• Journal of Power System Engineering
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• v.20 no.5
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• pp.92-97
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• 2016

In this study, the seawater Heat Pump System using seawater with temperature of annual domestic conditions ($0^{\circ}C$ to $25^{\circ}C$) is designed in order to compare its performance against the Heat Pump using unused heat of seawater. As a potential replacement for current refrigerants that exacerbate global warming and ozone delpetion, a Low GWP refrigerant's performance is analyzed. The basic water to water Heat Pump system is chosen and three commercial refrigerants - R134a, R410a, R32 - are used to compare against new Low GWP refrigerant R1234ze. When seawater with temperature of $25^{\circ}C$ is used, the performance change showed maximal increase in COP, 38.3%. low GWP refrigerant R1234ze, showed great performance characteristics reach to 5.242 and Existing commercial refrigerant, R134a showed only less than 0.03 performance difference against R1234ze. The study confirms notable performance of R1234ze refrigerant through simulation as environmentally friendly refrigerant for domestic seawater Heat Pump.

• Environmental Analysis Health and Toxicology
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• v.21 no.4 s.55
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• pp.365-373
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• 2006

Emission of methyl bromide (MeBr) from soil was implicated in stratospheric ozone depletion. To determine multi analysis of alternatives fumigants for MeBr, this paper describes the methods of analysis in water and soil. The MeBr, methyl iodide (Mel), propargyl bromide (PBr), cis 1,3-dichloropropene (cis 1,3-D), trans 1,3-dichloropropene (trans 1,3-D) and chloropicrin(CP) are separated on the base line on GC-ECD at three column of AT+DB+DB (90m) with temperature programing of $35^{\circ}C{\rightarrow}110^{\circ}C$ on GC-ECD. The relative retention time for MeBr, Mel, PBr, cis 1,3-D, trans 1,3-D and CP is 1.0, 1.4, 2.3, 3.2, 3.6 and 3.7, respertively. The detection limit for MeBr, Mel, PBr, cis 1,3-D, trans 1,3-D and CP is 469 pg, 5 pg, 21 pg, 79 pg, 101 PE and 5pg, respectively. Recovery of MeBr Mel, PBr, cis 1,3-D, trans 1,3-D and CP in water added 150 ppm fumigants were 81%, 96%, 95%, 97%, 98% and 99%, respectively. Recovery of MeBr, MeI, PBr, cis 1, 3-D, trans 1,3-D and CP in soil added 150ppm fumigants were 56%, 84%), 85%, 81%, 87% and 88%, respectively.

• Journal of Environmental Science International
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• v.16 no.12
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• pp.1463-1468
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• 2007

Emission of methyl bromide(MeBr) of soil fumigant was implicated in stratospheric ozone depletion. To determine the environmental fate for 1,3-dichloropene(1,3-D) of alternatives fumigants for MeBr, this paper researched the transformation for 1,3-D in water and soil. Half lives of cis-1,3-D in water with first-order kinetics are 9.9day and 1.7day at $25^{\circ}C\;and\;40^{\circ}C$, half lives of trans-1,3-D are 8.6day and 1.5day at $25^{\circ}C\;and\;40^{\circ}C$, respectively. Transformation for 1,3-D in water at high temperature faster then at low temperature. Hydrolysis for 1,3-D in water are unaffected at $pH\;2.5{\sim}pH\;10.0$, but hydrolysis for 1,3-D at pH 11.5 higher then at $pH\;2.5{\sim}pH\;10.0$. Half lives of cis-1,3-D in soil are 11.5day and 7.7day at 3% and 10% of soil moisture, half lives of trans-1,3-D are 9.9day and 6.9day at 3% and 10% of soil moisture, respectively. Transformation for 1,3-D in water increased with increasing soil moisture. Transformation for trans-1,3-D isomer are more rapid then cis-1,3-D isomer in water and soil. This research has identified that transformation for 1,3-dichloropropene are affected by temperature, pH, soil moisture, and isomer of cis and trans in water and soil.

• Journal of Environmental Science International
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• v.22 no.9
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• pp.1153-1160
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• 2013

While a range of natural organic matter (NOM) types can generate high levels of disinfection by-products (DBPs) after chlorination, there is little understanding of which specific compounds act as precursors. Use of eight model compounds allows linking of explicit properties to treatability and DBP formation potential (DBPFP). The removal of model compounds by various treatment processes and their haloacetic acid formation potential (HAAFP) before and after treatment were recorded. The model compounds comprised a range of hydrophobic (HPO) and hydrophilic (HPI) neutral and anionic compounds. On the treatment processes, an ozone oxidation process was moderate for control of model compounds, while the HPO-neutral compound was most treatable with activated carbon process. Biodegradation was successful in removing amino acids, while coagulation and ion exchange process had little effect on neutral molecules. Although compared with the HPO compounds the HPI compounds had low HAAFP the ozone oxidation and biodegradation were capable of increasing their HAAFP. In situations where neutral or HPI molecules have high DBPFP additional treatments may be required to remove recalcitrant NOM and control DBPs.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.12
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• pp.1292-1297
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• 2005

The use of ozone in water and wastewater treatment systems has been known to be a process that is limited by mass transfer. The most effective way to overcome this limitation is to increase the interfacial area available for mass transfer by decreasing the size of the ozone gas bubbles that are dispersed in solution. Electrostatic spraying(ES) of ozone into water was investigated in this work as a method of increasing the rate of mass transfer of ozone into a solution and thereby increasing the rate of phenol oxidation. Results were obtained for ES at input power levels ranging from 0 to 4 kV and compared with two different pore-size bubble diffusers($10{\sim}15{\mu}m$ and $40{\sim}60{\mu}m$). It was determined that the rate of mass transfer could be increased by as much as 40% when the applied voltage was increased from 0 to 4 kV as a result of the smaller bubbles generated by ES. In addition, ES was shown to be more effective than the medium-pore-size($10{\sim}15{\mu}m$) bubble diffuser and the best results were achieved at low gas flow rates.

• Korean Journal of Remote Sensing
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• v.15 no.3
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• pp.253-266
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• 1999

ADEOS(Advanced Earth Observing Satellite)/IMG(Interferometric Monitor for Greenhouse Gases) measurements - temperature, water vapor($H_2O$), ozone($O_3$) have been compared with the radio sonde and ozone sonde observations at Osan and Pohang stations for the 4 cases on 10 Jan.(a), 28 Jan.(b), 2 Apr.(c), and 19 Jun.(d) 1997 to detect the error ranges of the IMG data. It showed that the IMG data of the cases (b), (d) when the ADEOS passed over the central part of Korea were quite stable with the good agreement with the sonde observations, however, that of (a),(c) when the ADEOS passed over south- east coastal area were unstable with the larger differences from the sonde-observations. The RMSE and bias analyses of temperature for the stable cases (b),(d) showed that the differences between the IMG data and the sonde observations were about 1~4 K at the 700~300 hPa level and about 4~5 K or more at the higher level, and the IMG measurements tended to be larger than the sonde observations at the higher level above 200 hPa, while no typical bias was seen at the lower level. The RMSE and bias analysis for the version of level 2 5_6_4_4 of ozone showed that the RMSE of ozone were quite small, in general, except at the higher level above 50~60 hPa in the all 4 cases, however the bias was generally big with the positive value in the troposphere and the negative in the stratosphere. An example of vertical profile of trace gases such as $CO_2, N_2O, CH_4, HNO_3$, CO measured by IMG was also presented and it showed that the IMG data had large differences between the 5 different observation points.

• Korean Journal of Environmental Agriculture
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• v.17 no.4
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• pp.352-357
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• 1998

This experiment was conducted to find out the effects of major nutrient levels(N, P, K) on ozone susceptibility of tomato plants(Lycopersicon esculentum Mill, cv. Pink Glory). Plants were grown in water culture system. A half-strength of Hoagland's nutrient solution was considered as a standard formulation($N_{100}$ $P_{100}$ $K_{100}$). The levels of major nutrients were adjusted through addition or removal of several fertilizer salts from the standard solution. Top growth was significantly decreased at the low nitrogen level or phosphorus removal condition. P- and K-contents of leaves were greatly decreased by removal of salts containing P and K from the nutrient solution. The rate of ozone injury was significantly increased when potassium was removed. However, the influence of nitrogen and phosphorus levels or high potassium level on injury occurrence did not show statistical significance compared to the standard solution. Ozone exposure resulted in reduction of chlorophyll, and increase of ethylene production, electrolyte leakage and malondialdehyde(MDA) contents. These changes were much more enhanced in plants grown at the potassium removal solution. Whereas the activity of superoxide dismutase(SOD) was low at the potassium removal treatment and this tendency remained after ozone exposure. These results indicated that potassium nutrient level in tomato plants is closely associated with the susceptibility to ozone injury.

• Journal of Korean Society of Forest Science
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• v.109 no.1
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• pp.50-61
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• 2020

Street trees are very important to urban environments as they can alleviate air pollution. However, when ozone is absorbed through the stomata, it can induce the formation of free radicals inside the tree, negatively affecting the vegetation. The present study investigated the Air Pollution Tolerance Index (APTI) of four major street tree species: Prunus yedoensis, Zelkova serrata, Chionanthus retusus, and Pinus densiflora. Two-year-old seedlings were placed in a phytotron and fumigated with 100 nL·L^-1 (ppb) ozone for 4 weeks, following which the ascorbic acid contents, chlorophyll contents, leaf pHs, and relative water contents were measured. There was no significant difference in the APTI of Prunus yedoensis and Zelkova serrata between the ozone and control treatments. By contrast, the ozone treatment caused the APTI of Chionanthus retusus to increase and that of Pinus densiflora to decrease compared with the respective controls. These results suggest that the APTI of these tree species exhibit very different responses to ozone. Therefore, more detailed research should be conducted on a range of species in the future.

• Journal of Environmental Science International
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• v.28 no.3
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• pp.341-356
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• 2019

In this study, the impacts of local meteorology caused by tidal changes in the West Sea on ozone distributions in the Seoul Metropolitan Area (SMA) were analyzed using a meteorological model (WRF) and an air quality (CMAQ) model. This study was carried out during the day (1200-1800 LST) between August 3 and 9, 2016. The total area of tidal flats along with the tidal changes was calculated to be approximately $912km^2$, based on data provided by the Environmental Geographic Information Service (EGIS) and the Ministry of Oceans and Fisheries (MOF). Modeling was carried out based on three experiments, and the land cover of the tidal flats for each experiment was designed using the coastal wetlands, water bodies (i.e., high tide), and the barren or sparsely vegetated areas (i.e., low tide). The land cover parameters of the coastal wetlands used in this study were improved in the herbaceous wetland of the WRF using updated albedo, roughness length, and soil heat capacity. The results showed that the land cover variation during high tide caused a decrease in temperature (maximum $4.5^{\circ}C$) and planetary boundary layer (PBL) height (maximum 1200 m), and an increase in humidity (maximum 25%) and wind speed (maximum $1.5ms^{-1}$). These meteorological changes increased the ozone concentration (about 5.0 ppb) in the coastal areas including the tidal flats. The increase in the ozone concentration during high tide may be caused by a weak diffusion to the upper layer due to a decrease in the PBL height. The changes in the meteorological variables and ozone concentration during low tide were lesser than those occurring during high tide. This study suggests that the meteorological variations caused by tidal changes have a meaningful effect on the ozone concentration in the SMA.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.52 no.7
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• pp.335-342
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• 2003

This paper presents a forward type high voltage pulse power supply for high voltage small current, which can be designed as a simple circuit configuration and managed easily using Power-MOSFET in the view of commercialization. According to the switching frequency, coupling factor(k) and duty ratio(D), the Principle of basic operation and the characteristics of the proposed pulse power supply are estimated. Simulation results have demonstrated the feasibility of the proposed pulse power supply. Also experimental results are presented to verify theoretical discussion with a lamp type ozonizer as a load. For studying the application at the part of environment of water, When ozonizer gas reacts with a colon bacillus, the sterilization characteristics of a colon bacillus according to the ozone concentration and response time have been investigated. This proposed pulse power supply will be able to be practically used as a pulse power supply in various environment improvement facilities like sterilization of colon bacillus, deodorization, and Nox gas elimination.