• Title/Summary/Keyword: ozone-water

Search Result 583, Processing Time 0.03 seconds

Optimization of Ozone Oxidation process for Decolorization form dyeing wastewater (염색폐수 색도저감을 위한 오존산화공정의 최적화)

  • Sin, Dong-Hun;Choe, Jang-Seung;Lee, Sang-Heon;Kim, Seong-Jin;Ryu, Seung-Han;Park, Jun-Hyeong;Choe, Seong-Uk
    • Proceedings of the Korean Society of Dyers and Finishers Conference
    • /
    • 2008.10a
    • /
    • pp.115-116
    • /
    • 2008
  • The textile wastewater discharged from printing and dyeing processes is characterized by high chemical oxygen demand(COD), low biochemical oxygen demand(BOD), and heavy color. The release of dyes into the environment constitutes only small proportion of water pollution, but dyes are visible in small quantities due to their brilliance. In this study, We are investigated to optimization of Ozone Oxidation process for Decolorization.

  • PDF

Temporal and Spatial Distributions of the Surface Solar Radiation by Spatial Resolutions on Korea Peninsula (한반도에서 해상도 변화에 따른 지표면 일사량의 시공간 분포)

  • Lee, Kyu-Tae;Zo, Il-Sung;Jee, Joon-Bum;Choi, Young-Jean
    • New & Renewable Energy
    • /
    • v.7 no.1
    • /
    • pp.22-28
    • /
    • 2011
  • The surface solar radiations were calculated and analyzed with spatial resolutions (4 km and 1 km) using by GWNU (Gangneung-Wonju National University) solar radiation model. The GWNU solar radiation model is used various data such as aerosol optical thickness, ozone amount, total precipitable water and cloud factor are retrieved from Moderate Resolution Imaging Spectrometer (MODIS), Ozone Monitoring Instrument (OMI), MTSAT-1R satellite data and output of the Regional Data Assimilation Prediction System(RDAPS) model by Korea Meteorological Administration (KMA), respectively. The differences of spatial resolutions were analyzed with input data (especially, cloud factor from MTSAT-1R satellite). And the Maximum solar radiation by GWNU model were found in Andong, Daegu and Jinju regions and these results were corresponded with the MTSAT-1R cloud factor.

Removal of Rhodamine B in Water by Ultraviolet Radiation Combined with Electrolysis(I) (전기분해와 UV 조사에 의한 수중의 Rhodamine B의 제거(I))

  • Park, Young-Seek
    • Journal of Environmental Health Sciences
    • /
    • v.34 no.6
    • /
    • pp.439-445
    • /
    • 2008
  • The feasibility study for the application of the removal and mineralization of Rhodamine B (RhB) was performed in a batch electrochemical reactor. The electro/UV process was consisted of DSA (dimensionally stable anode) electrode and UV-C or ozone lamp. The experimental results showed that RhB removal by the ozone lamp was higher than that of the UV-C lamp. Optimum current of the electro/UV process was 1 A. The electrochemical, UV and electro/UV process could completely degrade RhB, while a prolonged treatment was necessary to reach a high level RhB mineralization. It was observed that RhB removal in electro/UV process is similar to the sum of the UV and electrolytic decolorization. However, it was found that the COD of RhB could be degraded more efficiently by the electro/UV process (90.2 %) than the sum of the two individual oxidation processes [UV (19.7%) and electrolytic process (50.8%)]. A synergetic effect was demonstrated between the UV and electrolysis.

The Effects of Preozonation on Organic Removal in Biological Activated Carbon Fluidized Bed (생물활성탄 유동상에서 전오존처리가 유기물 제거에 미치는 영향)

  • 우달식;곽필재;남상호
    • Journal of environmental and Sanitary engineering
    • /
    • v.13 no.1
    • /
    • pp.166-173
    • /
    • 1998
  • This study was to investigate the effects of preozonation on the waterborne organic removal by the biologically active GAC fluidized bed on a laboratory scale. The raw water to be treated comes from midstream of Han river. As the ozone dose was increased in the range of $1~3{;\}mgO_{3}/mgDOC$, it produced BDOC from 1.82 to 2.65 times. And BDOC formation can be expressed as [BDOC] = 0.74 + 0.21[DOC] ($R^{2}{\;}={\;}0.8399$). The effects of combination of ozonation followed by BACFB (Biological Activated Carbon Fluidized Bed) process were analyzed. At the ozone doze of $1~3{\;}mgO_{3}/mgDOC$, the large fraction of BDOC was removed by BACFB, but parameter revealed only around 10% reduction.

  • PDF

Studies on Ozonation of Nicotine (니코틴의 오존화 반응에 관한 연구)

  • Taek-Kyu Park;Ki-Hwan Kim;Tae-Sung Huk
    • Journal of the Korean Chemical Society
    • /
    • v.28 no.5
    • /
    • pp.323-327
    • /
    • 1984
  • Nicotine was reacted with an equimolar amount of ozone in methylene chloride and distilled water. The reaction mixture was separated by column chromatography or thin layer chromatography and then purified by vacuum distillation. The six compounds obtained from this reaction were characterized by NMR, IR and Mass spectrometry. These were identified as unchanged nicotine, nornicotine, anabasine, ${\beta}$-nicotyrine, cotinine and nicotine-N-oxide. From these results, reaction mechanism for the ozonolysis ofon nicotine was proposed; the pyrrolidine ring is attacked by ozone at the 1'-position followed by further transformation.

  • PDF

Electrical and Structural Properties of ZnO:Pt Films Prepared by Ultrasonic Spray Pyrolysis (초음파분무열분해법으로 제조한 ZnO:Pt막의 전기적 및 구조적 특성)

  • Ma, Tae-Young;Park, Ki-Cheol
    • Journal of Sensor Science and Technology
    • /
    • v.13 no.1
    • /
    • pp.66-71
    • /
    • 2004
  • Pt-doped zinc oxide (ZnO:Pt) films were deposited by ultrasonic spray pyrolysis. Resistivity variation with Pt concentration was measured. The Pt distribution in ZnO:Pt films was studied through Auger Electron Spectroscopy (AES). The ZnO:Pt films were annealed in the ambient of air, water vapor and ozone, respectively. The variation in crystallographic properties and surface morphologies with respect to the annealing condition was observed by X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The resistivity variation of the films with the annealing condition was measured. Finally, Atomic Force Microscopy (AFM) measurements were carried out to study the effects of the annealing on the roughness of ZnO:Pt films.

Removal Characteristics of Synthetic Musk Compounds in Water by Ozone Treatment (오존처리에 의한 수중의 인공 사향물질 제거특성)

  • Seo, Chang-Dong;Son, Hee-Jong;Yoom, Hoon-Sik;Lee, Sang-Won;Ryu, Dong-Chun
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.34 no.2
    • /
    • pp.73-78
    • /
    • 2012
  • In this study, three different synthetic musk compounds (SMCs) in the Nakdong river water (raw water) and rapid sand filtered water were treated by $O_3$ process. The experimental results showed that the removal efficiency of musk ketone (MK) was lower than removal efficiency of AHTN (7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene) and HHCB (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[c]-2-benzopyran) for both the raw water and the rapid sand filtered water. And in general, the removal efficiencies of three SMCs in the raw water were lower than that in the sand filtered water. Under the $O_3$ dose of 0.5~10.0 mg/L, the removal rate constants (k) of three SMCs for the raw and sand filtered waters increased rapidly with the increased $O_3$ dose. In the case of drinking water treatment plants (DWTPs) which were selected pre- and post-$O_3$ processes (located in the downstream of Nakdong River), operation conditions of pre- and post-$O_3$ process were $0.5{\sim}2.0mg{\cdot}O_3/L$ (2~4 min) and $0.5{\sim}2.5mg{\cdot}O_3/L$ (6~8 min). Therefore, $O_3$ doses and contact times of same conditions with above were very difficult to remove SMCs in DWTPs.

On the Recycling Substances and a Clean Technology Development for the Treatment of Mixed Acid Waste Water with Ozone (오존을 이용한 혼산폐수처리에 관한 청정기술개발 및 재이용 물질 회수에 관한 연구)

  • 김재우
    • Journal of environmental and Sanitary engineering
    • /
    • v.15 no.2
    • /
    • pp.34-40
    • /
    • 2000
  • In the tungsten industry, molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. Nitric acid dissolution method which used prevalently up to the present, takes nitric acid as major component and use noxious material such as sulfuric acid and hydrochloric acid remove molybdenum wire which used as center supporter by dissolve selectively within the range of no damage on tungsten wire. Mixed acid waste water occurred to the process were difficult to be decomposed by the conventional methords. This mixed acid waste water was treated by ozone, and It was obtained using possible by-product through the treatment waste water. For the three reactors with the same volume ; Blank reactor, Disturbance plate reactor, Packed-bed reactor ; the results were as follows : For the blank reactor COD removal efficiency in the pH = 4 (HRT : 6hr) was 28.5%, COD removal efficiency in the pH = 7 (HRT : 6hr) was 28.6%, and COD removal efficiency in the pH = 10 (HRT : 6hr) was 27.8%. For the disturbance plate reactor COD removal efficiency in the pH = 4 (HRT : 6Min.) was 86.5%, COD removal efficiency in the pH =7 (HRT : 6Min.) was 84.4%, and COD removal efficiency in the pH = 10 (HRT : 60Min.) was 86.8%. For the packed-bed reactor COD removal efficiency in the pH = 4 (HRT : 40Min.) was 76.0%, COD removal efficiency in the pH = 7 (HRT : 40Min.) was 81.3%, and COD removal efficiency in the pH = 10 (HRT : 40Min.) was 84.6%. After O3 treatment using possible by-product(Na2SO4) was 150g/ℓ.

  • PDF

Tertiary Treatment of Sewage by Micro Bubble Ozone and BAF System (미세기포 오존과 생물여과 시스템을 이용한 생활하수의 3차 처리에 관한 연구)

  • Kang, Dong-Han;Jang, Young-Ho;Kim, Jong-Su;Kim, Keug-Tae
    • Journal of Korean Society on Water Environment
    • /
    • v.27 no.6
    • /
    • pp.877-884
    • /
    • 2011
  • In this paper, the removal characteristics of dissolved organic carbon (DOCs) by micro bubble ozonation process and $O_3/UV$ process were comparatively studied. In the point of DOC removing reaction coefficient, micro bubble ozonation system and $O_3/UV$ process had not significant difference, $0.0120sec^{-1}$ and $0.0141sec^{-1}$. Therefore micro bubble ozonation process is more suitable for tertiary treatment of sewage in the point of installation and maintenance cost-reducing. The optimum ozone injection rate was 2.0 g $O_3/g$ DOC and HRT was 3 min for the micro bubble ozonation process. The removal efficiency of DOC and SUVA in micro bubble ozonation system was 32.8% and 58.3% respective. Biological aerated filter (BAF) process was installed to remove soluble organic material increased by micro bubble ozonation system. And the effluent BOD of BAF was below 1.0 mg/L. In the view of cost-effectiveness, $O_3/BAF$ process was more profitable than $O_3/UV/BAF$ process for tertiary treatment of sewage. In order to nitrify ammonia in the BAF process completely, $NH_4{^+}-N$ concentration in the influent water of BAF should be designed considering low water temperature in the winter season.

Effect of Ozone Concentration on AOP Efficiency of Secondary Effluent from Pig Slurry Purification System (오존 접촉농도가 양돈슬러리 2차 처리수의 고도처리 효율에 미치는 영향)

  • Jeong, K.H.;Jeon, S.K.;Ryu, S.H.;Kim, J.H.;Kwag, J.H.;Ann, H.K.;Jeong, M.S.;Yoo, Y.H.
    • Journal of Animal Environmental Science
    • /
    • v.17 no.3
    • /
    • pp.181-188
    • /
    • 2011
  • With an increasing livestock population, animal manure production has been steadily increasing in Korea. This trend has forced farmers to spend more money for animal manure treatment in their farm. Therefore, research utilizing animal manure as a renewable resources has become increasingly important. The purpose of this study was to develop a stable advanced wastewater treatment system can be applied to conventional animal wastewater treatment processes and evaluate its contribution to reduce effluent discharge volume by recycling as flushing water. AOP (advanced oxidation process) process improved wastewater treatment efficiency in terms of color, suspended solids (SS) and chemical oxygen demand (COD). Due to the addition of Hydrogen peroxide ($H_2O_2$), pathogens, Salmonella and E. coli, reduction was accomplished. To enhance ozone treatment effect, three levels of ozone test on secondary effluent of pig slurry purification system were conducted. At the level of 5 g/hr, 6.7 g/hr and 8.4 g/hr color of secondary effluent of pig slurry purification system were decreased from 2,433 to 2,199, 2,433 to 1,980 and 2,433 to 243, respectively.