• 제목/요약/키워드: oxidation

검색결과 10,211건 처리시간 0.032초

액상 모델 시스템에서 베타-카로틴의 Co-oxidation에 대한 리폭시게나아제 및 기타 관련 인자들의 영향 (Effect of Lipoxygenase and Other Factors on the Co-oxidation of $\beta$-Carotene in Aqueous Model System)

  • 최홍식;김혜경
    • 한국식품영양과학회지
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    • 제24권2호
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    • pp.202-207
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    • 1995
  • The effects of lipoxygenase, linoleic acid, tocopherol and pH on the co-oxidation of $\beta$-carotene in the aqueous system were studied. It showed that the co-oxidation of $\beta$-carotene was noticeable at both pH 7.4 and 9.0. As the concentraitons of linoleic acid and $\beta$-carotene increased, the rate of oxidation of $\beta$-carotene tended to be increased. However, $\alpha$- and $\delta$-tocopherol retarded the co-oxidation of $\beta$-carotene. As the concentrations of tocopherols increased, $\beta$-carotene was more stabilized, generally. But low concentration of $\alpha$-tocopherol(10-4M) acted more effective antioxidant than high concentration of it(10-3M) at pH 7.4. The antioxidant effect of tocopherol greatly depended on pH ; it was outstanding at pH 7.4.

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열간 압연강의 고온산화에 미치는 전기로제조법, 고로제조법 및 탄소량의 영향 (Effect of Arc Furnace Manufacturing Process, Blast Furnace Manufacturing Process, and Carbon Content on High-temperature Oxidation of Hot-rolled Steel between 650 and $900^{\circ}C$)

  • 김민정;봉성준;이동복
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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    • pp.75-76
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    • 2011
  • Hot-rolled steel plates of SPHC and SS400 were oxidized at 600, 750 and $900^{\circ}C$ for 2hr in air. With an increase in oxidation temperature, their oxidation rates increased, being accompanied with formation of pores and cracks in the thickened oxide scales that were non-adherent. The SPHC steels that were manufactured by either the arc furnace or the blast furnace displayed similar oxidation rates, indicating that their oxidation rates were insensitive to the manufacturing processes. The medium-carbon SS400 steel displayed a little faster oxidation rates than the low-carbon SS400 steel, indicating that the carbon content did not significantly influence the oxidation rates.

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Net Methane Oxidation Performance of Anaerobic Sewage Sludge

  • Yi, Taewoo;Kim, Tae Gwan;Lee, Eun-Hee;Lee, Jung-Hee;Cho, Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • 제22권10호
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    • pp.1452-1456
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    • 2012
  • The anaerobic oxidation of methane (AOM) in anaerobic sewage sludge was characterized. The net methane oxidation was observed in samples amended with methane plus sulfate or with methane alone, whereas methane formation was observed in the samples without methane, indicating that methane oxidation and formation occurred simultaneously. The ratio of the net methane oxidation rate to $H_2S$ formation was 100:1, suggesting that the AOM was not closely associated with sulfate reduction in the anaerobic sludge. The net AOM was positively associated with the methane concentration and sludge dilution ratio. However, the rate of AOM was negatively correlated with organic substrate (acetate) concentration. Therefore, the production and oxidation of methane could be controlled by environmental conditions and dissolved organic compounds in the bulk solution.

강기판 위에 코팅된 Ni-W의 고온산화거동 (High Temperature Oxidation Behavior of Ni-W Coatings Electrodeposited on Steel)

  • 고재황;권식철;장도연;이동복
    • 한국표면공학회지
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    • 제36권6호
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    • pp.430-436
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    • 2003
  • The nanoocrystalline Ni-l5W(at.%) coating electrodeposited on the high carbon steel was oxidized at 700 and $800^{\circ}C$ in air, and the resultant oxidation properties were investigated using XRD, EPMA, TGA and TEM. The oxidation resistance of the coating was not so good that most of the coating was oxidized after oxidation at $800^{\circ}C$ for 5 hrs. The oxidation led to the formation of the outer, thin NiO oxide scale and the inner, porous, rather thick ($NiWO_4$+NiO) mixed layer containing a bit of $WO_2$. During oxidation, substrate elements such as Fe and Cr diffused outwardly toward the coating, according to the concentration gradient.

Electrochemical Oxidation of Benzidine and Hydrazobenzene

  • Won Mi-Sook;Shim Yoon-Bo;Park Su-Moon
    • Bulletin of the Korean Chemical Society
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    • 제13권6호
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    • pp.680-683
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    • 1992
  • The electrochemistry of benzidine and hydrazobenzene was studied in water-acetonitrile mixed solutions at various pHs and the results are reported. The cyclic voltammetric peak for the oxidation of benzidine shows a pH dependency of -62 mV/pH in the pH range of 0-3.5, no pH dependency between pH values of 3.5 and about 10.5, and of about -50 mV/pH between pH=10.50 and 14.0, indicating that oxidation mechanisms differ depending on the pH of the medium. However, the CV peak for the hydrazobenzene oxidation is shown to be independent of pH of the medium, suggesting that the proton is not involved in the rate limiting step of the electrochemical oxidation of hydrazobenzene to azobenzene. Results of in situ spectroelectrochemical experiments indicate that the oxidation products obtained during the oxidation of benzidine and hydrazobenzene depend on the result of dynamic equilibria taking place at various pHs.

텅스텐 폴리사이드의 산화반응속도에 미치는 인 도핑 농도의 영향 I (Effects of Phosphorus Doping Concentration on the Oxidation Kinetics of Tungsten Polycide I)

  • 이종무;윤국한;임호빈;이종길
    • E2M - 전기 전자와 첨단 소재
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    • 제4권1호
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    • pp.19-30
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    • 1991
  • W/Si의 조성비가 2.6인 CVD텅스텐 실리사이드를 어닐링처리후 dry 또는 wet oxidation하여 폴리사이드 구조에서 다결정 Si내의 농도가 실리사이드의 산화반응속도에 미치는 영향을 조사하였다. 인의 농도에 관계없이 항상 실리사이드의 산화속도가 (100)Si의 그것보다 더 높았다. 저온에서 dry oxidation한 경우 인의 농도가 증가함에 따라 산화속도는 감소하였으나 고온에서 dry oxidation한 경우에는 P농도와 산화속도간에 상관관계가 별로 없었다. 한편, wet oxidation의 경우에는 모든 산화온도에서 인의 농도가 높을수록 실리사인의 산화속도가 더 낮은 것으로 나타났다.

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열산화에 의한 티타늄의 발색효과 (Color Evolution in Anodized Titanium)

  • 송오성;홍석배;이정임
    • 한국표면공학회지
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    • 제35권5호
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    • pp.325-329
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    • 2002
  • We investigated the oxide thickness and color evolution with the oxidation temperatures between $370^{\circ}C$ and $950^{\circ}C$ for 30 minutes in an electric furnace. Oxide thickness and color index were determined by cross sectional field emission scanning electron microscopy (FESEM) images and digital camera images, respectively. We confirmed that thermal oxidation was suitable for the mass production of color-titanium products, while coloring process window was narrow compared with anodizing oxidation process.

Precipitation of Manganese in the p-Xylene Oxidation with Oxygen-Enriched Gas in Liquid Phase

  • Jhung, Sung-Hwa;Park, Youn-Seok
    • Bulletin of the Korean Chemical Society
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    • 제23권3호
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    • pp.369-373
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    • 2002
  • The liquid phase oxidation of p-xylene has been carried out with oxygen-enriched gas, and the manganese component was precipitated probably via over-oxidation to $Mn^{4+}$. The precipitation increased with rising oxygen concentration in the reaction gas and occurred mainly in the later part of the oxidation. The activity of the reaction decreased, and the blackening of the product and side reactions to carbon dioxide increased with the degree of precipitation. Precipitation can be decreased with the addition of metal ions, such as cerium, chromium and iron.

$\beta$-Sialon 소결체의 산화 거동 (Oxidation Behavior of $\beta$-Sialon)

  • 박용갑;장병국
    • 한국세라믹학회지
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    • 제26권3호
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    • pp.341-346
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    • 1989
  • In order to evaluate the oxidation behavior of $\beta$-Sialon, $\beta$-Sialon ceramics was prepared from Si3N4, Al2O3, AlN and Y2O3 system. The specimens were oxidized in an oxygen atmosphere at 1, 20$0^{\circ}C$ for 9days. Oxidation behavior was evaluated by weight gain oxidation process, surface roughness. Microscopy, EDX and X-ray diffraction analysis were also used for the evaluation. The weight and surface roughness ofoxidized specimens were increased with increasing the oxidation time. Oxidized products were mullite, $\alpha$-cristobalite, yttrium aluminum oxide and yttrium silicate oxide.

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