• Title/Summary/Keyword: oxidation behavior

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A Study on the Flame Temperature and KL Value in Inner and Outer Cavity in a D.1. Diesel Engine (디젤엔진에서 Cavity 내 .외측의 화염온도와 KL치에 관한 연구)

  • 이태원;윤수한;정성식;하종률
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.3
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    • pp.18-27
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    • 2002
  • Flame behavior in inner and outer the cavity and flame temperature have an important influence on the formation and oxidation of NOx and soot. Therefore, in this study, the combustion chamber of toroidal and reentrant that have different flow characteristics of inside and outside the cavity and load, and so forth are determined as parameters of experimental conditions. An attempt has been made to obtain the effect of flame temperature and KL value in idler and outer cavity on the formation and oxidation of soot using the two-color method.

A Study on the New Isolation Technology to Improve the Bird's Beak and the Device Characteristics (Bird's Beak 및 소자특성 개선을 위한 새로운 Isolation 기술에 대한 연구)

  • 남명철;김현철;김철성
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.12
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    • pp.106-114
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    • 1994
  • The local oxidation of silicon (LOCOS) technology, which uses a silicon nitride film as an oxidation mask and a pad oxide beween the silicon nitride and the silicon substrate, has been widely used in integrated circuits for process simplicity. But, due to long brid's beak length, there are difficulties in scabilities. Many advanced isolation techniques have been wuggested for the feduction of bird's beak length. In this paper, we presented reduced bird's beak length using the polybuffered oxide and the silicon nitride as the sidewall. Also, investigating the electrical behavior of the parasitic Al-gate MOSFET on LOCOS, we proved the validity for new isolation process.

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A Study on the Decomposition Properties of Disperse Dye Ozone Oxidation Treatment and the Optimum Treatment Condition(I) (Ozone 산화처리에 의한 분산염료의 분해성 및 최적처리조건에 관한 연구)

  • Kim, Sam Soo;Huh, Man Woo;Han, Myung Ho;Yoon, Jong Ho;Cho, Hwan;Kim, Dong Kwon
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.43-55
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    • 1996
  • When some disperse dye was decolored with oxidation power of ozone, the results in investigation of decoloration behavior with dye solution and its order of reaction and variation of TOC were as follow: 1. Order of decoloration for Some disperse dye is C.I. Disperse Blue 79>Blue 73> Red 343>Red 60>Blue 354>Yellow 42. 2. Velocity of decoloration for the all dyestuffs was the fastest when pH 3. 3. TOC was rapidly reduced between 10 min. and 20 min. 4. For the reduction of TOC ozone was needs many times as compared with decoloration of dyestuffs.

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Cobalt Oxide Nanorods Prepared by a Template-Free Method for Lithium Battery Application

  • Kim, Seong-Jun;Kim, Eun-Ji;Liu, Meilin;Shin, Heon-Cheol
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.206-213
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    • 2016
  • Transition metal oxide-based electrodes for lithium ion batteries have recently attracted much attention because of their high theoretical capacity. Here we report the electrochemical behavior of cobalt oxide nanorods as anodes, prepared by a template-free, one-step electrochemical deposition of cobalt nanorods, followed by an oxidation process. The as-deposited cobalt has a slightly convex columnar structure, and controlled thermal oxidation produces cobalt oxides of different Co/O ratios, while the original shape is largely preserved. As an anode in a rechargeable lithium battery, the Co/O ratio has a strong effect on initial capacity and cycling stability. In particular, the one-dimensional Co@CoxOy core shell structure obtained from a mild heat-treatment results in superior cycling stability.

Tribological Behaviors of Chromium Carbide Coatings by HVOF Thermal Spraying (HVOF 열용사에 의한 크롬 카바이드 코팅의 마모.마찰거동)

  • 김장엽;임대순;이상로;변응선;이구현
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1315-1321
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    • 1995
  • The optimal coating condition for chrominum carbide coating was selected by Taguchi method. The wear tests with coated specimens by HVOF method were performed in the temperature to 80$0^{\circ}C$. Applied normal loads were selected to be from 8N to 30N. The worn surfaces and subsurfaces were characterized by XRD, EPMA, AES and SEM. The wear track increased with increasing applied normal load, and in terms of the temperature range from 400 to $600^{\circ}C$, below that range, the wear track increased, and above that temperature ragne, the wear track decreased. The degree of oxidation caused by the test temperature and the frictional heating was responsible to the unique high temperature wear behavior chromium carbide coatings.

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Uniform Coating of Organic-Capped Ba-Ti-O Nanolayers on Spherical Ni Particles

  • Lee, Yong-Kyun;Choi, Jae-Young;Yoon, Seon-Mi;Lee, Jong-Heun
    • Korean Journal of Materials Research
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    • v.17 no.2
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    • pp.86-90
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    • 2007
  • The organic-capped Ba-Ti-O nanolayers were coated uniformly on spherical Ni particles for multilayer ceramic capacitor (MLCC) applications via the formation of Ti-hydroxide nano-coating layers and their subsequent reaction with Ba-stearate at $180^{\circ}C$. The capping of organic shell on oxide coating layer changed the hydrophilic surface structure into hydrophobic one, which significantly improved the dispersion behavior in hydrophobic solvents such as terpineol and butanol. In addition, the uniform coating of Ba-Ti-O layer was advantageous to prevent Ni oxidation. This method provides a useful chemical route to fabricate organic-soluble Ba-Ti-O coated Ni particles for a highly integrated passive component.

The Effect of Rapid Solidification Process on the Oxidation Behavior of Fe-Cr-Al Alloys at Elevated Temperature (Fe-Cr-Al 합금의 급속응고가 고온산화거동에 미치는 영향)

  • 문병기;김재철;김길무
    • Journal of Surface Science and Engineering
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    • v.29 no.1
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    • pp.36-44
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    • 1996
  • Fe-Cr-Al and Fe-Cr-Al-Hf alloys prepared either by arc melting or by single roll casting(melt spinning) were exposed to air isothermally at 900~$1100^{\circ}C$. Whisker-like alumina was observed on the surface of the specimens when oxidized at $900^{\circ}C$, but convoluted alumina above $1000^{\circ}C$. All the Hf-free specimens and Hf-added specimens produced by single roll casting formed only external scale mainly composed of $Al_2O_3$ after oxidation at 900~$1100^{\circ}C$ for 100 hours, but Hf-added specimen produced by arc melting formed Hf-rich internal oxides below the thin external $Al_2O_3$ scale except at $900^{\circ}C$. Most of the rapidly solidified Fe-Cr-Al alloys showed smaller weight gains than conventionally casted ones besides Hf-added one oxidized at $1100^{\circ}C$.

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Characterization of Air and SO2 Gas Corrosion of Silicon Carbide Nanofibers (탄화규소 나노섬유의 고온 대기 및 SO2 가스분위기에서의 부식물성)

  • Kim, Min-Jung;Lee, Dong-Bok
    • Journal of Surface Science and Engineering
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    • v.43 no.1
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    • pp.36-40
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    • 2010
  • The SiO vapor that was generated from a mixture of Si and $SiO_2$ was reacted at $1350^{\circ}C$ for 2 h under vacuum with carbon nanofibers to produce SiC nanofibers having an average diameter of 100~200 nm. In order to understand the gas corrosion behavior, SiC nanofibers were exposed to air up to $1000^{\circ}C$. SiC oxidized to amorphous $SiO_2$, but its oxidation resistance was inferior unlike bulk SiC, because of high surface area of nanofibers. When SiC nanofibers were exposed to Ar-1% $SO_2$ atmosphere, SiC oxidized to amorphous $SiO_2$, without forming $SiS_2$, owing to the thermodynamic stability of $SiO_2$.

SAMs of 2-Aminoethanethiol Modified with 3,4-Dihydroxyphenylalanine for the Electrocatalytic Oxidation of NADH on Gold Electrodes

  • Cha, Seong-Keuck
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.786-790
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    • 2004
  • 2-Aminoethanethiol (aet) has been used to make self-assembled monolayer (SAMs) on gold electrodes, which are subsequently modified with 3,4-dihydroxy phenylalanine (dpa). Such modified electrodes having various types of Au/aet-dpa were employed in the electrocatalytic oxidation of NADH. The purpose of this study to characterize the responses of such modified electrodes in terms of the immobilization procedure, pH of the solution and applied potential. The reaction of the surface immobilized dpa with NADH was studied using the rotating disk electrode technique and a value of $2.2{\times}10^4M^{-1}s^{-1}$ was obtained for the second-order rate constant in 0.1 M Tris/$NO_3^-$buffer (pH=8.0). The hydration behavior of the films was characterized by quartz crystal microbalance. When used as a NADH sensor, the Au/aet-dpa electrode exhibited good sensitivity and an excellent correlation (r ${\geq}$ 0.99) for NADH concentration which extended to $3.8{\times}10^{-3}$ M.

Voltammetric Determination of Bisphenol A Using a Carbon Paste Electrode Based on the Enhancement Effect of Cetyltrimethylammonium Bromide (CTAB)

  • Huang, Wensheng
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1560-1564
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    • 2005
  • The influence of cetyltrimethylammonium bromide (CTAB) on the electrochemical behavior of bisphenol A at the carbon paste electrode (CPE) was investigated. CTAB, with a hydrophobic C-H chain, can adsorb at the CPE surface via hydrophobic interaction and then change the electrode/solution interface, and finally affects the electrochemical response of bisphenol A, confirming from the remarkable oxidation peak current enhancement. The electrode process of bisphenol A was examined, and then all the experimental parameters which affects the electrochemical response of bisphenol A, such as pH value of the supporting electrolyte, accumulation potential and time, potential scan rate and the concentration of CTAB, were examined. Finally, a sensitive and simple voltammetric method was developed for the determination of bisphenol A. Under the optimum conditions, the oxidation peak current of bisphenol A varied linearly with its concentration over the range from $2.5\;{\times}\;10^{-8}\;to\;1\;{\times}\;10^{-6}$ mol/L, and the detection limit was found to be $7.5\;{\times}\;10^{-9}$ mol/L. This method was successfully employed to determine bisphenol A in some waste plastic samples.