Characterization of NOM Behavior and DBPs Formation in Water Treatment Processes

정수처리공정에서 NOM 거동과 소독부산물 발생특성

  • 김상은 (서울특별시 상수도연구원) ;
  • 구윤희 (서울시립대학교 환경공학부) ;
  • 유명진 (서울시립대학교 환경공학부) ;
  • 장현성 (서울특별시 상수도연구원) ;
  • 이수원 (서울특별시 상수도연구원) ;
  • 한선희 (서울특별시 상수도연구원)
  • Received : 2007.02.02
  • Accepted : 2007.08.13
  • Published : 2007.08.15

Abstract

Disinfection by-products(DBPs) are formed through the reaction between chlorine and natural organic matter(NOM) in water treatment. For reducing the formation of chlorinated DBPs in the drinking water treatment, there is a need to evaluate the behavior of NOM fractions and the occurrence of DBPs for each fraction. Among the six fractions of NOM, the removal of HPOA and HPIN got accomplished through coagulation and sedimentation processes. Advanced water treatment processes were found to be most significant to remove the HPOA and HPON. It was found that HPOA made the most THMFP level than any other fractions and HPIA and HPOA formed higher HAAFP. The fraction of NOM with MW less than 1k Da was 32.5~54.3% in intake raw water. Mostly the organic matter with MW more than 1k Da was removed through coagulation and sedimentation in the drinking water treatment processes. In case of advanced water treatment processes, the organic matter with MW 1k~100k Da decreased by means of ozone oxidation for high molecular weight substances. As the result low molecular organic matter increased. In the BAC and GAC processes, the organic matter with MW less than 100k Da decreased.

Keywords

References

  1. Amy G., Siddiqui M., Ozekin K. Zhu H.W. (1998) Empirically based models for predicting chlorination and ozonation by-product, USEPA Office of Groundwater and Drinking water, Cincinnati, OH
  2. APHA, AWWA, WEF (1998) Standard Methods for the examination of water and wastewater - 20th, United Book press
  3. Croue J,P., Violleau D., Labouyrie L. (2000) Disinfection byproduct formation potentials of hydrophobic and hydrophilic natural organic matter fractions: a comparison between a lowand a high-humic water, Natural organic matter and disinfection by-products; characterization and control in drinking water, American chemical society, pp. 139-153
  4. Gang D., Clevenger T.E., Banerji S.K. (2002) Relationship of chlorine decay and THMs formation to NOM size, J. of Hazardous Materials, 3909,pp 1-12
  5. Hem L.J. and Efraimsen H. (2001) Assimilable organic carbon in molecular weight fractions of natural organic matter, Wat. Res., 35(4), pp. 1106-1110 https://doi.org/10.1016/S0043-1354(00)00354-7
  6. Hwang C.J., Sclimenti M.J., Kransner S.W. (2000) Disinfection by-product formation reactivities of natural organic matter fractions of low-humic water, Natural organic matter and disinfection by-products: characterization and control in drinking water, American Chemical Society, pp. 173-187
  7. Jegatheesan V., Lamsal P.R., Visvanathan C., Ngo H.H., Shu L. (2002) Effect of natural organic compounds on the removal of organic carbon in coagulation and flocculation processes, Wat. Sci. & Technol.: Water supply, 2(5-6), pp. 473479.
  8. Kilduff J.E., Mattaraj S., Wigton A., Kitis M., Karanfil T. (2004) Effects of reverse osmosis isolation on reactivity of naturally occurring dissolved organic matter in physicochemical processes, Wat. Res., 38, pp. 1026-1036 https://doi.org/10.1016/j.watres.2003.10.049
  9. Korshin G.V., Li C.W., Benjamin M.M. (1997) Monitoring the properties of natural organic matter through UV spectroscopy: a consistent theory, Wat. Res., 31(7), pp. 1787-1795 https://doi.org/10.1016/S0043-1354(97)00006-7
  10. Leenheer J.A. (1981) Comprehensive approach to preparative isolation and fractionation of dissolved organic carbon from natural waters and wastewaters, Eviron. Sci. & Tech., 15(5), pp. 578-587 https://doi.org/10.1021/es00087a010
  11. Singer, P.C. (2002) Occurrence of haloacetic acids in chlorinated drinking water, Wat. Sci. Tech.: Water supply, 2(56), pp.487-492 https://doi.org/10.2166/ws.2002.0208