• 제목/요약/키워드: organic pollutants

검색결과 790건 처리시간 0.026초

진해만 패류양식장의 저질에 관한 연구 (Study on Bottom Mud of Shellfish Farms in Jinhae Bay)

  • 조창환;양한변;박경양;염말구
    • 한국수산과학회지
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    • 제15권1호
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    • pp.35-41
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    • 1982
  • 진해만 패류양식장의 어장가치를 진단하는 기초자료를 준비코자 양식장 저이의 오염정도를 구명하고 아울러 저이오염원의 기원을 파악코자 1981년 하계 중 만내 87개의 조사지점에서 저직성분을 조사하였다. 1. 저는 만 전체에 걸쳐 이질로 덮혀 있었다. 2. 페오파이친색소양은 $7.6-48.2{\mu}g/g$건이, COD양은 9.7-38.5 mg/g건이, 강열감양은 $8.1-14.2\%$ 그리고 유화물양은 0.1mg/g 이하로부터1.07mg/g 까지 이었다. 3. 상기 4개 항목의 양의분포는 다함께, 진해만 입구부인 잠도근처에서 견내양쪽으로 갈수록 많았으며, 저이오염도는 패류양식장이 많은 가조도 서부해역이 가장 높았다. 4. 가조도 서부해역의 대부분이 COD와 유화물양에 있어 부영양역의 상한치를 상인하고 있었다.5. 이오염의 주원은 양식패와 부착동물 배비물인 유기물의 축적이라 추측되었다.

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하수의 최종 유출수 수질 개선을 위한 침전조 모형실험에 적용한 끈상 미생물접촉재와 미나리의 고도처리효율에 관한 연구 (Advanced Treatment Efficiency of Biological String Media and Oenanthe javanica for Effluent Quality Improvement in the Sedimentation Model Plant)

  • 배준삼;이상호
    • 한국산학기술학회논문지
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    • 제7권3호
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    • pp.440-447
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    • 2006
  • 본 연구의 목적은 미나리와 끈상 미생물접촉재를 이용하여 생활하수의 하수처리장 방류수의 수질 개선을 위함이다. 최종 방류수의 수질을 개선하기 위한 침전조 모형 플랜트를 2개 제작하여 실험하였는데, 하나(Tank 1)는 기존 하수처리장 침전조와 같게 제작 하였으며, 다른 하나의 침전조(Tank 2)는 침전조의 수초섬 상부에는 미나리를 식재하고 하부에는 끈상 미생물 접촉재를 배치하였다. 유기 오염물질인 BOD, 부유고형물질인 SS, 질소 그리고 인에 대한 고도처리 효율을 검증하였다. 실험 결과 Tank 2에서 유출되는 배출수가 Tank 1에서 배출되는 유출수보다 처리 효율이 향상되었다. 처리 효율을 살펴보면, Tank 1보다 Tank 2 유출수의 BOD는 $7.9%{\sim}38.8%$가 향상되었으며, 부유고형 물질인 SS는 $14.3%{\sim}60.0%$ 향상되었다. 부영양화 물질인 T-N은 $9.6%{\sim}31.5%$ 향상되었으며, T-P는 $33.0%{\sim}80.0%$까지 향상되었다. 처리 효율로 판단하면 T-P와 SS 제거효율이 BOD와 T-N보다 높았다.

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정수처리에서의 생물활성탄 공정 (Biological Activated Carbon (BAC) Process in Water Treatment)

  • 손희종;유수전;노재순;유평종
    • 대한환경공학회지
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    • 제31권4호
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    • pp.308-323
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    • 2009
  • 생물활성탄 공정은 정수처리에서 획기적인 공정으로 평가받고 있으며, 전 세계적으로 많은 정수장에서 BAC 공정을 채택하여 운전하고 있다. BAC 공정의 장점은 활성탄에 흡착된 오염물질들이 활성탄 표면에서 서식하고 있는 다양한 미생물 집합체(생물막)에 의해 생물분해되어 자연적으로 활성탄의 재생이 이루어져 활성탄 사용기간의 연장을 유도하여 정수처리 비용을 감소시킬 수 있다는 것이다. 또한, 유입수중의 생분해 가능한 유기물질들을 제거하여 배 급수관망에서 미생물의 재성장을 억제하는데 탁월하다. 그러나 BAC 공정의 효율이 활성탄 표면에 형성되어 있는 생물막에 의해 제한되어지는 문제점도 있다. 본 논문에서는 GAC에서 BAC로의 전환, BAC 생물막의 특성, 오염물질의 제거 메카니즘, BAC 공정에 영향을 미치는 인자들, BAC 공정의 제어 및 BAC 공정의 모델링에 대해 크게 여섯 부분으로 상세하게 기술하였다.

Ecological and human health risk from polychlorinated biphenyls and organochlorine pesticides in bivalves of Cheonsu Bay, Korea

  • Choi, Jin Young;Yang, Dong Beom;Hong, Gi Hoon;Kim, Kyoungrean;Shin, Kyung-Hoon
    • Environmental Engineering Research
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    • 제21권4호
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    • pp.373-383
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    • 2016
  • Cheonsu Bay, one of the most important in Korea as a coastal fishery is a semi-enclosed bay that is surrounded by large farmlands and industrial areas. This coastal environment has been affected by anthropogenic pollutants, such as polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs). The objectives of this study were to investigate the distribution of PCBs and OCPs in sediment, Manila clams, and mussels from Cheonsu Bay; the accumulation pattern of these chemicals in these bivalves in relation to seasonal changes; and the ecological risk from sediments and the risk to the Korean population from the consumption of these bivalves. The levels of ${\Sigma}PCBs$, ${\Sigma}DDT$, and ${\Sigma}HCHs$ were 69.3-109, 40.3-49.3 and 6.25-17.8 ng/g lipid in Manila clams, and 70.6-159, 38.6-102 and 9.00-13.5 ng/g lipid in Mussels. Significant seasonal variations in PCBs and OCPs concentrations were observed in the two bivalves, suggesting that the accumulation of PCBs and OCPs in these species is related to their spawning times. The dietary intake of these two bivalves and the resulting lifetime cancer risk (LCR) and non-cancer risk were calculated for the human population. The consumption of these bivalves seemed to be safe in relation to human health with negligible LCR and non-cancer risk.

황복(Takifugu obscurus)에 대한 중금속, 유기주석화합물 및 다환방향족탄화수소(PAHs)의 급성 독성 (Acute Toxicity of Dissolved Inorganic Metals, Organotins and Polycyclic Aromatic Hydrocarbons to Puffer Fish, Takifugu obscurus)

  • 이정석;이규태;김동훈;김진형;한경남
    • Environmental Analysis Health and Toxicology
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    • 제19권2호
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    • pp.141-151
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    • 2004
  • We exposed juvenile puffer fish, Takifugu obscurus(30 days after hatching) to various aqueous pollutants including 4 kinds of inorganic metals (Ag, Cd, Cu and Hg), 2 organotin compound.; (tributyltin [TBT] and triphenyltin[TPhT]) and 5 polycyclic aromatic hydrocarbon (PAH) compounds (chrysene, fluoranthene, naphthalene, phenanthrene and pyrene) to estimate median lethal concentrations (LC50s) of each pollutant after the 96-hour acute exposure. Among the inorganic metals, Hg (52 $\mu\textrm{g}$/L; 96-h LC50) was most toxic to test animals and followed by Ag (164 $\mu\textrm{g}$/L), Cu (440 $\mu\textrm{g}$/L) and Cd (1180 $\mu\textrm{g}$/L). Aqueous TBT was more toxic between the two organotins; the 96-h LC50 for TBT (5.1 $\mu\textrm{g}$/L) was 3 times lower than that of TPhT (17.3 $\mu\textrm{g}$/L). The acute toxicity of PAH compounds was highest for chrysene (1.5 $\mu\textrm{g}$/L; 96-h LC50) and decreased in the order of pyrene (65 $\mu\textrm{g}$/L) > fluoranthene (158 $\mu\textrm{g}$/L) > phenanthrene (432 $\mu\textrm{g}$/L) > naphthalene (8690 $\mu\textrm{g}$/L). The toxicity of PAH compounds wat closely related to their physico-chemical characteristics such as $K_{ow}$ and water solubility, and well explained by simple QSAR relationship. The sensitivity of puffer fish to various inorganic and organic pollutants was generally comparable to various fish species widely used as standard test species in previous studies and further evaluation should be conducted to develop adequate testing procedure for T. obscurus when used in various toxicity tests.

수도권 초미세먼지 농도모사: (V) 북한 배출량 영향 추정 (PM2.5 Simulations for the Seoul Metropolitan Area: (V) Estimation of North Korean Emission Contribution)

  • 배민아;김현철;김병욱;김순태
    • 한국대기환경학회지
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    • 제34권2호
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    • pp.294-305
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    • 2018
  • Quantitative assessment on the impact from North Korean emissions to surface particulate matter(PM) concentration in the Seoul Metropolitan Area (SMA), South Korea is conducted using a 3-dimensional chemistry transport model. Transboundary transport of air pollutants and their precursors are important to understand regional air quality in East Asian countries. As North Korea locates in the middle of main transport pathways of Chinese pollutants, quantifiable estimation of its impact is essential for policy making in South Korean air quality management. In this study, the Community Multiscale Air Quality Modeling System is utilized to simulate regional air quality and its sensitivity, using the Comprehensive Regional Emissions inventory for Atmospheric Transport Experiment 2015 and the Clean Air Policy Support System 2013 emissions inventories for North and South Korea, respectively. Contributions were estimated by a brute force method, perturbing 50% of North and South Korean emissions. Simulations demonstrate that North Korean emissions contribute $3.89{\mu}g/m^3$ of annual surface PM concentrations in the SMA, which accounts 14.7% of the region's average. Impacts are dominant in nitrate and organic carbon (OC) concentrations, attributing almost 40% of SMA OC concentration during January and February. Clear seasonal variations are also found in North Korean emissions contribution to South Korea (and vice versa) due to seasonal characteristics of synoptic weather, especially by the change of seasonal flow patterns.

낙동강 수계 자연습지의 계절별 수질변화특성 분석 (Analysis of Seasonal Water Quality Variation of a Natural Wetland in the Nakdong River Basin)

  • 김영윤;이광섭;이석모;강대석;성기준
    • 한국물환경학회지
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    • 제25권5호
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    • pp.713-719
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    • 2009
  • A natural wetland in the Nakdong River basin which effectively removes non-point source pollutants was investigated for 2 years to understand wetland topography, vegetation types, and water quality characteristics. The water depth of the natural wetland was in the range of 0.5~1.9 m which is suitable for the growth of non-emergent hydrophytes. The wetland has a high length to width ratio (3.3:1) and a relatively large wetland to watershed area ratio (0.057). A broad-crested weir at the outlet increases the retention time of the wetland whose hydrology is mainly dependent on storm events. The concentrations of dissolved oxygen in the growing season and the winter season showed anoxic and oxic conditions, respectively. Diurnal variations of DO and pH in the growing season were also observed due to weather change and submerged plants. COD and TP concentrations were low in the winter season due to low inflow rate and increased retention time. Increased TP concentrations in the spring season were caused by degradation of dead wetland plants. Nitrogen in the wetland was mostly in organic nitrogen form (>75%). During the growing season, ammonium concentration was high but nitrate nitrogen concentration was low, possibly due to anoxic and low pH conditions which are adverse conditions for ammonificaiton and nitrification. The results of this study can be used as preliminary data for design, operation, monitoring and management of a constructed wetland which is designed to treat diffuse pollutants in the Nakdong river watershed.

UV조사에 의한 방향족오염물의 분해 (Degradation of Aromatic Pollutants by UV Irradiation)

  • 민병철;김종향;김병관
    • 공업화학
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    • 제8권3호
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    • pp.502-509
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    • 1997
  • 방향족 오염물을 UV산화-고도산화처리기술로 처리할 때, 여러 가지 반응조건에 따른 분해효율에 대해 고찰하였다. 벤젠 50ppm, 에틸벤젠 150ppm, 크실렌 250ppm을 각각 초기농도로하여 UV조사 하에서 시간변화에 따른 분해실험을 행한 결과, 반응 1시간 후 약 95% 이상의 분해율을 나타내었으나, 톨루엔의 경우에는 43%의 분해율을 보였다. 단일성분이 혼합성분에서 보다 분해가 좋았으며, pH변화에서는 벤젠은 pH변화에 관계없이 분해가 잘 되었으며, 에틸벤젠 92%(pH 4.0), 90%(pH 6.4), 91%(pH 10.0), 크실렌 95%(pH 4.0), 90%(pH 6.4), 92%(pH 10.0), 그러나 톨루엔은 80%(pH 4.0), 43%(pH 6.4), 70%(PH 10.0)의 분해율을 나타내었다. 방향족 오염물의 TOC 감소는 에틸벤젠을 제외하고는 유사 1차 반응속도식에 일치하였으며, 이로부터 속도상수를 결정할 수 있었다.

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포도밭에 대한 비점오염원 유출특성 해석 (Analysis of Nonpoint Sources Runoff Characteristic for the Vineyard Areas)

  • 윤영삼;이상협;유재정;이재관
    • 한국환경과학회지
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    • 제20권3호
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    • pp.361-372
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    • 2011
  • This study analyzed the characteristics of stormwater runoff by rainfall type in orchard areas for two years. Effluents were monitored to calculate the EMCs and runoff loads of each pollutant. The runoff characteristics for nonpoint sources from vineyards were also inspected based on independent variables that affect runoff such as rainfall and rainfall intensity. The average runoff loads of each pollutant from vineyard_A and vineyard_B were found as follows: BOD 39.13 mg/$m^2$, COD 112.13 mg/$m^2$, TOC 54.98 mg/$m^2$, SS 1,681.8 mg/$m^2$, TN 18.29 mg/$m^2$, and TP 4.06 mg/$m^2$, which indicates that the COD's runoff load was especially high. The average EMCs from vineyard_A and vineyard_B, which represents the quality of rainfall effluent, were also analyzed: BOD 3.5 mg/L, COD 11.5 mg/L, TOC 5.2 mg/L, SS 211.7 mg/L, TN 1.774 mg/L, and TP 0.324 mg/L. This suggested that the COD, as an indicator of organic pollutants, is high in terms of EMCs as well. As rainfall increased, the EMCs of BOD, COD, TOC and SS kept turning upward. At a point, however, the high rainfall brought about dilution effects and began to push down the EMCs. Higher rainfall intensities led to the increase in the EMCs that displays the convergence of rainfall. Low rainfall intensities also raised pollutant concentrations, although the concentrations themselves were slightly different among pollutants.

학교건물의 실내공기환경 개선방안에 관한 건축계획적 연구 (Architectural Implementation of the Indoor Air Quality in the Elementary School Classroom)

  • 구재오;배선철;김곤
    • KIEAE Journal
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    • 제7권1호
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    • pp.15-22
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    • 2007
  • Indoor air quality(IAQ) problems are not limited to large office buildings that are inadequately operated. In fact, many school buildings have significant potentials of air pollution and indoor air pollutants may be of particular concern because it is estimated that most young students who are physically weak to the pollutants spend about 90% of their time in classrooms. The goal of the study is to provide academic and architectural information on the major factors that influence indoor air quality in the elementary school. In order to gain a better understanding of IAQ problems in schools, a series of measurement studies of indoor air quality were designed and 3 different elementary school buildings located in Chuncheon were selected. The levels of CO, $CO_2$, and total volatile organic compounds(TVOCs) including formaldehyde(HCHO), major concern of this study, were measured in absence of students after class. As the results, it is noticeable that most indoor air pollution comes from sources inside the building, which are, for example, adhesives, upholstery, manufactured wood products, art and scientific supplies. The level of CO was measured similarly to that of outdoors, which means no impact on the indoor air problems since it is lower than the code. Ventilation played an important role in the level of $CO_2$ of which difference was 1.7 times in rough and 230 % of difference in the level was detected among the 3 school buildings. This concludes that indoor air problems might be result of poor building design with inadequate location of corridors within space organization or occupant activity patterns of ventilation.