• Journal of Korean Society of Environmental Engineers
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• v.31 no.8
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• pp.627-634
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• 2009

This study was done to find out the formation mechanism of chlorate by electrochemical process using chloride ion ($Cl^-$) as an electrolyte. Firstly, the effective factors such as pH and initial chloride concentration were figured out to see the formation property of chlorate during electrolysis. And the relation of free chlorine, and mixed oxidants such as OH radical and ozone with chlorate were estimated to concretize the formation mechanism. As a result, it was found that the major reaction of chlorate formation would be electrochemical reaction with free chlorine, and also the direct oxidation of chloride ion and the reaction by OH radical were participated in the formation of chlorate. Moreover, it was observed that formed chlorate was oxidized to perchlorate. Lastly, the optimum condition was recommended by comparing free chlorine with chlorate concentration during the electrochemical process with the different electrode separation.

• Journal of Korean Society on Water Environment
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• v.33 no.2
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• pp.170-180
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• 2017

The study used jet water flow, ultra-sonication and ozonation system units to investigate impact of the unit components on water quality of stagnant Yeo-cheon River reach, Korea. Samples were collected at six locations, before operation and after 1, 3 and 6 hrs of operation. By operating the water flow unit only, dissolved oxygen increased as high as 90% after 3 hr at 25 m downstream of the device and Chl-a was reduced by 80%. Incorporating sonication, greater than 80% of Chl-a was removed even at 100 m distance from the device. Besides, total dissolved phosphorus was reduced from an average value of $420({\pm}70){\mu}g/L$ before ultrasonic irradiation to $160({\pm}40){\mu}g/L$ after the treatment. Releasing ozone into the flow with sonication, Chl-a was considerably removed from the water column and ammonia nitrogen was also decreased to average value of $20{\mu}g/L$ from $60{\mu}g/L$. However, as only $3{\ast}10^{-3}mg/L$ of ozone was used for safety purpose and due to brief reaction time it takes, effect of integrating ozone to the system covered limited area. Generally, combining sonication to jet flow is promising in preventing algal bloom formation since it has effectively removed Chl-a from the water column.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.4
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• pp.395-407
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• 2007

Disinfection by-products(DBPs) are formed through the reaction between chlorine and natural organic matter(NOM) in water treatment. For reducing the formation of chlorinated DBPs in the drinking water treatment, there is a need to evaluate the behavior of NOM fractions and the occurrence of DBPs for each fraction. Among the six fractions of NOM, the removal of HPOA and HPIN got accomplished through coagulation and sedimentation processes. Advanced water treatment processes were found to be most significant to remove the HPOA and HPON. It was found that HPOA made the most THMFP level than any other fractions and HPIA and HPOA formed higher HAAFP. The fraction of NOM with MW less than 1k Da was 32.5~54.3% in intake raw water. Mostly the organic matter with MW more than 1k Da was removed through coagulation and sedimentation in the drinking water treatment processes. In case of advanced water treatment processes, the organic matter with MW 1k~100k Da decreased by means of ozone oxidation for high molecular weight substances. As the result low molecular organic matter increased. In the BAC and GAC processes, the organic matter with MW less than 100k Da decreased.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2000.11a
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• pp.104-105
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• 2000

High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, T$_{sub}$, and ozone gas pressures, PO$_3$. The correlation diagrams of the BSCCO phases appeared against T$_{sub}$ and PO$_3$are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 phases as well as Bi2212 one come out as stable phases depending on T$_{sub}$ and PO$_3$. From these results, the thermodynamic evaluations of ΔH and ΔS which are related with Gibbs'free energy change for single Bi2212 or Bi2223 phase are performed.ormed.i2212 or Bi2223 phase are performed.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08b
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• pp.1415-1418
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• 2007

Electronic and structural properties of the interfaces formed by pentacene deposited on a polymer-based dielectrics are investigated by electron spectroscopy, atomic force microscopy, and water contact angle measurement. There is strong influence of surface treatment of the polymer dielectrics on the energy level alignment and the surface topography upon the pentacene deposition.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.1
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• pp.64-68
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• 2001

High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, T$\_$sub/, and ozone gas pressures, PO$_3$. The correlation diagrams of the BSCCO phases appeared against T$\_$sub/ and PO$_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 phases as well as Bi2212 one come out as stable phases depending on T$\_$sub/ and PO$_3$. From these results, the thermodynamic evaluations of ΔH and ΔS, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase are performed.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.8
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• pp.736-741
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• 2002

Phase intergrowth some kinds of the $Bi_2Sr_2Ca_{n-1}Cu_nO_y$ phases is observed in the thin film fabrication at ultralow co-deposition with multi targets by means of ion beam sputtering. The molar fraction of the Bi2212 phase in the mixed crystal of the grown films is investigated as a function of the applied ozone pressure and the substrate temperature. The activation energy for the phase transformation from the Bi2201 to the Bi2212 is estimated in terms of the Avrami equation. This study reveals that the formation of a liquid phase contributes significantly to the construction of the Bi2212 phase in the thin films, differing from the bulk synthesis.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07a
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• pp.490-493
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• 2002

Phase intergrowth some kinds of the Bi$_2$Sr$_2$Ca$\_$n-1/Cu$\_$n/O$\_$y/ phases is observed in the thin film fabrication at ultralow co-deposition with multi targets by means of ion beam sputtering. The molar fraction of the Bi2212 phase in the mixed crystal of the grown films is investigated as a function of the applied ozone pressure and the substrate temperature. The activation energy for the phase transformation from the Bi2201 to the Bi2212 is estimated in terms of the Avrami equation. This study reveals that the formation of a liquid phase contributes significantly to the construction of the Bi2212 phase in the thin films, differing from the bulk synthesis.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.304-307
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• 2001

High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, $T_{sub}$, and ozone gas pressures, $PO_3$. The correlation diagrams of the BSCCO phases appeared against $T_{sub}$ and $PO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi220l and Bi2223 phases as well as Bi2212 one come out as stable phases depending on $T_{sub}$ and $PO_3$. From these results, the thermodynamic evaluations of ${\Delta}H$ and ${\Delta}S$ S, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase are performed.

• Proceedings of the KIEE Conference
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• 2002.07c
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• pp.1707-1709
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• 2002

Ionic wind may be produced by DC corona discharges. In this work, the electrical effect has studied to evaluate applicability in fields of electrostatic cooling, ozone generation, electrostatic precipitation, heat transfer, air flow modification, and etc. The ionic wind velocity was measured as a function of the distance of pin to plate and the diameter of punched hole. The pin to punched-plate electrode generates airflow from pin to plate and the flow direction is controlled by the hole size of punched-plate, input voltage and distance between two electrodes. As a consequence, the ionic wind velocity is nearly proportional to the applied voltages and ranges from 1 to 3 m/sec.