• Title/Summary/Keyword: oxygen gas

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Calculation of non-condensable gases released in a seawater evaporating process (해수 증발과정에서의 기체방출량 계산)

  • Jeong, Kwang-Woon;Chung, Hanshik;Jeong, Hyomin;Choi, Soon-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.182-190
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    • 2017
  • All liquids contain a small amount of gaseous components and the amount of gases dissolved in a liquid is in accordance with Henry's Law. In a multi-stage thermal-type seawater desalination plant, as the supplied seawater undergoes variations in temperature and pressure in each evaporator, the gases dissolved in the seawater are discharged from the liquid. The discharged gases are carbon dioxide, nitrogen, oxygen, and argon, and these emitted gases are non-condensable. From the viewpoint of convective heat transfer, the evaluation of non-condensable gas released during a vacuum evaporation process is a very important design factor because the non-condensable gases degrade the performance of the cooler. Furthermore, in a thermal-type seawater desalination plant, most evaporators operate under vacuum, which maintained through vacuum system such as a steam ejector or a vacuum pump. Therefore, for the proper design of a vacuum system, estimating the non-condensable gases released from seawater is highly crucial. In the study, non-condensable gases released in a thermal-type seawater desalination plant were calculated quantitatively. The calculation results showed that the NCG releasing rate decreased as the stage comes getting a downstream and it was proportional to the freshwater production rate.

Influence of Transgenic Corn on the In vitro Rumen Microbial Fermentation

  • Sung, Ha Guyn;Min, Dong Myung;Kim, Dong Kyun;Li, De Yun;Kim, Hyun Jin;Upadhaya, Santi Devi;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.12
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    • pp.1761-1768
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    • 2006
  • In this study, the comparative effects of transgenic corn (Mon 810 and Event 176) and isogenic corn (DK729) were investigated for their influence on in vitro rumen fermentation. This study consisted of three treatments with 0.25 g rice straw, 0.25 g of corn (Mon810/Event176/DK 729) mixed with 30 ml rumen fluid-basal medium in a serum bottle. They were prepared in oxygen free conditions and incubated at $39^{\circ}C$ in a shaking incubator. The influence of transgenic corn on the number of bacterial population, F. succinogenes (cellulolytic) and S. bovis (amylolytic), was quantified using RT-PCR. Fermentative parameters were measured at 0, 2, 4, 8, 12 and 24 h and substrate digestibility was measured at 12 and 24 h. No significant differences were observed in digestibility of dry matter, NDF, ADF at 12 and 24 h for both transgenic and isogenic form of corns (p>0.05) as well as in fermentative parameters. Fluid pH remained unaffected by hybrid trait and decreased with VFA accumulation as incubation time progressed. No influence of corn trait itself was seen on concentration of total VFA, acetic, propionic, butyric and valeric acids. There were no significant differences (p<0.05) in total gas production, composition of gas (methane and hydrogen) at all times of sampling, as well as in NH3-N production. Bacterial quantification using RT-PCR showed that the population number was not affected by transgenic corn. From this study it is concluded that transgenic corn (Mon810 and Event 176) had no adverse effects on rumen fermentation and digestibility compared to isogenic corn. However, regular monitoring of these transgenic feeds is needed by present day researchers to enable consumers with the option to select their preferred food source for animal or human consumption.

A Study on Combustion Characteristics in terms of the Type of Fuel Supply Device (Feeder) of a Wood Pellet Boiler (목재펠릿보일러의 연료공급 장치의 형태에 따른 연소특성에 관한 연구)

  • Choi, Yun Sung;Euh, Seung Hee;Oh, Kwang Cheol;Kim, Dae Hyun;Oh, Jae Heun
    • Journal of Energy Engineering
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    • v.24 no.2
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    • pp.120-128
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    • 2015
  • This study reports the combustion characteristics, such as burner temperature and the concentration of exhausted gas ($O_2$, $CO_x$, $NO_x$) due to the different types and pitches of the fuel supply feeder of the wood pellet boiler. The 1st grade wood pellets composed of mainly larch have been used for the experiment. In case of using the spring feeder, mean temperature of burner was approximately $821.76^{\circ}C$, and the mean concentration of oxygen, carbon monoxide, carbon dioxide and nitrogen oxide were approximately 8.88%, 93.35ppm, 12.15% and 139.83 ppm, respectively. The test result with the spring feeder was shown to approach the condition of complete combustion compared to that of a screw feeder and were in good agreement with authentication judgement standard. Furthermore, the combustion efficiency was improved according to the growth of screw pitch. The control of air flow rate from the blower and ventilator is needed to achieve the complete combustion.

Evaluation of Combustion Gas for Carbon Oxide of Wood Coated with Bis-(dialkylaminoalkyl) Phosphinic Acids Additives

  • Jin, Eui;Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.30 no.4
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    • pp.65-72
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    • 2016
  • This study examined the generation of combustion toxic gases of pinus rigida specimens processed with bis-(dimethylaminomethyl) phosphinic acid (DMDAP), bis-(diethylaminomethyl) phosphinic acid (DEDAP), and bis-(dibutylaminomethyl) phosphinic acid (DBDAP). Each pinus rigida plate was coated three times with 15 wt.% flame retardants in an aqueous solution. The specimens were then dried at room temperature. The production of combustion toxic gases was investigated using a cone calorimeter (ISO 5660-1). The first time to peak mass loss rate ($1^{st}-TMLR_{peak}$) processed with the chemical additives decreased to 5.9 from 41.2% compared with the unprocessed specimen. The second time to the peak mass loss rate ($2^{nd}-TMLR_{peak}$) for the processed specimens was decreased 1.8% for DMDAP and 5.3% for DBDAP and increased 1.8% for DEDAP. The peak carbon monoxide ($CO_{peak}$) production was 1.5 to 2.0 times higher than that of the unprocessed plate. The peak carbon dioxide ($CO_{2peak}$) production was reduced 0.01 times for DMDAP and increased 1.15 to 1.19 times for DEDAP and DBDAP compared with the unprocessed specimens. In particular, the oxygen concentration was much higher than 15%, which can be fatal to humans and the resulting hazard can be eliminated. Overall, the combustion toxicity of flammable gas were increased partially by the chemical additives compared with those of the unprocessed plate.

A Study on the Estimation Accuracy of Energy Expenditure by Different Attaching Position of Accelerometer (가속도계의 부착위치에 따른 에너지 소비량의 예측 정확도에 관한 연구)

  • Kang, Dong-Won;Choi, Jin-Seung;Mun, Kyung-Ryoul;Bang, Yun-Hwa;Tack, Gye-Rae
    • Korean Journal of Applied Biomechanics
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    • v.19 no.1
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    • pp.179-186
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    • 2009
  • This works studied to compare gas analyzer with accelerometer and the estimation of energy expenditure based on different attaching position of tri-axial accelerometer such as waist and top of the foot Based on the fact that oxygen intake increases more radically linearly during walking more than 8.0km/hr. 9 male subjects performed walking and running on the treadmill with speed of $1.5{\sim}8.5km$/hr and $4.5{\sim}13.0km$/hr, respectively. Commercially available Nike + iPod Sports kit was used to compare energy expenditure with sensor module attached to their foot. Actual energy expenditure was determined by a continuous direct gas analyzer and two multiple regression equations of walking and running mode for different attaching position were developed. Results showed that estimation accuracy of energy expenditure using waist mounted accelerometer was higher than that of the top of the foot and Nike + iPod Sports kit. Results of energy expenditure based on waist and top of the foot showed that the crossover state of energy expenditure occurred at 7.5km/hr. But Nike + iPod Sports kit could not find intersection of energy expenditure in all nine subjects. Therefore the sensor module attached to the waist and separate multi regression equation by walking and running mode was the best to estimate more accurate prediction.

A Study on Optimization of Spray Type Flue Gas Desulfurization (FGD) System (모사 탈황흡수탑을 이용한 Spray Type 탈황설비 최적운전 방안에 관한 연구)

  • An, Hi-Soo;Park, Seung-Soo;Kim, Ki-Hyoung;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.18 no.1
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    • pp.29-35
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    • 2007
  • Recently, due to narrow margin on design factor of flue gas desulfurization (FGD) systems or aging of systems, some problems such as decrease of $SO_2$ removal efficiency and difficulty on coping with unstable state are arising on FGD systems. On this study, to cope with these problems several methods such as adjustment of reagent pH, inlet $SO_2$ concentration, variation of units of operation pump, installation of liquid distribution ring (LDR) were attempted to increase the $SO_2$ removal using spray type simulated FGD system. Also, sulfite and Al/Fx ion effects on limestone blinding were experimented. When three absorber recirculation pumps were operated, $SO_2$ removal was increased by 12% in comparison with that of two pumps operation. $SO_2$ removal was increased by 2~7% after installation of LDR. Dissolved oxygen increased up to 0.5 ppm and limestone binding effect was alleviated after injection of dibasic acid (DBA) with the concentration of 500 and 1,000 ppm. When $Al^{3+}$ and $F^-$ ions were coexisting, the dissolution rate of limestone was decreased by 20%.

Influence of Preheating on Quality Changes of Fresh-cut Muskmelon (가공 전 열처리가 Fresh-cut Muskmelon의 품질변화에 미치는 영향)

  • 박연주;문광덕
    • Food Science and Preservation
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    • v.11 no.2
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    • pp.170-174
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    • 2004
  • Whole muskmelon was blanched at 50$^{\circ}C$ water for inhibition decline of fresh-cut melon quality from direct heat treatment. The muskmelon, after storage at 5$^{\circ}C$ for 24 hours, was processed to melon cylinders with 2 cm diameter. The changes of color, texture and the quality characteristics such as gas composition. soluble solid content, pH during storage at 5$^{\circ}C$ were measured. Degree of oxygen contents decreased and that of carbon dioxide in melon cylinder increased during storage. Especially, changes of gas composition inside packages appeared high level cor in blanched melon cylinders than non-treatment melons. Blanching with whole fruits at 50$^{\circ}C$ had effects on hardness in melon cylinder. Blanched melon, without regard on branching time, appeared higher hardness value than that of non-blanched melon at 6 days storage. There were slight difference between treatment on melon cylinder color. Degrees of change in soluble solid contents and pH on melon cylinder blanched at 50$^{\circ}C$ for 20minuets were lower than that of other treatments. In consequence, blanching with whole fruit at 50$^{\circ}C$ for 20minuets, before minimal processing, was effective in preserving of texture and quality of melon cylinder during storage.

Preparation of CeO$_2$ Thin Films as an Insulation Layer and Electrical Properties of Pt/$SrBi_2$$Ta_2$$O_9$/$CeO_24/Si MFISFET (절연층인 CeO$_2$박막의 제조 및 Pt/$SrBi_2$$Ta_2$$O_9$/$CeO_24/Si MFISFET 구조의 전기적 특성)

  • Park, Sang-Sik
    • Korean Journal of Materials Research
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    • v.10 no.12
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    • pp.807-811
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    • 2000
  • CeO$_2$ and SrBi$_2$Ta$_2$O$_{9}$ (SBT) thin films for MFISFET (Metal-ferroelectric-insulator-semiconductor-field effect transistor) were deposited by r.f. sputtering and pulsed laser ablation method, respectively. The effects of sputtering gas ratio(Ar:O$_2$) during deposition for CeO$_2$ films were investigated. The CeO$_2$ thin films deposited on Si(100) substrate at $600^{\circ}C$ exhibited (200) preferred orientation. The preferred orientation, Brain size and surface roughness of films decreased with increasing oxygen to argon gas ratio. The films deposited under the condition of Ar:O$_2$= 1 : 1 showed the best C- V characteristics. The leakage current of films showed the order of 10$^{-7}$ ~10$^{-8}$ A at 100kV/cm. The SBT thin films on CeO$_2$/Si substrate showed dense microstructure of polycrystalline phase. From the C-V characteristics of MFIS structure with SBT film annealed at 80$0^{\circ}C$, the memory window width was 0.9V at 5V The leakage current density of Pt/SBT/CeO$_2$/Si structure annealed at 80$0^{\circ}C$ was 4$\times$10$^{-7}$ /$\textrm{cm}^2$ at 5V.

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Method for Rapid Determination and Removal of Nitrogen Oxides in Flue Gases (Ⅰ). Rapid Determination on Nitrogen Oxides (배기가스중 질소산화물의 신속측정법과 그 제거에 관한 연구 (제1보). NO$_x$의 신속 정량법)

  • Yong Keun Lee;Tong Oh Seo;Kee Jung Paeng;Man Koo Kim;Kyu Ja Whang
    • Journal of the Korean Chemical Society
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    • v.29 no.1
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    • pp.52-60
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    • 1985
  • Oxides of nitrogen (NO$_x$) in exhaust gases was determined by absorbing the gas in alkaline peroxide solution containing 0.03${\%}$ H2O2 and 0.1N NaOH. About 100 ppm of NO$_x$ was rapidly oxidized to NO$_2$ or N$_2$O$_5$ by H$_2$O$_2$ and required a contact time of 2 minutes with the absorbing solution for complete absorption. With vigorous shaking including air or oxygen gas, high concentration of NO$_x$ (>200 ppm) can be absorbed within 30 minutes. The remaining H$_2$O$_2$ affect the absorbance of color solution strongly. However, the excess H$_2$O$_2$ was completely decomposed by zinc powder 0.5g and the sample solution should be adjusted to the pH range 6.1∼6.6 before the reduction so that conversion of nitrate to nitrite ion is possible. The absorbed NO$_x$ is determined colorimetrically by the diazotization-coupling method with sulfonilamide and NEDA as the coupling agent. The sensitivity of the new method was 4.48 ${\times}$ 10$^4$ as molar absorptivity which was high sensitive compared with that obtained for the usual zinc reduction NEDA method with O$_3$. This method was far more rapid, brief and accurate than previously published O$_3$-NEDA method in Korean industrial standard.

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Time-Dependent Modeling of Performance Degradation for PEMFC Single Cell System to Evaluate the Cell Performance and Durability: Effects of CO Poisoning (고분자전해질 연료전지의 성능과 안정성 시험을 위한 단위전지의 시간 경과에 따른 모델링: 일산화탄소 피독현상에 의한 효과)

  • Kim, Jong-Sik;Kim, Pil;Joo, Ji-Bong;Kim, Woo-Young;Yi, Jong-Heop
    • Clean Technology
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    • v.14 no.1
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    • pp.61-68
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    • 2008
  • There have been great attentions on polymer electrolyte membrane fuel cell (PEMFC) due to their advantageous characteristics such as zero emission of hazardous pollutant and high energy density. In this work, we evaluated degradation phenomena and stability of single cell performance via one dimensional single cell modeling. Here, CO poisoning on anode on anode was considered for cell performance degradation. Modeling results showed that the performance and stability were highly degraded with CO concentration in fuel gas. In addition, cell performance was reduced by slow oxygen reduction on cathode in long term operation. In order to overcome, it is required to increase ratio o#hydrogen in the fuel gas of anode and high Pt loading contained in the cathodic catalyst layer.

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