• Title/Summary/Keyword: oxygen transfer

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Effect of Ce0.9Gd0.1O1.95 as a promoter upon the oxygen transfer properties of MgMnO3-δ-Ce0.9Gd0.1O1.95 composite oxygen carrier materials for chemical looping combustion

  • Hwang, Jong Ha;Lee, Ki-Tae
    • Journal of Ceramic Processing Research
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    • v.20 no.1
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    • pp.18-23
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    • 2019
  • Chemical looping combustion (CLC) is a promising carbon capture and storage (CCS) technology whose efficiency and cost primarily relies on the oxygen carrier materials used. In this paper, gadolinium-doped ceria (GDC, Ce0.9Gd0.1O1.95) was added as a promoter to improve the oxygen transfer rate of MgMnO3-δ oxygen carrier materials. Increasing GDC content significantly increased the oxygen transfer rate of MgMnO3-δ-GDC composites for the reduction reaction due to an increase in the surface adsorption of CH4 via oxygen vacancies formed on the surface of the GDC. On the other hand, the oxygen transfer rate for the oxidation reaction decreased linearly with increasing GDC content due to the oxygen storage ability of GDC. Adsorbed oxygen molecules preferentially insert themselves into oxygen vacancies of the GDC lattice rather than reacting with (Mg,Mn)O to form MgMnO3-δ during the oxidation reaction.

HYDRAULIC ANALYSIS OF OXYGEN TRANSFER THROUGH AIR ENTRAINMENT IN RIPARIAN RIFFLES

  • Kim, Jin-Hong
    • Water Engineering Research
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    • v.4 no.3
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    • pp.127-139
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    • 2003
  • This paper presents the hydraulic analysis of the oxygen transfer through the air entrainment and the relationships between the efficiency of the oxygen transfer and the hydraulic parameters in the riparian riffles. Field survey on the pool-riffle formation of the river reach and the measurements of the oxygen transfer in the riffles were performed. Air entrainment occurred more frequently in the edged gravels rather than in the round and edgeless ones, and it was formed mainly from behind the trailing edges of the gravels. Oxygen transfer was found to be proportional to the flow velocity, the flow discharge, and the Froude number, but to be not closely related to the particle diameter. Average value of oxygen transfer in the riffles of study area was about 0.085, which shows good efficiency compared with results of smooth chute. Variation of the water level, which increases in proportion to the flow velocity and the flow discharge, seems to make the air entrainment more active, but has not been verified quantitatively. Relationships between the air entrainment and the variation of the water level must be considered in the further study.

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Oxygen Transfer Characteristics of an Ejector Aeration System

  • Yang, Hei-Cheon;Park, Sang-Kyoo
    • International Journal of Fluid Machinery and Systems
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    • v.5 no.1
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    • pp.10-17
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    • 2012
  • The objective of this study was to investigate the oxygen transfer characteristics of an ejector aeration system. In order to evaluate the oxygen transfer performance of the ejector aeration system, a comparative experiment was conducted on a conventional blower aeration system. The effect of entrained air flow rate and aerating water temperature on the oxygen transfer efficiency was investigated. The dissolved oxygen concentration increased with increasing entrained air flow rate, but decreased with increasing aerating water temperature for two aeration systems. The volumetric mass transfer coefficient increased with increasing entrained air flow rate and with increasing aerating water temperature for both aeration systems. The average mass transfer coefficient for the ejector aeration system was about 20% and 42% higher than that of the blower aeration system within the experimental range of entrained air flow rates and aerating water temperatures.

Selection of Oxygen Carrier Candidates for Chemical Looping Combustion by Measurement of Oxygen Transfer Capacity and Attrition Loss (산소전달량 및 마모손실 측정에 의한 매체순환연소용 산소전달입자 후보 선정)

  • KIM, HANA;PARK, JAEHYEON;BAEK, JEOM-IN;RYU, HO-JUNG
    • Journal of Hydrogen and New Energy
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    • v.27 no.4
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    • pp.404-411
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    • 2016
  • To select appropriate oxygen carrier candidates for chemical looping combustion, reduction characteristics of seven oxygen carriers were measured and discussed using three different reduction gases, such as $H_2$, CO, and $CH_4$. Moreover, attrition losses of those oxygen carriers also measured and compared. Among seven oxygen carrier particles, OCN703-1100 and NiO/bentonite particles showed higher oxygen transfer capacity than other particles, but these particles showed more attrition loss than other particles. C14 and C28 particles which used as cheap oxygen carriers in European country showed lower oxygen transfer capacity and less attrition loss. Based on the experimental results, we could select OCN717-R1SU, NC001, and N002 particles as candidates for future works because these oxygen carriers showed enough oxygen transfer capacity and good attrition resistance.

Oxygen Transfer in Microbial System (미생물 배양 시스템에서의 산소 전달)

  • 최동원
    • The Korean Journal of Food And Nutrition
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    • v.7 no.4
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    • pp.399-405
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    • 1994
  • Some method was introduced to explain oxygen transfer from broth to cell during aerobic microbe cultivation. It is explained by 5 steps that how desolved oxygen can reach to cell. Among these steps film resistance was the most important factor to describe oxygen transfer. Lumped model and distributed model was introduced to explain oxygen diffusion rate and oxygen consumption rate which occurs in the microbe pellet.

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Numerical study of oxygen transport characteristics in lead-bismuth eutectic for gas-phase oxygen control

  • Wang, Chenglong;Zhang, Yan;Zhang, Dalin;Lan, Zhike;Tian, Wenxi;Su, Guanghui;Qiu, Suizheng
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2221-2228
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    • 2021
  • One-dimensional oxygen transport relation is indispensable to study the oxygen distribution in the LBE-cooled system with an oxygen control device. In this paper, a numerical research is carried out to study the oxygen transport characteristics in a gas-phase oxygen control device, including the static case and dynamic case. The model of static oxygen control is based on the two-phase VOF model and the results agree well with the theoretical expectation. The model of dynamic oxygen control is simplified and the gas-liquid interface is treated as a free surface boundary with a constant oxygen concentration. The influences of the inlet and interface oxygen concentration, mass flow rate, temperature, and the inlet pipe location on the mass transfer characteristics are discussed. Based on the results, an oxygen mass transport relation considering the temperature dependence and velocity dependence separately is obtained. The relation can be used in a one-dimensional system analysis code to predict the oxygen provided by the oxygen control device, which is an important part of the integral oxygen mass transfer models.

The Oxygen Transfer and Oxygen Uptake in Antibiotic Fermentation using Streptomyces kanamyceticus (항생물질발효에서의 산소전달 및 흡수속도에 관한 연구)

  • Lee, Kye-Joon;Moo Bae
    • Microbiology and Biotechnology Letters
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    • v.10 no.3
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    • pp.223-226
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    • 1982
  • The aim of the present study was to assess the oxygen transfer rate and oxygen uptake rate in antibiotic fermentation. As a model study, cultures of Streptomyces kanamyceticus in a complex medium were analyzed to evaluate the oxygen transfer and uptake rates using oxygen balance technique. Quantitative evidence for the effect of oxygen transfer rate on the volumetric antibiotic production was clearly demonstrated. The oxygen uptake rates and the specific oxygen requirements were significantly changed with culture time. Those phenomena were indicative of biological turnover in the antibiotic fermentation.

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Oxygen Transfer Characteristics & Pure Oxygen Application Study on Circulation Flow Rate of the JLB (Jet Loop Bioreactor) (Jet 폭기 시스템의 순환유량에 따른 산소전달 특성 및 순산소 적용성 검토)

  • Park, Noh-Back;Song, Yong-Hyo;Pack, June-Gue;Jun, Hang-Bae
    • Journal of Korean Society on Water Environment
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    • v.25 no.6
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    • pp.896-901
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    • 2009
  • In this study, in order to apply the air and pure oxygen in the Jet Loop Reactor (JLB) in which the oxygen transfer rate is high, differentiate the operation mode according to each air flowrate and liquid flowrate and investigate the oxygen transfer characteristic, an experiment was carried out. The oxygen concentration with the air flowrate ($Q_g$) and liquid flowrate ($Q_L$) was identical but the oxygen transfer coefficient ($K_L{\cdot}a$) is linear depending on degree of two factors. The width of an increase is small in $0.1min^{-1}$ when the air flowrate is 0.2 L/min with increasing the liquid flowrate. Whereas, the increment was exposed to be very high for $1.5min^{-1}$ when the air flowrate was 5 L/min. In the experiments using the pure oxygen, it was 30 mg/L of oxygen concentration finally and it was 3.5 times than using the air. But the time reached the saturated concentration was similar to using the air, and $K_L{\cdot}a$ was similar to using the air too. Analysis between two independent variable and oxygen transfer of the correlation is the same model like $K_L{\cdot}a={0.0161Q_L}^{1.5371}{Q_g}^{0.5433}$ using with coefficient non linear regression analysis. It was resulted that the liquid flowrate were approximately three times than air flowrate on effect to oxygen transfer rate.

Treatment of Food Waste Leachate using Pure-Oxygen Jet Loop Reactor(JLR) (순산소 Jet 폭기 시스템을 이용한 음폐수 처리 특성)

  • Yoon, Ae-Hwa;Park, Noh-Back;Bae, Jong-Hun;Jun, Hang-Bae;Kwon, Young-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.6
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    • pp.763-773
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    • 2010
  • The removal efficiencies and a total oxygen transfer coefficient for food waste leachate(FWL) were estimated by using Jet Loop Reactor(JLR). Pure oxygen was used instead of air to improve oxygen concentration in the JLR for high total chemical oxygen demamd(TCOD) in FWL. In JLB, in order to examining the oxygen transfer characteristic, the circulation flowrate and oxygen flowrate were controlled with 7~10 L/min(1.5 L/min interval) and 0.2~0.5 L/min (0.1 L/min interval) and we experimented according to the each condition. As a result, Oxygen uptake rate(OUR) and oxygen transfer rate could be maximized than the oxygen flowrate to increase the circulation flowrate. In addition, it determined that JLR using the pure oxygen which can obtain the greatest oxygen transfer rate as it was the high-concentration organic wastewater like the food waste leachate through the continuous experiment was appropriate.

Mixed Flow and Oxygen Transfer Characteristics of Vertical Orifice Ejector (수직 오리피스 이젝터의 혼합유동 및 산소전달 특성)

  • Kim, Dong Jun;Park, Sang Kyoo;Yang, Hei Cheon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.1
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    • pp.61-69
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    • 2015
  • The objective of this study is to experimentally investigate the mixed flow behaviors and oxygen transfer characteristics of a vertical orifice ejector. The experimental apparatus consisted of an electric motor-pump, an orifice ejector, a circulation water tank, an air compressor, a high speed camera unit and control or measurement accessories. The mass ratio was calculated using the measured primary flow rate and suction air flow rate with experimental parameters. The visualization images of vertically injected mixed jet issuing from the orifice ejector were qualitatively analyzed. The volumetric oxygen transfer coefficient was calculated using the measured dissolved oxygen concentration. At a constant primary flow rate, the mass ratio and oxygen transfer coefficient increase with the air pressure of compressor. At a constant air pressure of the compressor, the mass ratio decreases and the oxygen transfer coefficient increases as the primary flow rate increases. The residence time and dispersion of fine air bubbles and the penetration of mixed flow were found to be important parameters for the oxygen transfer rate owing to the contact area and time of two phases.