• Proceedings of the Korean Society of Precision Engineering Conference
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• 2002.05a
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• pp.844-847
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• 2002

This paper is to investigate the wear behavior of submerged-arc clad materials by the wear test with a ball-on-disk type wear testing machine in air. The specimens were clad with Stoody105 alloy wire on a carbon steel (SM45C) substrate by submerged-arc cladding process under different welding parameters. The wear behavior of the cladding through ball-en-disk test has been studied under the wear load from 5N to 16N and sliding speed from 8cm/s to 35cm/s. The weight of the specimen loss was measured. Scanning electron micrographs of the worn surface show a layer of oxide film formed on the worn surface. Oxidation wear mechanism controls the wear process. The spalling of the oxide is caused by the repeated rubbing fatigue mechanism.

• Tribology and Lubricants
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• v.16 no.1
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• pp.15-21
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• 2000

Radiation of Nd-YAG laser changes and refines the surface microstructure of steels, which gives rise to enhancement of hardness and resulting wear resistance. In the present work, the effect of processing parameters during the surface modification with laser on the wear behavior of the SM45C steel was studied by means of wear testing. The counter material was alumina ceramics. The microstructure observation revealed the dependence of molten depth and width on the defocusing distance. The laser modification of steel surface give rise to improved wear resistance in the testing speed range of either <0.2 m/s or >0.9 m/s Material transfer from steel was wear observated the surface of counter material when testing speed was lower than 0.7 m/s.

• Journal of the Korean Society for Precision Engineering
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• v.20 no.1
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• pp.179-186
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• 2003

This paper is to investigate the wear behavior of submerged-arc claddings by the wear test with a ball-on-disk type wear testing machine in air. The specimens were clad with Stoody105 alloy wire on a medium carbon steel (SM45C) substrate by submerged-arc cladding process under different welding parameters. The wear behavior of the cladding through ball-on-disk test has been studied under the wear load from 5 to 16 N and the sliding speed from 8 to 35 cm/s. The weight loss of the specimen was measured. Scanning electron micrographs of the worn surface show a layer of oxide film formed on the worn surface. Oxidation wear mechanism controls the wear process. The spatting of the oxide is caused by the repeated rubbing fatigue mechanism.

• Corrosion Science and Technology
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• v.2 no.1
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• pp.41-46
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• 2003

Flow-Accelerated Corrosion behavior concerning both activation and mass transfer process of SA106 Gr.C steel was studied using rotating cylinder electrode in room temperature alkaline solution by DC and AC electrochemical techniques. Passive film was tanned from pH 9.8 by step oxidation of ferrous product into hydroxyl compound. Corrosion potential shifted slightly upward with rotating velocity through the diffusion of cathodic species. Corrosion current density increased with rotating velocity in pH 6.98, while it soon saturated from 1000 rpm at above pH 9.8. On the other hand the limiting current increased with rotating speed regardless of pH values. It seems that activation process, which represents formation of passive film on the bare metal surface, controls the entire corrosion kinetics

• Journal of Korea Foundry Society
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• v.23 no.3
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• pp.122-129
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• 2003

The abilities and fading behaviors of 5 different inoculants were evaluated by the thermal analyses of the melts which were held at constant temperature after addition in induction furnace. The silicon content was preserved at the high holding temperature of 1,450${\sim}$1,500$^{\circ}C$, which reduced by oxidation at the low one. The inoculation temperature should be higher to obtain better and reproducible result. The inoculation performance of 1%Ba-Fe-Si was the best on the bases of effect and fading behavior.

• Proceedings of the Korean Nuclear Society Conference
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• 1999.05a
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• pp.279-279
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• 1999

To improve the corrosion model of the fuel performance analysis code COSMOS, a model was developed considering thermohydraulic phenomena and the effect of water chemistry and low Sn in the alloy composition on the corrosion behavior. It is assumed that the lithium enhancement factor influences the corrosion behavior only if the subcooled void is present in the coolant. The developed model was verified with the database obtained from Grohnde and Ringhals 3 reactors. Comparison of predicted oxide thickness with measured data showed the applicability of COSMOS code to analyze the cladding oxidation. In the future, the effect of the hydride in the cladding and the precipitate changes due to irradiation should be included.cluded.

• Journal of Ocean Engineering and Technology
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• v.16 no.2
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• pp.60-66
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• 2002

The remote measurement system(RMS) as a new experimental method is limited in its application to crack measurement at elevated temperatures because of the oxide layer on the specimen surface. Since TiAIN and Cr coating layers have a high resistance to oxidation and wear, this paper proposed a TiAIN and Cr coating technique for specimens to facilitate the measurement of crack growth behavior using RMS. To investigate the effects of the coating layer, tension and fatigue tests were carried out at room temperature and at $538^{\circ}C$. The test material was 1Cr-1Mo-0.25V steel which is widely used as a turbine rotor material. From the experimental results, it was found that the mechanical properties of the TiAIN and Cr coated specimens were similar to those of the substrate. Accordingly, the TiAIN and Cr coated layer had hardly any influence on the fatigue crack propagation.

• Nuclear Engineering and Technology
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• v.32 no.6
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• pp.595-604
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• 2000

Flow-Accelerated Corrosion Behavior of SA106 Gr.C steel in room temperature alkaline solution simulating the CANDU primary water condition was studied using Rotating Cylinder Electrode. Systems of RCE were set up and electrochemical parameters were applied at various rotating speeds. Corrosion current density decreased up to pH 10.4 then it increased rapidly at higher pH. This is due to the increasing tendency of cathodic and anodic exchange half-cell current. Corrosion potential shifted slightly upward with rotating velocity. Passive film was formed from pH 9.8 by the mechanism of step oxidation and the subsequent precipitation of ferrous species into hydroxyl compound. Above pH 10.4, the film formation process was active and the film became stable. Corrosion current density showed increment in pH 6.98 with the rotating velocity, while it soon saturated from 1000 rpm above pH 9.8. This seems that activation process which represents formation of passive film on the bare metal surface controls the entire corrosion process

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.2020-2021
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• 2007

Viologen derivative has been widely investigated because of their well-electrochemical behavior including the electron acceptor for the electric charge delivery mediation of the devices. The viologen exist in three main oxidation states, namely, $V^{2+}{\rightleftarrows}V^{{\cdot}+}{\rightleftarrows}V^0$. These redox reactions are highly reversible and can be cycled many times without significant side reaction. In this paper, we determined the time dependence to resonant frequency shift of QCM during self-assembly process and the electrochemical behavior of the self-assembled viologen monolayers by electrochemical QCM method. The redox reactions of viologen were highly reversible and the EQCM has been employed to monitor the electrochemically induced adsorption of SAMs during the redox reactions.

• Journal of Surface Science and Engineering
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• v.36 no.4
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• pp.347-355
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• 2003

Roughening of metal surfaces frequently enhances the adhesion strength of metals to polymers by mechanical interlocking. When a failure occurs at a roughened metal/polymer interface, the failure prone to be cohesive. In a previous work, an adhesion study on a roughened metal (oxidized copper-based leadframe)/polymer (Epoxy Molding Compound, EMC) interface was carried out, and the correlation between adhesion strength and failure path was investigated. In the present work, an attempt to interpret the failure path was made under the assumption that microvoids are formed in the EMC as well as near the roots of the CuO needles during compression-molding process. A simple adhesion model developed from the theory of fiber reinforcement of composite materials was introduced to explain the adhesion behavior of the oxidized copper-based leadframe/EMC interface and failure path. It is believed that this adhesion model can be used to explain the adhesion behavior of other similarly roughened metal/polymer interfaces.