• 한국대기환경학회지
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• 제13권1호
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• pp.41-49
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• 1997

Status of photochemical air pollution in the Greater Seoul Area (GSA) between 1990 and 1995 was assessed in terms of frequency distributions, number of days exceeding standards, average concentration and meteorological effects. In Seoul compared with other areas in Korea, daily maximum concentration was higher but average concentration was not so high due to lower daily minimum from April to October. The top 5th percentile was high especially in summer season. Average number of days exceeding 100 ppb at monitoring stations in GSA was highest in 1994, the hottest year, but it was only 4 days a year. Mean meteorological pattern of high ozone days could be summarized as low wind speeds, high temperatures, strong solar radiation, and low precipitation. Westerlies were more frequent on high ozone days and at Pangi station located in the eastside of GSA, both number of high ozone days and average concentration were high. Effect of precursor transport on the rise of ozone concentration was, however, not consistently important on the whole in GSA.

• 한국환경과학회지
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• 제21권9호
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• pp.1097-1113
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• 2012

Ozone is the secondary photochemical pollutant formed from ozone precursor such as nitrogen dioxide and non-methane volatile organic compounds(VOCs). The ambient concentration of ozone depends on several factors: sunshine intensity, atmospheric convection, the height of the thermal inversion layer, concentrations of nitrogen oxides and VOCs. Busan is located in the southeast coastal area of Korea so the ozone concentration of Busan is mainly affected from the meteorological variables related to the sea such as sea breeze. In this study the ozone concentrations of Busan in 2008~2010 were used to analyse the cause of the regional ozone difference in eastern area of Busan. The average ozone concentration of Youngsuri was highest in Busan however the average ozone concentration of Gijang was equal to the average ozone concentration of Busan in 2008~2010. The two sites are located in eastern area of Busan but the distance of two sites is only 9km. To find the reason for the difference of ozone concentration between Youngsuri and Gijang, the meteorological variables in two sites were analyzed. For the analysis of meteorological variables the atmospheric numerical model WRF(Weather Research and Forecasting) was used at the day of the maximum and minimum difference in the ozone concentration at the two sites. As a result of analysis, when the boundary layer height was lower and the sea breeze was weaker in Youngsuri, the ozone concentration of Youngsuri was high. Furthermore when the sea breeze blew from the south in the eastern area of Busan, the sea breeze at Youngsuri turned into the southeast and the intensity of sea breeze was weaker because of the mountain in the southern region of Youngsuri. In that case, the difference of ozone concentration between Youngsuri and Gijang was considerable.

• Asian Journal of Atmospheric Environment
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• 제2권1호
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• pp.47-53
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• 2008

In this study, we analyzed how ozone pollution could be differently measured and how these different measures varied year to year and across the ten most populated cities in the United States, from 1980 to 2000. Although peak values of ozone concentration have been significantly reduced in most polluted U.S. cities for the last 20 years, the annual average values of ozone concentration have not been lowered as much as peak values. Ozone concentration data for each city shows a unique pattern of distribution, central tendency, and also there is a wide variation among different ozone measures. Two different cities with the same annual mean concentration of ozone can experience very different distributions of ozone concentration within a year. Ozone measures also show a wide margin of variability as they are estimated from different ozone monitoring sites within each city. Ozone pollution statistics can be largely varied depending on the choice of measures, monitoring sites, and averaging time period. EPA's new ozone standard of 0.08 ppm averaged over an eight-hour appears to be more stringent than the current maximum ozone standard of 0.12 ppm averaged over one hour.

• 한국환경과학회지
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• 제11권12호
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• pp.1253-1259
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• 2002

This study analyzes the surface ozone, NO and $NO_2$ concentration data from 1997 to 1999 in Daegu. It investigates effect on precursor during high-ozone episode days. The high-ozone episode is defined when a daily maximum ozone concentration is higher than 100 ppb(ambient air quality standard of Korea) in at least one station among six air quality monitoring stations. The frequency of episodes is 13 days(33 hours). The frequency is the highest in May and September, and the area with the highest frequency is Nowondong and Manchondong. The average value of daily maximum ozone concentration with high ozone episode is 81.6 ppb, and that of 8-hour average ozone concentration is 58.6 ppb. It means that ozone pollution is continuous and wide-ranging in Daegu. The daily variation of NO, $NO_2$ and $O_3$ in high-ozone episodes are inversely proportional one another. Nowondong an industrial area, is affected by pollutants that are emitted from the primary sources, while Manchondong a residential area, is affected by the advection of $O_3$ or by the primary pollutants like VOCs.

• 한국대기환경학회지
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• 제19권5호
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• pp.611-619
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• 2003

Characteristics of the ozone concentrations in Seoul were analyzed for the data between May and September from 1996 to 2000. Observation data from 27 stations in Seoul are used. Among the results from 27 stations, representative results from 2 stations (City hall and Gwanak representing downtown and background areas of Seoul, respectively) are presented. The 24-hour average ozone concentrations of Gwanak (28.6 ppb) are higher than City hall (14.9 ppb). The 24-hour average ozone concentrations on Sunday are higher than other days at both sites. During weekday, the 24-hour average ozone concentrations on Wednesday are higher than other days. Although the mean of the I-hour daily maximum ozone concentrations at Gwanak is higher than City hall, the . ozone concentrations above 95th percentile at City hall are higher than Gwanak. As a result, the number of days on which the 1 - hour ozone concentration exceeding 100 ppb and 120 ppb at Gwanak (17 and 3) are lower than City hall (29 and 9). To sum up, both sites are VOCs limited region and the mean ozone concentration in Gwanak is higher because of the lower N0$_2$ concentration. But high ozone cases occur more frequently in City hall when conditions are right.

• 한국대기환경학회지
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• 제2권1호
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• pp.73-79
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• 1986

This study is carried out to determine the concentration of the ozone and the factors affecting the variation of ozone concentration in the ambient air in Seoul. The one-hour average concentration of ozone $(O_3)$, sulfur dioxide $(SO_2)$, nitrogen oxides (NO and $NO_2$), suspended particulate (TSP), carbon monoxide (CO) and non-methane hydrocarbon (NMHC) at 5 sites in Seoul measured from September to October in 1983 and 1984 were analysed statistically along with meteorological data for the same period. The results were as follows; 1. The average concentrations of ozone at 5 sites during the period ranged from 3.3 to 9.1 ppb, they were below 20 ppb of the ambient air quality standard of Korea. 2. The maximum hourly concentration of ozone occurred between 2 and 3 p.m. in a day and concentration at night were very low but higher concentrations were observed at around 4 a.m. 3. The concentration ratio between NO and $NO_2$ in Seoul was relatively lower than that for the cities of foreign countries reported so far. 4. The ozone concentration has negative correlationships with the concentration of other primary pollutants$(SO_2, NO, NO_2, CO and NMHC)$ in simple regression analyses. 5. The ozone concentration was positively correlated to wind speed, temperature and insolation intensity but negatively correlated to relative humidity. 6. Stepwise multiple regression analysis of the ozone concentration to the pollutants and meteorological factors indicate that insolation intensity and $[NO_2]/[NO]$ were the primary influencing factors. 7. The three factors of insolation intensity, $[NO_2]/[NO] and NO_2$ concentration had a significant combined effect on the ozone concentration $(r^2 = 0.47-0.57)$.

• 한국대기환경학회지
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• 제16권6호
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• pp.607-623
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• 2000

Major trends of ozone concentration variations in Korea were investigated by using observation data from around 100 stations for the period of 1991∼1997. In addition, important regulating those variations were inferred. Three measures such as the number of days exceeding 80ppb, the 95th percentile of daily maxima, and the annual average concentration were used for the analysis of multi-scale ozone concentration variations. Three areas in the southwest (Sosan, Mokpo, and Cheju) of which monitoring has been operated since 1995 showed the highest annual average concentrations over; this was noted because of the high annual average in the Yosu area in the early 1990s. Large increases in annual average concentrations were observed along the relatively cleaner areas connecting Kangnung and Kwangju(northeast to southwest), in contrast to polluted areas connecting Seoul and Pusan(northeast to southeast). Both the number of exceedance days and the daily maximum concentration were nearly constant in the Greater Seoul Area in spite of interannual flucturations associated with year-to-year changes in air temperature. Within the Greater Seoul Area, all three measures usually showed the same trend; they decreased in the middle and west and increased in the east and northeast. All three measures including the number of exceedance days increased largely at Sillim where the average concentration was high but no exceedance days were recorded in the early 1999s, Nationwide ozone concentration variations appear to be determined by the competitive influence of long-range transport and local urban emissions, Within the city including the Greater Seoul Area, changes in emission which accompany changes in population and in the number if vehicles ( in the process of urban development) were found to be important components of ozone concentration variations.

• 한국대기환경학회지
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• 제15권6호
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• pp.747-755
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• 1999

Effects of precipitation and cloud cover on high ozone days are examined by investigating the precipitation and average cloud cover before the ozone peak time within a day. High ozone days above 100 ppb in the Greater Seoul Area(GSA) for the ozone season from May to September are chosen for the analyses in terms of the surface meteorological data during 1990~1997. The result shows that the effect of precipitation on the rise of ozone concentration is definitely negative so that ozone concentration could not rise above 100ppb immediately after precipitation. But, the effect of cloud cover is associated with the variations of other meteorological parameters. The number of high ozone days with "zero" cloud cover is rather less than that with cloud cover of 1 to 4 since temperature is usually lower in "zero" cloud cover days. Furthermore, ozone concentration can rise above 100ppb even with full cloud cover when the wind is weak and the temperature is high.temperature is high.

• 한국대기환경학회지
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• 제12권1호
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• pp.55-66
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• 1996

One-hour average concentrations of ground-level ozone from around 80 monitoring stations in Korea during 1991 to 1993 were analyzed to examine characteristics of the ozone concentration variations. Two types of variations were observed: one was for the Capital area typified by Kwanghwmun, and the other was for the south and east seashore region typified by Tongkwangyang. In the Capital area including Seoul, Inchon, Kyonggi-do and Chunchon, mean daily 1-hout maximum was the highest in June following high monthly averages in spring. But frequent precipitation prevented further rise of daily maximum in July and August even though there were frequent episodes of high concentration exceeding 100ppb. In the south and east seashore region, average concentration was the highest throughout the year, and daily maximum and minimum simultaneously changed owing to small contributions from photochemical reactions. The typical annual variation was spring peak, summer down, and fall rise. Spring peak accompanied an usual observations of background variations at remote sites in the Northern Hemisphere. Riess of average and daily maximum with lower daily minimum in fall were attributable to photochemical reactions.

• 환경위생공학
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• 제21권1호
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• pp.58-65
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• 2006

This study is measured in at ozone concentrated places in school and outside of school where places that use copy machine and the others do not use one. Library copy room, Search room, Y-Copy, J-copy, R-shop are the places using copy machines and Search room, K-apt, J-billiard hall are the opposite. The measurement was held three times a day-the morning, the afternoon and the evening-once for each at indoor and outdoor. 8 places were lower than domestic ozone concentration standard(0.06ppm). The indoor ozone concentration average was the highest in Search room of school and was the lowest in Library restroom. The outdoor ozone concentration average was the highest in J-billiard hall.