• Title/Summary/Keyword: oxygen rich combustion

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Structure of Edge Flame in a Methane-Oxygen Mixing Layer (메탄/순산소 혼합층에서 edge flame의 구조)

  • Choi, S.K.;Kim, J.;Chung, S.H.;Kim, J.S.
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.149-156
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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Combustion Characteristics of Minco Sub-bituminous Coal at Oxy-Fuel Conditions (민코 아역청탄의 순산소 연소특성)

  • Kim, Jae-Kwan;Lee, Hyun-Dong;Jang, Seok-Won;Kim, Sung-Chul
    • Journal of the Korean Society of Combustion
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    • v.14 no.2
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    • pp.1-9
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    • 2009
  • New way to effectively capture $CO_2$ in coal fired power plant is the combustion of coal using oxy-fuel technology. Combustion characteristics of Minco sub-bituminous coal at oxy-fuel conditions using TGA and drop tube furnace (DTF) were included activation energy about the char burnout, volatile yield and combustion efficiency of raw coal, the porosity of pyrolyzed char and fusion temperature of by-product ash. TGA result shows that the effect of $CO_2$ on combustion kinetics reduces activation energy by approximately 7 kJ/mol at air oxygen level(21% $O_2$) and decreases the burning time by approximately 16%. The results from DTF indicated similar combustion efficiency under $O_2/CO_2$ and $O_2/N_2$ atmospheres for equivalent $O_2$ concentration whereas high combustion efficiency under $O_2/N_2$ than $O_2/CO_2$ was obtained for high temperature of more than $1,100^{\circ}C$. Overall coal burning rate under $O_2/CO_2$ is decreased due to the lower rate of oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. By-product ash produced under $O_2/CO_2$ and $O_2/N_2$ was similar IDT in irrelevant to $O_2$ concentration and atmospheres gas during the coal combustion.

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Prediction of Biodiesel Combustion, CO and NOX Emission Characteristics in Accordance with Equivalence Ratio (당량비 변화에 따른 바이오디젤 연소 및 CO, NOX 생성 특성 예측)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of the Korean Society of Combustion
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    • v.21 no.1
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    • pp.1-7
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    • 2016
  • This study was performed to provide the basic information of the combustion, CO and $NO_X$ characteristics of biodiesel in accordance with equivalence ratio. The closed homogeneous reactor model used for the analysis. The analysis conditions were set to 900 K of the initial temperature, 20 atm of initial pressure and equivalence ratio was changes from 0.6 to 1.4. The results of analysis were predicted and compared in terms of combustion temperature, combustion pressure, CO and $NO_X$ emissions. The results of combustion characteristics showed that ignition delay was decreased and the combustion temperature and combustion pressure was increased in accordance with equivalence ratio. CO emission was decreased in lean condition(${\Phi}$ < 1.0), however, CO emission was increased in rich condition(${\Phi}$ > 1.0) because oxygen supply insufficient. $NO_X$ emission showed the largest amount in condition 0.8 of equivalence ratio because the oxygen concentration was sufficient.

Numerical Analysis on Cooling Characteristics of Oxidizer-Rich Preburner (산화제 과잉 예연소기 냉각 성능 수치 해석)

  • Lee, Seon-Mi;Ha, Seong-Up;Lee, Soo Yong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.3
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    • pp.67-75
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    • 2013
  • The numerical analysis for the verification of preburner's cooling characteristics applying to kerosene-LOx rocket engine has been fulfilled. The distribution of combustion gas properties in primary combustion zone was calculated by the mixture ratio based on head injector arrangement, the properties of oxygen flowing in wall channels as coolant were applied under real-gas conditions, and multi-phase mixing model was employed to calculate the mixing process of primary combustion zone with liquid oxygen which was used for wall cooling. The results of numerical analysis were compared with the experimental results, hence thermo-physical properties in cooling channels and a combustor could be quantitatively identified.

Study on Pressure Fluctuations Observed in Combustion of Oxygen-Rich Preburners (산화제 과잉 예연소기 연소에서 관찰되는 압력섭동에 대한 연구)

  • Seo, Seonghyeon;Kang, Sang Hun;Lee, Soo-Yong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.2
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    • pp.122-127
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    • 2013
  • The paper includes the analytic results of pressure fluctuation data from the combustion of an oxidizer-rich preburner applicable to high-performance, closed-cycle liquid rocket engine systems. The combustion experiments went through two different steps of a chamber pressure during single run. Self-excited pressure fluctuations with a frequency of 78 Hz were observed only at the relatively low chamber pressure condition. These pressure fluctuations are regarded as a bulk mode. The intensity of pressure fluctuations by a root-mean-square value is 13.3% normalized by the chamber static pressure and no pressure excitation was observed at the design pressure condition. The bulk mode has an identical phase across the inside of the chamber and reveals the similar characteristics to the Helmholtz resonator.

Study on Combustion Gas Properties of a Fuel-Rich Gas Generator (연료 과농 가스발생기의 연소 가스 물성치에 관한 연구)

  • 서성현;최환석;한영민;김성구
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.10
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    • pp.56-60
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    • 2006
  • It is essential to predict thermodynamic properties of combustion gas with respect to a propellant mixture ratio for the development of a gas generator for a liquid rocket engine. The present study shows the temperature measurement of exit combustion gas as a function of a mixture ratio through the series of combustion tests of a fuel-rich gas generator with liquid oxygen and Jet A-1. The measurements of dynamic and static pressures, and combustion gas temperatures allowed the estimation of thermodynamic properties like a specific heat ratio, a gas constant, and a constant pressure specific heat of the combustion gas. The comparison of the experimental results with predictions made by interpolation parameters obtained from the modification of the chemical equilibrium code indicates that the interpolation method calibrated using the temperature measurements can be utilized as an effective tool for the initial design of a fuel-rich gas generator.

NOx Reduction Characteristics of Air Staging Burner for Pulverized-coal Combustion (공기 다단공급식 미분탄 버너의 NOx 저감 특성)

  • Park, Chu-Sik;Kim, Sung-Won;Choi, Snag-Il
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.153-160
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    • 2001
  • The combustion test used DTF was performed to obtain the characteristics of NOx emission and reduction. In this test, major factor of NOx emission was a stoichiometric air ratio. At the onset of combustion to be rich oxygen, NOx was produced rapidly. Optimum condition for NOx reduction was formed under about AR:0.7 in the combustion test of Alaska coal. Investigations were undertaken with 200KW(th) test combustor. In combustion test, the major variables were coal feed ratio of center/outer, stoichiometric air ratio at the onset of combustion. The lowest NOx emission, 182ppm(6% O2 base), was achieved at about AR:0.6 of the first combustion stage with low NOx burner. Also, unburned carbon content of char collected in this combustion condition was about 1wt%.

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Constant Volume Premixed Combustion Characteristics of Dimethyl Ether and LPG Fuel (DME와 LPG 연료의 정적 예혼합 연소특성)

  • 김태권;임문혁;장준영
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.5
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    • pp.83-88
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    • 2003
  • Measurements on the combustion characteristics of dimethyl ether(DME:$CH_3$O$CH_3$) as compared with LPC in constant volume combustion chamber have been conducted. The DME is a good alternative fuel having oxygen component in fuel. To elucidate the combustion characteristics of dimethyl ether as a fuel, the combustion pressures, combustion durations, and pollutants(NOx, $CO_2$, CO) are measured with equivalence ratios(Ø), and initial Pressures of fuel-air mixture. In the case of DME, the NOx concentration peaks in leu flame Ø = 0.85~0.9, and $CO_2$ concentration peaks at Ø=1.1, while the CO concentration abruptly rises at the condition of fuel-rich mixtures.

Study of the Ignition with TEAL for an Oxygen Rich Preburner (산화제 과잉 예연소기를 위한 TEAL 점화연구)

  • Moon, In-Sang;Moon, Il-Yoon;You, Jae-Han;Lee, Sun-Mee;Lee, Soo-Yong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.97-100
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    • 2011
  • It is critical to set up the starting sequence of liquid rocket engines because not carefully arranged process can lead the engine damages. Thus, many efforts were made to prevent the hard start at the ignition. Hypergolic fuels are frequently used to ignite LRE and TEAL, one of the hypergolic fuel is also used for kerosene-LOx LRE ignition. However, since we are still lack of experiences igniting oxygen rich preburners of the staged combustion cycle engines, it would be helpful to estimate the TEAL ignition phenomena before the actual tests.

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A Study on Comparisons Between Combustion Temperatures Calculated by Two-Region Model and Measured by Two-Color Method in Premixed Constant-Volume Combustion (정적 예혼합기 연소에 있어서 2영역 모델 및 2색법에 의한 연소온도 비교에 관한 연구)

  • S.K.Lee
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.3
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    • pp.300-310
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    • 1999
  • A constant-volume combustion chamber is developed to measure the burnt gas temperature over the wide ranges of equivalence ratio from 1.5 to 2.7 and pressure from 0.1 to 2.7 and pressure from 0.1 to 6 MPa by two-color method. The combustion temperature is also calculated by the conventional two-region model. The premixed fuel rich propane-oxygen-inert gas mixtures under high pressures are simultaneously ignited by eight spark plugs located on the circumference of combustion chamber with 45 degree intervals. The eight converging flames compress the end gases to high pressures. The transmissiv-ity in the chamber center during the final stage of combustion at the highest pressure is measured by in situ laser extinction method. Comparisons are made with the combustion temperatures between two-color method and two-region model. It is found that the burnt gas temperature mea-sured by two-color method is higher than that calculated by two-region model because of being the negative temperature gradient on the calculation and the temperature distribution of light path-length on the measurement and the burnt gas temperature for the turbulent combustion is higher than that of the laminar combustion under the same conditions because the heat loss for turbulent combustion is lower due to the shorter combustion period.

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