• Title/Summary/Keyword: ozone-water

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순환여과시스템에서 오존을 이용한 암모니아성 질소의 탈질화 연구

  • Huh, Mock;Lim, Jin-Suk;Kim, Boo-Gil
    • Journal of Environmental Science International
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    • v.7 no.4
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    • pp.493-500
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    • 1998
  • An experimental study was conducted to Indentify the dlrpct denitrification of ammonium nitrogen In culture water by ozone. During the experimnet period, pH was 7.8-8.8. pH was grdually lower after ammonium nitrogen was reacted with ozone under Br . In addition, it can be tmown that the culturing water was improved greatly form the inverstigation of T-N by biofilm and ozonation. As the results of a variation of recirculation rate, denitrification of ammonium nitrogen was in increased in proportion to the recirculation rate. But Nitrification of microorganism was opposite to the recirculation rate. With the increasing injected ozone in ozonation tank uner 21 clrculation/day(6.71 /min), dinitrification of ammonium nitrogen was Increased lineraly in propotion to the Increasing of injected ozone concentration.

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Degradation and Neutralization of Total Residual Oxidant (TRO) in the Treated Ballast Water by Ozonation

  • Park, Sung-Jin;Bin, Jung-In;Lee, Eon-Sung;Kim, In-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.3
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    • pp.399-406
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    • 2010
  • The aims of this study are to provide data on the ozone dosage control system and TRO sensor performance, to assess the performance of the degradation of total residual oxidant (TRO) neutralizer and to provide data on degradation rates of TRO in the ballast tanks, following treatment by the Ozone BWTS. This study includes the results of an evaluation of the TRO neutralizer, which was tested on the test barge. Accordingly, it has undertaken the evaluation of TRO degradation rates following treatment by the Ozone BWTS.

Assessing the removal efficiency of Synedra sp. through analysis of field data from water treatment plants

  • Seo, Dae-Keun;Kim, Yeong-Kwan
    • Membrane and Water Treatment
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    • v.11 no.2
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    • pp.141-149
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    • 2020
  • Prechlorination could increase the removal efficiency of Synedra, but there was no significant effect of increasing the amount of chlorine added. However, a removal efficiency of greater than 80% was noted when ozone was injected at concentrations greater than 2 mg/L. Also, it was found that on addition of polyamine, a removal efficiency of 80% or more could be achieved. As a result of the analysis of field operation data from the water treatment plants G and B, it was found that at water treatment plant G, the filter run time decreased to 10 hours or less when only coagulant was injected, but the filter run time increased to around 40 hours when polyamine (3 mg/L) was also injected. The Synedra population in the raw water subsequently increased to 2,340 cells/mL, and the filter continued running for more than 20 hours. At water treatment plant B, the average Synedra removal efficiency was 56% when only coagulant was injected, and the filter run time decreased drastically with the increasing population of Synedra in the raw water. However, the removal efficiency of Synedra reached 79% when polyamine was injected together with the coagulant, 90% when ozone was also injected, and 95% when polyamine and ozone were injected together and the filter continued running for over 50 hours. The filter run time was maintained at 60 hours when a Synedra population of 6,890 cells/mL flowed into the Paldang water source, but the filter run time with Synedra at 1,960 cells/mL decreased rapidly from 65 hours to 35 hours when the ratio of the size of the individual Synedra reaching 250 ㎛ or more, increased from 38% to 94%. Therefore, the size of the Synedra is considered to be a factor that significantly influences filter clogging, as well as the size of the Synedra population.

Study on the Characteristics of Dielectric Barrier Discharging System and Usability as a Disinfectant (2계면 플라즈마 방전시스템(DBD System)의 특징 및 소독제로서 방전수의 사용가능성에 대한 연구)

  • Ryu, Seungmin;Park, Heekyung;Lee, Bongju
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.529-536
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    • 2004
  • Innovated technique to inactivate microorganisms has been developed. This technique uses plasma discharge in 2-phase (Air-Water). Dielectric Barrier (two phase) Discharging system is able to produce new oxidants for microorganisms. Products from discharging are $HNO_2$, $NO_2{^-}$, $HNO_3$, $NO_3{^-}$ and ozone but many other radicals can be generated as well. DBD water has low concentration of ozone (about 0.5mg/L), $NO_2{^-}$, $NO_3{^-}$ (about 10mg-N/L, 20mg-N/L respectively) and lots of $H^+$. These products play an important role in oxidation. Oxidation power by KI titration methods is approximately equivalent to $50mg-O_3/L$. Surprisingly stored DBD water could oxidize KI and maintain stable pH (about pH3) even after several days. Stored DBD water for 5 days has also more than 4log disinfection power to E. coli. However, DBD water cannot be used for drinking water directly due to it's toxicity. Additional process to neutralize pH and decrease toxicity must be applied.

Effects of the El Niño on Tropospheric Ozone in a Simulation using a Climate-Chemistry Model (기후-대기화학모델이 모의한 엘니뇨가 대류권 오존에 미치는 영향)

  • Moon, Byung-Kwon;Yeh, Sang-Wook;Park, Rokjin J.;Song, Chang-Keun;Youn, Daeok
    • Journal of the Korean earth science society
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    • v.34 no.7
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    • pp.662-668
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    • 2013
  • We examine the effects of El Ni$\tilde{n}$o on tropospheric ozone through the simulation of a Climate-Chemistry model for a 40-year period (1971-2010). The Empirical Orthogonal Function (EOF) analysis reveals that the tropospheric ozone concentration in the central-eastern Pacific decreases when the El Ni$\tilde{n}$o occurs, which is consistent with the observation. However, the increase of ozone over Indian Ocean-Indonesia regions is weak in the simulation compared to the observations. We analyze details of the 2006 El Ni$\tilde{n}$o event to understand the mechanism that caused the change of ozone due to El Ni$\tilde{n}$o. It is found that enhanced convection as well as higher water vapor followed by shortened lifetime has led to lower the tropospheric ozone. Downward motion induced by the changes of atmospheric circulation due to sea surface temperature forcing, together with the decrease of water vapor, has brought ozone produced in the upper troposphere over the Indian Ocean.

Physiological and Biochemical Responses of Sedum kamtschaticum and Hosta longipes to Ozone Stress (기린초와 비비추의 오존에 대한 생리·생화학적 반응)

  • Cheng, Hyo Cheng;Woo, Su Young;Lee, Seong Han;Kwak, Myeong Ja;Kim, Kyeong Nam
    • Horticultural Science & Technology
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    • v.31 no.1
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    • pp.1-7
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    • 2013
  • In this study, the resistance to ozone and characteristics of ozone-induced damage were investigated on the perennial ground cover plant species. Sedum kamtschaticum and Hosta longipes were exposed to $200{\mu}g{\cdot}kg^{-1}$ ozone for 8 hours per day (from 08:00 to 16:00) in the naturally irradiated phytotron. The extent of ozone-induced damage was measured through the analysis of physiological parameters, such as water use efficiency (WUE), chlorophyll content (Chl. a, Chl. b, Chl. a + b, and Chl. a/b ratio), carotenoid contents, and the induction of reactive oxygen species (ROS). Ozone exposure significantly reduced the daytime WUE in both species. The contents of chlorophyll and carotenoid were also decreased and ROS, such as hydrogen peroxide ($H_2O_2$) and superoxide radical ($O_2{^-}$) were accumulated after ozone exposure. The above results of this study suggested that S. kamtschaticum is more resistant to atmospheric ozone than Hosta longipes. Considering its fast responses to ozone, it was also assumed that Hosta longipes can be used as an indicator plant of an increase in atmospheric ozone concentration.

Comparison of Sanitization Process for Long-Term Storage of Fresh Red Pepper (생 홍고추 장기저장을 위한 살균공정의 비교)

  • Yang, Jin-Hyun;Lee, Young-Chun;Lee, Kyoung-Hae
    • Korean Journal of Food Science and Technology
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    • v.39 no.4
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    • pp.419-424
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    • 2007
  • The optimum sanitization conditions for fresh red pepper were acquired with hot water, ozone water, hydrogen peroxide and sodium hypochlorite. At this condition, the sanitized red pepper was frozen at $-70^{\circ}C$, stored at $-30^{\circ}C$ for 30 days and then changes of quality in each treatment were measured. Escherichia coli and coliform group were found to be negative with the conditions of 4 min hot water treatment at $95^{\circ}C$, 6 min ozone water (0.5 ppm) treatment, 12 min sanitization for 2%-hydrogen peroxide and of 4 min 3%-sodium hypochlorite treatment. Drip loss was generated highest at the hot water treatment to be 15%. The content of ascorbic acid was less than 40% of the control at all treatments except ozone water treatment. The content of cartenoids was 124.16-182.87 mg% at ozone water treatment which was found to be the least loss. The sensory evaluation showed that most treatments except ozone water treatment were significantly different to the control (p < 0.05). Therefore, ozone treatment was evaluated to be the best method for producing the sanitized fresh red pepper.

Effect of Ozone Treatment for Nakdong River Raw Water I. Efficiency of Water Treatment by Conducting Batch Test of Ozonation Experiments (낙동강 상수원수의 오존처리 효과 I. 회분식 오존처리에 의한 수처리효과)

  • 조주식;임영성;이홍재;허종수
    • Journal of Environmental Science International
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    • v.10 no.6
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    • pp.393-399
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    • 2001
  • This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using ozonation. for raw water, Nakdong River was used. By conducting batch ozonation test, the following results were obtained. when ozone dosage of 5mg/$\ell$was used, preozonation of raw water reduced turbidity, KMnO$_4$consumption, DOC(dissolved organic carbon), UV254 absorbance, THMFP(trihalomethane formation potential) as much as 3.9NTU, 5.5mg/$\ell$, 1.15mg/$\ell$, 0.112 and 0.065mg/$\ell$, respectively. In case of postozonation of sand filtered water, water quality was also improved with decrease in turbidity, KMnO$_4$consumption, DOC, UV254 absorbance and THMFP at the amount of 0.08NTU, 2.6mg/$\ell$, 0.88mg/$\ell$, 0.042 and 0.018mg/$\ell$, respectively. On the other hand, contents of dissolved oxygen increased at the level of 1.3mg/$\ell$ after preozonation process and 1.0mg/$\ell$ after postozonation process. The effect of ozone dosage was higher than that of its contact time for the removal of the pollutants.

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The measurement of Ozone Concentration and Simulation of Electric Field Distribution at Dielectric Tube of one Layer with Globular Dielectric in Water (구형 유전체비드를 가지는 단층절연방전관의 수(水)오존농도측정 및 전계분포 시뮬레이션)

  • Lee, Dong-Hoon;Park, Jae-Youn;Park, Hong-Jae;Koh, Hee-Seog;Lee, Hyun-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.08a
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    • pp.44-47
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    • 2003
  • In this paper, the electric field distribution in dielectric tube with one layer and spherical dielectric($ZrO_2$) in water was simulated. The reactor was made up of the spherical dielectric that is diameter : 3.0[mm], $ZrO_2(\varepsilon_r:10)$ and one glass plate of thickness(2[mm]), $\varepsilon_r$(10) as electrode. The discharge gap was 8[mm]. To get more strong electric field, the dielectric constant should be higher comparatively. Using the spherical dielectric for water discharge in dielectric tube, the location of equipotential line was shifting from the interior to the exterior. At real water discharge experimental, ozone was measured higher dissolved ozone in water at condition of water rate(l[l/min]) and injector than condition of non-injector or 2~3[l/min].

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Removal of Sulfamethoxazole using Ozonation or UV Radiation; Kinetic Study and Effect of pH (오존 처리 및 UV 조사를 이용한 Sulfamethoxazole 제거; 동역학적 고찰 및 pH 영향)

  • Jung, Yeonjung;Kim, Wangi;Jang, Hayoung;Choi, Yanghwun;Oh, Byungsoo;Kang, Joonwun
    • Journal of Korean Society on Water Environment
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    • v.24 no.1
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    • pp.63-68
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    • 2008
  • This study was performed to assess the potential use of ozone or UV radiation for the treatment of water contaminated with sulfamethoxazole (SMX), which is frequently used antibiotic in human and veterinary medicines, especially focusing on the kinetic study and effect of pH. In a study using ozone alone, kinetic study was performed to determine second-order rate constant ($k_{O3,SMX}$) for the reactions of SMX with ozone, which was found to be $1.9{\times}10^6M^{-1}s^{-1}$ at pH 7. The removal efficiencies of SMX by ozone were decreased with increase of pH due to rapid decomposition of ozone under the condition of various pH (2.5, 5.3, 7, 8, 10). In a UV irradiation study at 254 nm, a kinetic model for direct photolysis of SMX was developed with determination of quantum yield ($0.08mol\;Einstein^{-1}$) and molar extinction coefficient ($15,872M^{-1}cm^{-1}$) values under the condition of quantum shielding due to the presence of reaction by-products formed during photolysis. For effect of pH on photolysis of SMX, SMX in the anionic state ($S^-$, pH > 5.6), most prevalent form at environmentally relevant pH values, degraded more slowly than in the neutral state (SH, 1.85 < pH < 5.6) by UV radiation at 254 nm.