• Title/Summary/Keyword: organic pollutants

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Improvement of Pressurized MF Pretreatment in MF/RO Process for Reuse (하수방류수 재이용 MF/RO 공정에서 가압식 MF의 전처리 성능 향상 방안 연구)

  • Na, Yumee;Park, Yong-Min;Lee, Yang-Woo;Kim, Won Kyong;Kim, Ji-Tae;Cho, Il-Hyoung
    • Membrane Journal
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    • v.24 no.5
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    • pp.350-357
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    • 2014
  • Pressurized MF membranes are used to remove suspended solid and colloidal materials of wastewater treatment plant effluent as the pretreatment of RO in reuse water production process. Membrane operation data and pollutants removal efficiency are investigated using 100 t/d scale pilot plant in J wastewater treatment plant located in Namyangju city. 40 LMH flux of pressurized MF membrane are obtained in various turbidity and temperature condition. Coagulation of dissolved organic enables flux improvement of MF from 40 LMH to 60 LMH. Pressure drop of 1st RO elements rapidly increased after long-term pause, which is because the complex contamination of organic matter and ionic substances of pluming systems.

Evaluation of Drainage by Near Infrared Spectroscopy

  • Takamura, Hitoshi;Miyamoto, Hiroko;Mori, Yoshikuni;Matoba, Teruyoshi
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1271-1271
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    • 2001
  • Water pollutants in drainage mainly consist of organic compounds. Hence, total organic carbon (TOC), chemical oxygen demand (COD), and biochemical oxygen demand (BOD) were generally used as the indices of pollution. However, these values are determined by special analyzer (TOC), titration method (COD), or microbe culture (BOD). Therefore, the development of simple and easy methods for the determination of water pollution is required. The authors reported the evaluation of water pollution by near infrared (NIR) spectroscopy in a model system with food components (Takamura et al. (200) Near Infrared Spectroscopy: Proceedings of 9th International Conference, pp. 503-507). In this study, the relationship between NIR spectra and drainage was investigated in order to develop a method for evaluation of drainage by NIR. Drainage was obtained in Nara Purification Center. The ranges of TOC, COD, and BOD were 0-130, 0-100 and 0-200, respectively. NIR transmittance spectra were recorded on NIR Systems Model 6250 Research Composition Analyzer in the wavelength range of 680-1235 and 1100-2500 nm with a quartz cell (light path: 0.5, 1, 2, 4 and 10mm) at 10-40. Statistical analysis was performed using NSAS program. A partial least squares (PLS) regression analysis was used for calibration. As the result, a good correlation between the raw NIR spectra and OC was obtained in the calibration. The best light path was 10 and 0.5mm in the wavelength range of 680-1235 and 110-2500nm, respectively. In the calibration, correlation coefficients(R) were 096-0.97 in the both range. In the prediction, however, a good correlation (R=0.89-0.96) was obtained only in the range of 6801235 nm, Similar results were obtained in the cases of COD and BOD. These results suggest the possibility that NIR spectroscopy can be used to evaluate drainage.

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Characteristics of Nonpoint Source Pollution from a Reclaimed Rice Paddy Field (계화 간척지구 강우 유출수의 비점오염원 유출특성에 관한 연구)

  • Lu, Weiwei;Yi, Qitao;Yu, Jianghua;Kim, Young-Chul
    • Journal of Wetlands Research
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    • v.11 no.3
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    • pp.9-19
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    • 2009
  • This research addressed nonpoint source (NPS) pollution characteristics in a reclaimed rice paddy field. The paddy has an area of around 2,998 ha and is divided as two sub-watersheds, whose areas are 1,181 ha and 1,817 ha, respectively. Monitoring of hydrologic runoff and NPS pollution was undertaken during three-month period from June to August, 2008. Totally, three sampling trips were made when rainfall depth were 66.0 mm, 23.5 mm, and 23.0 mm, respectively. Generally pollution load increased with the heavier cultivation activity in Korea. Exported pollutants from the rice paddy, including TSS, TN and TP, have same levels as forest discharge. Organic nitrogen is main pattern but it mainly exists in the forms of dissolved organic nitrogen (DON). For phosphorus, dissolved inorganic phosphorus (DIP) takes the main part although part of them is associated with fine particles. This is different compared with other watersheds, where particles-associated phosphorus is the main form.

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Health Risk Assessment by Potential Exposure of NO2 and VOCs in Apartments (공동주택내 이산화질소(NO2) 및 휘발성유기화합물(VOCs) 노출에 따른 건강 위해성 평가)

  • Jung, Soon-Won;Yang, Won-Ho;Son, Bu-Soon
    • Journal of Environmental Health Sciences
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    • v.33 no.4
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    • pp.242-249
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    • 2007
  • Indoor air quality has become a topic of interest and concern. Especially changes in construction design and the increased use of synthetic products may result in an increasing of complaints and health effects about the quality of indoor air at home. In this study, nitrogen dioxide($NO_2$) and volatile organic compounds(VOCs) within new and established apartments on the basis of 4 years of building year were measured every 3 days consecutively during 60 days. We selected each 10 house in Seoul, Asan and Daegu, respectively, and produced risk numbers for hazard quotients, and predicted increases in incidence of cancer. The calculations were made for the adult with default exposure values and also made for a worst case scenario using Monte-Carlo simulation as describing the reasonable exposure(RME). Mean of Monte carlo analysis by benzene, in the construction under 4 years (male: $9.2{\times}10^{-5}$, female: $1.0{\times}10^{-4}$) and over 4 years (male: $6.8{\times}10^{-5}$, female: $8.3{\times}10^{-5}$) exceeded $10^{-6}$ of permitted standards in US EPA, RME of Monte carlo analysis. In construction under 4 yews (male: $9.9{\times}10^{-3}$, female: $9.6{\times}10^{-3}$) and over 4 years (male: $9.8{\times}10^{-3}$, female: $7.8{\times}10^{-3}$) exceeded $10^{-4}$ of maximum permitted standards in US EPA. The hazard index of non-carcinogenic pollutants by nitrogen dioxide, toluene, m,p-xylene and o-xylene, both male and female in apartment constructed under 4 yews and over 4 years was found less than the permitted standards of hazardous health effects in CTE. Significant cancer risks and non-cancer hazard quotients were predicted in under 4 yews of building year.

A Study on the VOCs Emission Characteristics by the Light Duty Diesel and LPG Fueled Vehicles (소형승합차량 및 RV차량의 휘발성 유기 화합물 배출특성 변화에 관한 연구)

  • Eom, Myung-Do;Ryu, Jung-Ho;Han, Jong-Su;Lyu, Young-Sook;Kim, Dae-Wook;Kim, Jong-Choon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.1
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    • pp.8-13
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    • 2008
  • Emissions from automobiles have long been considered a prime source of pollutants involved in smog formation and ozone production. Especially VOCs are associated with serious environmental problems such as photo-chemical smog as well as human health effects. Since motor vehicles are a major source of VOCs, estimating of emission from mobile source is the most important factor to control VOCs. VOCs are emitted from various pollution like motor vehicles, mobile and stationary source that has characteristics of toxicity, cancer-causing, bio-accumulation, durability in air and diffusion can exert a bad influence upon human health and environment. However we don't have any standard or regulation about VOCs emissions. This study is summarized as VOCs emission characteristics from in-use light-duty diesel and LPG fueled vehicles. The vehicle exhaust-gas test mode is CVS cycle and nier-10 cycles that developed on EPA and National Institute of Environmental Research. TO-14 method (Toxic Organic) was chosen for VOCs analysis from EPA in USA. This study results will be useful when make a emission factor and rule making of emission standard about domestic VOCs emission for the improve to air condition.

A Study on Installation of Removal Device for Volatile Organic Compounds from Petrochemical Plant (석유화학 공장에서 VOCs 제거시설 설치사례 연구)

  • 김석택
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.95-101
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    • 2000
  • High growth of economy and industrial development was produced every air pollutants, that is, SOx, NOx, dust, VOCs and malodorous gas was produced. Recently, volatile organic compounds(VOCs) was bring about very serious environmental problems. Ulsan petrochemical complex was densely a large scale of petrochemical plant. This study was carried out to select treatment equipment of VOCs produced from petrochemical plant, and has compared with Carbon filter, Regenerative thermal oxidation(RCO) and Flare stack for technical merit and demerit but also initial investment and operating cost.

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Source Tracking of Particular Matters using Stable Isotope Analysis and Water Quality Characteristics in Gulpo and Anyang Stream, Han-River (한강수계 굴포천과 안양천에서 안정동위원소와 수질 특성을 이용한 입자성 물질의 기원 추적)

  • Hong, Jung-Ki;Im, Jong Kwon;Son, Ju Yeon;Noh, Hye-Ran;Yu, Soon-Ju;Lee, Bo-Mi
    • Journal of Korean Society on Water Environment
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    • v.36 no.2
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    • pp.116-124
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    • 2020
  • This study aims to identify the characteristics of organic matter and pollutant sources using water quality and stable isotope ratios (δ15N, δ13C) of the two inflow tributaries (Gulpo (GP) and Anyang (AY) streams). Water samples were analyzed in June and September 2018, and the results showed that the concentrations of nutrients, such as TN and NO3-N, were increased at GP4, which is located at the downstream of sewage treatment facilities(STFs). TOC and TN ratios showed a strong positive correlation (R2 = 0.77, p<0.01) at all points except for GP4. The results of GP's stable isotope ratio analysis do not appear to be a constant cluster compared to AY because GPs with large amounts of pollutants from the industry (metal processing companies, etc.) have less tributary, shorter waterway and significantly different external sources. This could be attributed to different sources of external inflow despite its smaller number of tributaries and shorter waterways than AY. In the first half of the year, the δ155N of GP4 was affected by discharge of STFs, while AY3 seemed to have an influence of tributary than the discharge of STFs. Consequently, using water quality, stable isotope ratio and C/N, the sources of contamination in two streams with different contaminants were identified and origin was estimated.

Risk Assessment of Aldehydes and Volatile Organic Compounds in the National Library of Korea Archive (국립중앙도서관 귀중서고 내 알데히드류 및 휘발성유기화합물(VOCs)에 대한 건강위해성평가)

  • Lee, Hye-Won;Lim, Hui Been;Lee, Kwi-Bok;Park, So Yeon;Jeon, Jeong In;Lee, Cheol Min
    • Journal of Environmental Science International
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    • v.29 no.6
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    • pp.673-682
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    • 2020
  • This study investigates the concentration distribution of aldehydes and volatile organic compounds (VOCs) in the archive of the National Library in Korea and evaluates the health risks to workers from hazardous chemicals. Acetaldehyde had the highest concentration among the nine species of aldehydes present in the archive and the concentration of toluene was the highest among the six species of VOCs. Most of the detected substances showed that their indoor concentrations were higher than the outdoor ones, suggesting the possibility of indoor sources of aldehydes and VOCs. The evaluation of health risks for workers based on these measurement results showed that not all substances were hazardous to the human body. However, considering the possibility of the presence of indoor sources and the potential limits of our study owing its short period, it is necessary to conduct long-term studies on the concentration distribution of indoor pollutants in the archive environment.

Heavy Metal Contamination in Sediments by Herbei Sprit Oil Spill (허베이 스피리트 원유 유출 사고에 의한 퇴적물의 중금속 오염)

  • Song, Yun Ho;Choi, Man Sik;Woo, Jun Sik;Sim, Won Joon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.18 no.2
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    • pp.70-79
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    • 2013
  • Since crude oil contains various pollutants including heavy metals, the environmental impact should be assessed for heavy metals as well as oil itself. In order to estimate the extent of heavy metal contamination, surface sediments were collected at the intertidal and coastal zone around the Herbei sprit oil spill area during December 2007 and January 2008. Organic carbon, sulfur and heavy metals were determined to assess heavy metal contamination in sediments. The crude oils contained C, S, V and Ni, but little toxic metals such as As, Cd, etc. From organic carbon content, the highest contaminated site was estimated that oils contributed to sediments up to 10%, and this site showed high V concentration. Potentially contaminated sediments by crude oil could be differentiated from unaffected sediments through V/Al and Ni/Al ratios, which can be used as indicators of oil contamination even after the oils were fully degraded.

Extension Possibility of Indoor Air Standards in Office Building by Health Risk Assessment (건강위해성평가에 의한 사무실 실내공기오염물질의 관리항목 확대)

  • Roh, Young-Man;Lee, Cheol Min;Kim, Yoon Shin;Kim, Seok Won;Kim, Chi-Nyon;Kim, Hyun-Wook;Cho, Kee Hong;Choi, Ho Chun;Kim, Jung Man
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.1
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    • pp.54-67
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    • 2006
  • This study was performed to deduct the extension possibility of the standards establishment for $NO_2$, $O_3$, Asbestos, Radon, total volatile organic compounds (TVOC) excluded in the indoor air part of Industrial Safety Acts in Korea. The air pollutants were sampled for 30 office buildings from August to September, 2005 in the metropolitan area. The airborne concentrations of $NO_2$, $O_3$, Radon and TVOC were 0.0092 ppm, 0.0035 ppm, 0.57 pCi/L and $423{\mu}g/m^3$, respectively. The management plan and reduction methods is required in the aspect of indoor air quality(IAQ) because the emission sources of those also exist in indoor as well as outdoor even though those were not exceeded the standards of the Ministry of Environment in Korea. The standard for TVOC in the new and remodeling office has to be established based on the risk assessment when hazard index exceeded "1" in the worst case scenario. In the state of art, the management of each volatile organic compounds has a difficulty due to not enough data for toxicological reference. Therefore, it is suggested that first of all, the standard for TVOC be established and then expanded to each materials for decision-making of improvement of IAQ in office.