• Title/Summary/Keyword: organic-inorganic hybrid materials

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Preparation of CaO-SiO2-PEEK bio-composites and in-vitro Evaluation (CaO-SiO2-PEEK 생체복합체의 제조와 in-vitro 특성평가)

  • Kim Ill Yong;Cho Sung Baek;Kim Jong Ock;Shin Jong Woo;Lee Sung Ho;Park Joong Keun;Kim Taik Nam
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.287-292
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    • 2004
  • A bio-composites were prepared by mechanical mixing with bioactive sol-gel derived $CaO-SiO_2$ and organic PEEK for bone repairing hybrid materials. The composites were characterized by in-vitro test. A bonelike apatite was formed on the surface of all bio-composites in SBF test. The cell morphology and adhesion on the surface of the composites having below 30% PEEK were clearly observed in L929 cell experiment.

Technology and Application of Hybrid Insulation Film for Electric Magnet Wire (하이브리드 절연필름의 전동기권선 적용 특성 연구)

  • Han, Se-Won;Han, Dong-Hee;Kang, Dong-Phil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.210-211
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    • 2006
  • This study presents the technology and application of hybrid insulation film for electric magnet wire. In order to make the high efficient motor with high space factor, it is necessary to develop a self-lubrication heat-resistant insulation film that can be used when the space factor 70% or more. A key to achieving high windability is to increase the lubricity and bonding strength of vanish, which for a magnet wire generally determines the mechanical scratches characteristics. Effective ways to reduce scratches include improving insulation film prepared by organic and inorganic hybrid synthesis methods.

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Synthesis of $SiO_2$ nanoparticles self-assembled thin film by organic.inorganic hybrid method

  • Hu, Yi;Lyu, Jhong-Ming;Liu, Tung-Cheng;Liu, Jiun-Shing
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1538-1541
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    • 2009
  • Amphiphobic thin films for touched panel application was prepared by $SiO_2$ nanoparticles self-assembled nanostructure. Silicon dioxide nano spheres were prepared by sol-gel method and well dispersed in a solution with surfacants of low surface energy. Nanostrcture thin films were obtained by spin coating technologies.

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Thermally Curable Organic-inorganic Hybrid Coatings on Ophthalmic Lenses by the Sol-Gel Method (졸-겔법에 의한 안경렌즈의 열경화형 유-무기 하이브리드 코팅)

  • Yu Dong-Sik;Lee Ji-Ho;Ha Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.3
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    • pp.465-470
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    • 2006
  • Coating are needed on ophthalmic lenses to enhance both the mechanical durability of the relatively soft plastic surface and the optical performance of lenses. Organic-inorganic hybrid materials as molar ratio of 3-glycidoxypropyltrimethoxysilane(GPTS), methyltrimethoxysilane(MTMS) and tetraethyl orthosilicate(TEOS) were used to improve the surface characteristics and the optical properties on allyl diglycol carbonate lenses. Coating for these plastics were at $140^{\circ}C$ for 4hrs, applied using the sol-grl process flow-coating technique. The coated lens properties of transmittance, adhesion, pencil hardness, abrasion resistance, hot water resistance and chemical resistance were investigated. The optimum properties was obtained when the ratio of GPTS : MTMS : TEOS was 1:1:2, respectively.

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Development of anti-corrosive coating technique for alloy plated steel sheet using silane based organic-inorganic hybrid materials (Silane계 유무기 하이브리드 적용 합금도금강판 내식성 향상 코팅 기술 개발)

  • Park, Jongwon;Lee, Kyunghwang;Park, Byungkyu;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.6
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    • pp.295-303
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    • 2013
  • Silane surface treatments have been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. The silane performance is comparable to, or in some cases better than, that of chromate layers. Based on the tetra-ethylorthosilicate(TEOS) and methlyl trieethoxysilane(MTES), inorganic sol was synthesized and formed hybrid networks with $SiO_2$ nano particle and polypropylene glycol(PPG) on Zn alloyed steel surface. According to SST results, addition of 10nm and 50nm $SiO_2$ nanoparticle in synthesized solution improved anti-corrosion property by its shear stress relaxation effect during curing process. Also, SST results were shown that anti-corrosive property was affected by the amounts of organic compounds.

Photostability Evaluation of a New Sunscreen Agent, Methoxycinnamidopropyl Polysilsesquioxane (신규 자외선차단제인 Methoxycinnamidopropyl Polysilsesquioxane의 광안정성 평가)

  • Jung, Taek-Kyu;Kim, Young-Back;Yoon, Kyung-Sup
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.3
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    • pp.227-236
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    • 2011
  • The new sunscreen agent, methoxycinnamidopropyl polysilsesquioxane, is manufactured as polymeric particles with an organic/inorganic hybrid composition. We have already reported the manufacturing method, physical properties, and sunprotection effects of methoxycinnamidopropyl polysilsesquioxane. In this study, we evaluated the photochemical properties and photostabilities of methoxycinnamidopropyl polysilsesquioxane that has the same functional group as a typical organic sunscreen agent, ethylhexyl methoxycinnamate (EHMC). Using the correlation of UV absorbance and fluorescence, we studied photostabilizers to enhance the photostability of methoxycinnamidopropyl polysilsesquioxane. Finally, we confirmed that octocrylene, ethylhexyl methoxycrylene, and bis-ethylhexyloxyphenol methoxyphenyl triazine were good photostabilizers for methoxycinnamidopropyl polysilsesquioxane.

Gel Polymer Electrolytes Derived from a Polysilsesquioxane Crosslinker for Lithium-Sulfur Batteries (리튬-황 전지용 폴리실세스키옥산 고분자 가교제로 제조된 겔 고분자 전해질의 전기화학적 특성)

  • Kim, Eunji;Lee, Albert S.;Lee, Jin Hong
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.467-471
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    • 2021
  • A ladder-like polysilsesquioxane (LPMA64) functionalized with a crosslinkable group was synthesized and used for the preparation of organic-inorganic hybrid gel polymer electrolytes through a thermal crosslinking process of the liquid electrolytes. A small weight percent of LPMA64 polymer crosslinker (5 wt%) was able to form a well-developed network structure, resulting in good dimensional stability with high ionic conductivity. The lithium-sulfur batteries fabricated with organic-inorganic hybrid gel polymer electrolytes exhibited stable C-rate and cycling performance with excellent Coulombic efficiency due to the alleviated lithium polysulfide shuttling effect during prolonged cycling. The result demonstrates that the organic-inorganic hybrid gel polymer electrolytes could be a promising candidate electrolyte for application in lithium-sulfur batteries.

Analysis of FTIR Spectra in Organic Inorganic Hybrid Type SiOC Films (유무기 하이브리드 SiOC 박막의 화학적 이동에 대한 FTIR 스펙트라 분석)

  • Oh Teresa
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.42 no.6 s.336
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    • pp.17-22
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    • 2005
  • Organic-inorganic hybrid type thin films are the next generation candidates as low-k materials. SiOC films are analyzed the bonding structure by the red and blue chemical shift using the fourier transform infraredspectra. Conventional chemical shift of organic chemistry is a red shift, but hybrid type SiOC films were observed the red and blue shift. The chemical shift originates from the interaction between the C-H bond and high electronegative atoms, and the blue shift in SiOC films is caused by the porosity due to the increase of the electron rich group such as much methyl radicals. The bonding structures of SiOC films are also divided into the Si-O-C cross-link structure and the Si-O-C cage-link structure due to the chemical shifts. The Si-O-C cross-link structure progressed the adhesion attributed to the C-H bond elongation in the reason of the red shift, and the dielectric constant also decreases.