• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E3
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• pp.121-127
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• 2003

The characteristics of heterogeneous photocatalytic decomposition were investigated at low concentration level of $O_3$on TiO$_2$for various operating parameters such as: loaded catalyst weight (0∼4 mg/$\textrm{cm}^2$), initial concentration of $O_3$(0.06∼10.0 ppm), gas flow rate (1.0 ∼ 2.5ι/min), and relative humidity (0∼80%). This study was conducted using a flow-type reactor at room temperature. Three kinds of pure TiO$_2$(P25, ST -01, and E- 23) were employed as photocatalyts. It was found that $O_3$removal ratio was identical, regardless of the loaded TiO$_2$weight in the range from 0.5 to 4.0 mg/$\textrm{cm}^2$. It was also found that higher initial ozone concentration results in greater oxidation rate of ozone and experimental data show kinetically a good agreement with Langmur-Hinshelwood kinetic model. We also observed that the removal ratio of $O_3$increases linearly with the increasing flow rate and also with the increasing relative humidity for each catalyst.

• Journal of Korean Society of Water and Wastewater
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• v.37 no.5
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• pp.253-259
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• 2023

Bioreactors are devices used by sewage treatment plants to process sewage and which produce active sludge, and sediments separated by solid-liquid are treated in anaerobic digestion tanks. In anaerobic digestion tanks, the volume of active sludge deposits is reduced and biogas is produced. After dehydrating the digestive sludge generated after anaerobic digestion, anaerobic digested wastewater, which features a high concentration of organic matters, is generated. In this study, the decomposition of organic carbon and nitrogen was studied by advanced oxidation process. Ozone-microbubble flotation process was used for oxidation pretreatment. During ozonation, the TOC decreased by 11.6%. After ozone treatment, the TOC decreased and the removal rate reached 80.4% as a result of the Ultra Violet-Advanced Oxidation Process (UV-AOP). The results with regard to organic substances before and after treatment differed depending on the organic carbon index, such as CODMn, CODCr, and TOC. Those indexes did not change significantly in ozone treatment, but decreased significantly after the UV-AOP process as the linkage treatment, and were removed by up to 39.1%, 15.2%, and 80.4%, respectively. It was confirmed that biodegradability was improved according to the ratio of CODMn to TOC. As for the nitrogen component, the ammonia nitrogen component showed a level of 3.2×10² mg/L or more, and the content was maintained at 80% even after treatment. Since most of the contaminants are removed from the treated water and its transparency is high, this water can be utilized as a resource that contains high concentrations of nitrogen.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2000.11a
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• pp.211-214
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• 2000

휘발성 유기물질은 ground level ozone의 전구체로써 미래 대기오염의 주원인이 될것으로 판단되는 물질이며 구미각국에서는 1990년 초반부터 그리고 국내에서는 최근에 와서 규제가 확정된 물질이다. 대표적인 휘발성 유기물질의 종류와 배출원을 Table 1과 Table 2에 나타내었다.(중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2007.10a
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• pp.139-140
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• 2007

• Journal of The Korean Association For Science Education
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• v.19 no.4
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• pp.585-594
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• 1999

The purpose of this study is to examine the concept of Greenhouse Effect as understood by middle school high school university students using a closed-form questionnaire. Based on results of the questionnaire which was administered to 619, the extent to which alternative concepts were held was quantified and compared the difference of various group based on grade level. gender, text and major. Also, subjects were divided into two groups, one is middle school students and the other is high school university students and common themes within conceptual framework of each group were identified by factor analysis. The result showed that students confused Greenhouse Effect with ozone layer depletion in stratosphere and linked familiar contamination around everyday life. acid rain. radioactive contamination, nuclear arsenal to Greenhouse Effect. These trends were more appreciable in female than male, biology major than any other major and text did not make any significant difference. In addition, the result of factor analysis showed that two groups linked familiar contamination around everyday life to Greenhouse Effect and high school university students understand the consequences of an increase in the Greenhouse Effect more systematically than middle school student, perceived the relation between the origin of an increase in the Greenhouse Effect and human activity but confused Greenhouse Effect with ozone layer depletion in stratosphere.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.6
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• pp.759-771
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• 2004

This study analyzed concentrations of volatile organic compounds (VOCs) produced from incineration of plastic wastes at $600^{\circ}C$. The plastic wastes used in this study included polyethyleneterephthlate (PETE), high density polyethylene (HOPE), polyvinyl chloride (PVC), low density polyethylene (LOPE), polypropylene (PP), polystyrene (PS) and other. Plastic wastes were heated from room temperature upto $600^{\circ}C$ providing the compressed air inside of a small-scale electric furnace for 90 minutes and then they were oxidized (incinerated) for 60 minutes at $600^{\circ}C$ maintaining the same air supply. VOCs emitted from the incineration process were sampled using an air sampling pump and Tedlar air bags for 150 minutes and then the components and concentrations of the VOCs were analyzed by a GC-MS. The most prominent chemical structure of the VOCs obtained from the incineration process of the HOPE, LOPE and PP, which include ethylene groups in their main chains, was identified as aliphatic hydrocarbons such as 1-hexene. However, aromatics such as benzene were major chemical structure from the incineration of PETE, PVC and PS which include benzene rings in their main chains. This study estimated the total VOC production from the incineration of the plastic wastes based on the real plastic waste production and the emission factors. 64% and 27% of the total VOC emissions consisted of aliphatic hydrocarbons and aromatics, respectively, which have double bonds within their molecular structure and thus a high ground level ozone formation potential.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.835-839
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• 2011

The characteristics of torch-type atmospheric pressure plasma and its sterilization effects have been analyzed. The length of plasma flame was varied with the level of applied voltage and the mixture gases composed of argon and oxygen. The effect of plasma flame on the temperature increase of surface treated was limited to $43^{\circ}C$ as a maximum temperature under exposing time of 10 min. The sterilization for E. coli was strongly affected by the applied voltage, the oxygen ratio in the mixture gas and the treatment time. At a high concentration of ozone, the increase of treatment time under the direct contact with plasma flame yields to maximize the effect of the sterilization on E. coli.

• Environmental and Resource Economics Review
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• v.30 no.2
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• pp.207-235
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• 2021

This paper examines the effects of ambient air pollution by ozone and particulate matter on traveling by mode of transport. We estimate the SUR model of travel time by different modes of transportation using individual level data of travel diaries. We find that, as air pollution levels rises, traveling by privately-owned vehicles increases but traveling by bus decreases. Our results also show that, when an air quality alert is issued, bus traveling increases in an effort to reduce pollution levels, but traveling by own car does not change and traveling by train declines. This suggests that alert programs may not be highly effective in reducing air pollution emissions from vehicles because voluntary switching to public transportation induced by air quality alerts is outweighed by individual effort of avoiding exposure to pollution.

• Journal of the Korean Chemical Society
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• v.60 no.6
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• pp.402-409
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• 2016

Thin films of lead sulfide colloidal quantum dots (CQDs) of 2.8 nm in diameter are fabricated and their surfaces are passivated by 3-mercaptopropionic acid (MPA) ligand or hybrid type ($MPA+CdCl_2$) ligand, respectively. The changes in valence band electronic structure and atomic composition of each PbS CQD film upon post-treatment such as air, N2 annealing or UV/Ozone have been studied by photoelectron spectroscopy. The air annealing makes the CQD fermi level to move toward the valence band leading to "p-type doping" regardless of ligand type. The UV/Ozone post-treatment generates $Pb(OH)_2$, $PbSO_x$ and PbO on both CQD surfaces. But the amount of the PbO has been reduced in hybrid type ligand case, especially. That is probably because the extra Pb cations in (111) surface are additionally passivated by $Cl_2$ ligand, which limits the reaction between the Pb cation and ozone.

• Journal of the Korean earth science society
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• v.23 no.8
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• pp.683-696
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• 2002

In this work. we investigated the ozone data sets that exceeded ambient air quality standards from 31 air quality monitoring stations dispersed across the Seoul metropolitan city during the period covering 1990 and 2000. To specifically describe spatial dependency of high level O$_3$ occurrence, we grouped our data into four different geographical ozone exceedance is much longer in SW than the other three sectors. When we compared the exceedance data in terms of occurrence frequency, the month of maximum frequency differed slightly among different sectors. Examination of long-term exceedance trend indicated that its frequency increased continuously from all sectors over the past years, although slightly opposite patterns existed in their absolute values. Most importantly, its peak occurrence frequency seemed to center in very recent years such as 1998 (NE sector) and 2000 (ail pattern sectors except NE). Consequently, we were able to describe the existence of certain patterns of ozone exceedance data sets in terms of both temporal and spatial scales.