• Title/Summary/Keyword: oxygen gas

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Vaporization Characteristics of Liquid Oxygen at High-Pressure Environment (고압 상태에서의 액체 산소의 증발 특성 해석)

  • 유용욱;김용모;손정락
    • Journal of the Korean Society of Propulsion Engineers
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    • v.2 no.3
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    • pp.90-98
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    • 1998
  • The vaporization process of liquid oxygen(LOX) at high pressure environment is numerically investigated. The present vaporization model can account for the high-pressure effects such as ambient gas solubility, real gas behavior and variable properties. The predicted phase-equilibrium compositions for $N_2$/$H_2$ and $O_2$/He system are well agreed with experimental data. The LOX vaporization characteristics is parametrically studied for wide range of the operating conditions encountered in the high-pressure combustion process of liquid rocket engine.

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Etch characteristics of ITO(Indium Tin Oxide)using ${SF_6}/{O_2}$-gas ECR(Electron Cyclotron Resonance) plasmas (ECR을 이용한 ${SF_6}/{O_2}$ 가스 플라즈마에 의한 ITO의 식각 특성연구)

  • 권광호;강승열;김곤호;염근영
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.7
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    • pp.563-567
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    • 2000
  • We presented the etch results of indium-tin oxide thin films by using SF$_{6}$/O$_2$gas electron cyclotron resonance plasma and conducted X-ray phtoelectron spectroscopy and quadrupole mass spectrometer analyses for the etch characteristics. The etch rate of the films was greatly dependent on that of oxygen which was the major constituent element of the films. The oxygen was removed by the forms like $O_2$or SOF$_2$. We examined the ratio of atomic content of O and In and the change of this ratio was related to the removal rate of InF$_{x}$ and the S-metal bonding.ing.

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Effects of CaO on the Ethanol Sensing Characteristics of $LaCoC_3$ ($LaCoC_3$ 산화물의 에탄올 감지특성에 미치는 CaO의 영향)

  • Rim, Byung-O;Shon, Tai-Won;Yang, Chun-Hoi
    • Journal of the Korean Society of Safety
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    • v.3 no.2
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    • pp.49-53
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    • 1988
  • The perovskite-type compounds $La_{1-x}Ca_xCoO_3$ were synthesized, their thermochemical properties and the gaseous sensitivity were investigated in ethanol vapor. The maximum response for detecting gas corresponded with the exothermic peak of DTA experiment. In any case the substituent was increased, the responsive ratio for detecting gas was grown upon. However, the needed time for response was later, and the operating temperature was elevated. The mechanism of this electrical conductivity was explained by the oxygen ionic diffusion through oxygen vacancy produced by the substituent.

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Preparation of ITO thin films with $O_2$ gas ratio (산소 가스 유량비 변화에 따른 ITO 박막의 제작)

  • Kim, Geon-Hi;Keum, Min-Jong;Lee, Gyu-Sung;Kim, Han-Ki;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.547-550
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    • 2004
  • Indium tin oxide(ITO) films were prepared as a function of varying the proportion of oxygen$[0{\sim}1.0sccm]$ at fixed he gas[20sccm] by facing targets sputtering(FTS) system. Then electrical and optical properties of ITO thin films were estimated by Hall effect measurement system and UV/VIS-spectrometer. In the result, at very little oxygen rate, we can prepare a low resistivity ITO thin film of $3.40{\times}10^{-4}[\Omega{\cdot}cm]$ and transmittance of over 80%. So we noticed that the ITO thin film with low resistivity and high transmittance was prepared by FTS at room temperature.

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The Effect of the Oxygen-Enrichment on the PAH Production in Fuel-Rich $CH_4/CH_3Cl$ Premixed Flames (과농조건인 $CH_4/CH_3Cl$ 예혼합화염에서 산소부화가 PAH 생성에 미치는 효과)

  • Lee, Ki-Yong
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.9-14
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    • 2010
  • Numerical simulations of freely propagating fuel-rich $CH_4/CH_3Cl$ premixed flames were performed at atmospheric pressure in order to understand the effect of the oxygen enrichment on the production of PAH. A chemical kinetic mechanism was used, which involved 157 gas-phase species and 1693 forward reactions. The calculated flame speeds were compared with the experiments for the flames established on the equivalence ratios of 1~1.6, the results of which were in good agreement. As the level of oxygen enrichment was increased, the concentrations of one or four ring aromatic hydrocarbons were decreased. This might cause the fact that the contribution of PAH species to soot was weakened.

Studies on the Fish Kills by Histopathological Characteristics in Gills and Caudal Fins (아가미 혈종과 지느러미 표피탈락 현상을 이용한 어류 폐사원인 연구)

  • 최필선;최성수;이길철;윤준헌;박광식
    • Environmental Analysis Health and Toxicology
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    • v.11 no.3_4
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    • pp.45-51
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    • 1996
  • Histopathological changes of gills and caudal fins isolated from fishes, Cyprinus carpio, Carassius auratus, and Hernibarbus labeo, which were killed by oxygen deficiency or toxic chemicals, were studied. The toxic chemicals were HCl, NaOH, chloroform, benzene, heavy metals(Cu, Cr, Zn, Pb, Hg), and o-dichlorobenzene. The exposure level was enough to kill the fishes within 30 minutes. Oxygen deficient water was prepared by aeration of nitrogen gas and the oxygen concentration was less than l ppm. Cryocutting was used for the rapid preparation of tissue slides and the tissues were stained by hematoxylin/eosin. In the fishes killed by hazardous chemicals, congestion and/or hyperplasia of secondary lamella and erosion of fin were found as the major histopathological changes. Whereas, these characteristics were not observed in gills or caudal fins of fishes killed by oxygen deficiency. These different bioindications appeared in the fishes killed by toxic substances or natural causes, can be used for the rapid identification of the causes of fish kills.

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Evolution, Fields of Research, and Future of Chemical-Looping Combustion (CLC) process: A Review

  • Shahrestani, Masoumeh Moheb;Rahimi, Amir
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.299-308
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    • 2014
  • This study presents a review on Chemical looping combustion (CLC) development, design aspects and modeling. The CLC is in fact an unmixed combustion based on the transfer of oxygen to the fuel by a solid oxygen carrier material avoiding the direct contact between air and fuel. The CLC process is considered as a very promising combustion technology for power plants and chemical industries due to its inherent capability of $CO_2$ capturing, which avoids extra separation costs of the of $CO_2$ from the rest of flue gases. This review covers the issues related to oxygen carrier materials. The modeling works are reviewed and different aspects of modeling are considered, as well. The main drawbacks and future research and prospects are remarked.

Interaction of Oxygen and Chlorine Dioxide in Pulp Bleaching (I) -Studies on the Degradation of Lignin Model Compounds- (펄프 표백시 산소와 이산화염소의 상호작용 (제1보) - 리그닌 모델화합물 연구 -)

  • 윤병호;황병호;김세종;최경화
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.3
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    • pp.74-78
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    • 2003
  • The structural property of phenolic and non-phenolic lignin has an effect on the reaction rate of lignin by oxygen and chlorine dioxide respectively. Moreover, the undesirable degradation of cellulose followed by lignin degradation is influenced by chemical charge and reaction time. In this paper, several lignin model compounds were used to illuminate the interaction of oxygen and chlorine dioxide by varying the position of O and D(OD, DO, ODO and DOD), and gas chromatography method was used to investigate the degradation of lignin by determining the content of methoxyl groups in lignin. It was shown that structural properties of lignin models were more influential on the degradation and demethylation of lignin than the above combination. Combination of oxygen and chlorine dioxide, however, was more effective in degradation of lignin than only one stage, and three stages than two stages.

Effect of MgO Contents on Electrical Properties and Oxygen Sensing Characteristics in Co1-xMgxO Ceramics (Co1-xMgxO세라믹스의 MgO함량에 따른 전기적 성질 및 산소가스 감지특성)

  • 최현국;이덕동;조상희
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.7-12
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    • 1989
  • The effects of composition ratios and sintering conditions in Co1-xMgxO ceramics on the sintering characteristics, electrical properties and oxygen sensing characteristics were investigated. In the same sintering conditions, porosity decreased with increase of MgO contents. The relationshiop of temperature and resistance in Co1-xMgxO ceramics showed NTC(negative temperature coefficient) characteristics at the temperature range from $700^{\circ}C$ to 1,10$0^{\circ}C$. In the case of pure CoO, however, the PTC(positive temperature coefficient) characteristics were shown over about 90$0^{\circ}C$. The electrical conductivity of Co1-xMgxO ceramics decreased proportionally with decrease of oxygen partial pressure at the range from 1 to 10-4(atm). Particularly, Co0.5Mg0.5O ceramics showed the highest sensitivity to oxygen gas.

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Nitrogen self-enrichment in the starburst galaxies under the metal poor environments

  • Chung, Ji-Won;Sung, Eon-Chang;Rey, Soo-Chang;Kyeong, Jae-mann
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.29.2-29.2
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    • 2010
  • We present elemental abundances of 412 blue compact dwarf galaxies (BCDs) at z=0.2~0.5 using the Sloan Digital Sky Survey (SDSS) DR7. The gas-phase nitrogen to oxygen abundance ratios (N/O) of sample galaxies increase as the oxygen to hydrogen abundance ratios (O/H) decrease. This indicates that the nitrogen is more enriched than the oxygen. We found that there is a noticeable distinction between the merger candidates and the isolated galaxies. Merging candidates show more enrichment of nitrogen abundance compared to isolated galaxies. On the other hand, neon and oxygen abundances for merging candidates are slightly lower than the isolated systems. We discuss the main cause of these trends with internal mixing and mass loss by fast rotation of young massive stars. We also discuss the environmental effect to the relation between specific star formation rate and galaxy mass.

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