mg/\ell$ oxidant for 30sec in sea water. Isolated scuticociliata showed the pathogenicity to the cultured hirame by artificial infection(I. P. injection, $10^5\;cells$/fish). The number of scuticociliata in the water could be counted by most probable number(MPN) method using tissue culture, and the minimum detectable number was $1.8\;cells/\ell$. The number in the reservoir tank for water supply to the culture tank was 110 cells/l. After cleaning by elimination of the sediments from of the reservoir tank and disinfected with formaldehyde, number of scuticociliata decreased and was counted less than $1.8\;cells/\ell$ and infection rate of cultured hirame was decreased.

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넙치(Paralichthys olivaceus)의 생존과 생리상태에 미치는 오존의 급성 독성 (Acute Toxicity of Ozone on Survival and Physiological Conditions of Olive Flounder, Paralichthys Olivaceus)

  • 김흥윤;오명주;정성주
    • 한국어병학회지
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    • 제12권1호
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    • pp.32-41
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    • 1999
  • 오존처리 해수중에 함유하는 잔류 옥시던트(TRO)가 양식 넙치의 생존, 혈액성상과 삼투질 농도, 산소소비 및 아가미 조직에 미치는 독성 영향을 조사하였다. TRO에 노출된 넙치의 48-hr 및 96-hr $LC_{50}$은 각각 26.4 와 22.3ppb이었고, 47ppb에서는 3시간 이내에 모두 치사하였으나 13ppb에서는 96시간 동안 폐사발생이 없었다. TRO 24~39ppb 농도범위에 노출된 넙치의 hematocrit, 헤모글로빈, 적혈구 수, 혈중 sodium과 chloride 이온 및 삼투압 농도는 TRO 농도가 높을수록 유의하게 증가하였고, 아가미 조직은 아가미 상피층이 모세혈관으로부터 박리되고, 괴사와 상피새포의 증생이 관찰되었다. 산소소비율은 TRO 농도가 높고, 노출이 계속될수록 감소하였다. 13ppb에서는 아가미 조직과 생리상태에 미치는 변화는 관찰되지 않았으나 혈당은 유의하게 증가하였다. 그러나 활성탄으로 TRO를 제거한 대조구에서는 오존의 독성 영향은 관찰되지 않았다. 잔류오존에 노출된 넙치는 삼투질 농도의 생리적 불균형 및 아가미 손상과 상피세포의 증생에 의한 산소섭취 부족이 치사를 유발하는 것으로 나타났다. 본 연구의 결과 해산어 양식장에서 오존을 사용할 경우에는 오존처리수중의 TRO는 제거하여야 하며, 비록 저농도라도 장기간 노출되면 양식어류의 생존과 생리상태에 미치는 영향은 현저할 것으로 평가되었다.

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