• Title/Summary/Keyword: organic method

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Fabrication of Large-Scale Single-Crystal Organic Nanowire Arrays for High-Integrated Flexible Electronics

  • Park, Gyeong-Seon;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.266.1-266.1
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    • 2013
  • Large-scale single-crystal organic nanowire arrays were generated using a direct printing method (liquidbridge- mediated nanotransfer molding) that enables the simultaneous synthesis, alignment and patterning of nanowires from molecular ink solutions. Using this method, single-crystal organic nanowires can easily be synthesized by self-assembly and crystallization of organic molecules within the nanoscale channels of molds, and these nanowires can then be directly transferred to specific positions on substrates to generate nanowire arrays by a direct printing process. Repeated application of the direct printing process can be used to produce organic nanowire-integrated electronics with two- or three-dimensional complex structures on large-area flexible substrates. This efficient manufacturing method is used to fabricate all-organic nanowire field-effect transistors that are integrated into device arrays and inverters on flexible plastic substrates.

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A Study on the preparation of optimum piezoelectric organic thin films of PVD method and switch characteristic (진공증착법을 이용한 최적의 압전성 유기박막의 제조와 스위치 특성에 관한 연구)

  • 박수홍;이선우;이희규
    • Journal of the Korean Vacuum Society
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    • v.8 no.3A
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    • pp.194-200
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    • 1999
  • In this paper studied was the piezoelectric properties of the $\beta$-PVDF organic thin films prepared by physical vapour deposition method. The molecular orientation of organic thin films was controlled by the application of an electric field and variation of substrate temperature during the evaporation process. Optimum conditions of manufacturing $\beta$-PVDF organic thin film by physical vapor deposition method is to keep at the substrate temperature of $80^{\circ}C$, at the applied electric field of 142.8 kV/cm. The voltage output coefficient increased from 1.39 to 7.04V increasing the force moment.

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A study on the economic background and management method in organic farming (유기농업의 경제적 배경과 경영방식에 관한 고찰)

  • Kim, Ho
    • Korean Journal of Organic Agriculture
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    • v.3 no.1
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    • pp.43-70
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    • 1994
  • Presently the concept of organic farming has not simply technical categories such as no agricul-tural chemicals and no chemical fertilizer but can be also extended to the categories of economics, food nutrition, environmental and philosophical aspects. Accordingly, in order to understand cor-rectly organic farming, it is necessary to look into the concept including these extended aspects. So the production and consumption activities of organic farming products are largely based on the fundamental philosophy of organic farming. That is, all the life that is included in an ecosystem has to live in symbiosis, which is based on life circulation principle. And if this circultaion system is destroyed, human life may be threatended. Farmers who produce organic farming prducts(organic farmer) receive price higher than general farmers. This study shows the gap of 46.9% in two products. Also, since the price of organic farming products is fluctuated less relatively, Organic farming pruducts can be competed against imported agricultural products in terms of food safety. And organic farming should be managed by crop rotation and composite farm management upon which the principle of material circulation is worked. This composite management is devided into 2 classes, which are individually livestock-have-composite management and regional composite management. These management method means that organic materials are crucial to maintain the structure and fertility and these organic materials are easily obtained from animal as by-products.

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Determination of the Formation Constants of Metal Complexes with Organic Acids by Adsorption Method (흡착법에 의한 금속이온과 유기산간의 착염 생성계수의 측정법)

  • Jae, Won-Mok
    • Journal of the Korean Chemical Society
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    • v.15 no.4
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    • pp.199-203
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    • 1971
  • The adsorption method for the determination of the formation constants of the metal complexes with organic acids was developed by using membrane filters. The adsorption method involved the measurements of radioactivities of the adsorbed metal on membrane filters and the filtrate solution after the radioactive metal ion were filtered through membrane filters in the presence of organic ions of varying concentration. Comparing the adsorption method with the ion exchange method, it was seen that the adsorption method was simpler and faster than the ion exchange method. As an example of the metal complex with organic acid yttrium citrate complex was chosen, and the formation constant of the complex obtained by the adsorption method showed $K_f=2.0{\times}10^{-4}(l. mole^{-1})$ at a pH of 7. Also the present study revealed that the carrierfree state of yttrium in aqueous solution was present in the completely ionized state.

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The Determination of Chemical Forms of Heavy Metals in Shooting Area Contaminated Soil Using Sequential Extraction Method (연속추출법을 이용한 사격장 오염토양 중 중금속의 화학적 형태 결정)

  • Moon, Gyeonghye;Park, Hongki;Yoo, Kyoungkeun;Manis Kumar, Jha;Richad Diaz, Alorro;Kim, Ju Yup
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.111-116
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    • 2015
  • The soil sample obtained from shooting area contaminated with Pb, Cu, and Zn was investigated to determine the chemical forms of heavy metals with Tessier’s sequential extraction method, which is constituted of five fractions such as ‘exchangeable’, ‘bound to carbonate’, ‘bound to oxide’, ‘bound to organic matter’, and residual fractions. The amount of organic matter was measured by loss on ignition (LOI) and then the results of ‘bound to organic matter’ and LOI were compared. The sequential extraction results show that 4.7%-45% of Pb, 6.2%-25.9% of Cu and 3.9%-15.3% of Zn belong to the ‘bound to organic matter’ fraction, but LOI result shows that only 1.0%-2.8% of organic matter exists in the soil sample. In heavy medium separation tests, because Pb and Cu extracted in ‘bound to organic matter’ and residual fractions were removed, the heavy metals in the fractions would exist as heavier forms. These results suggest that the part of heavy metal extracted in ‘bound to organic matter’ fraction would result from the oxidation of metallic forms by hydrogen peroxide and nitric acid used in the fraction, and, consequently, that the ‘bound to organic matter’ fraction should be investigated in detail to determine the removal method and treatment capacity when the Tessier’s sequential extraction method is used to examine heavy metal contaminants resulted from elemental metal like bullets.

Soil Organic Carbon Determination for Calcareous Soils (석회암 유래 토양의 토양유기탄소 분석법 연구)

  • Jung, Won-Kyo;Kim, Yoo-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.396-402
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    • 2006
  • Soil organic carbon has long been considered as the most critical factor to evaluate the soil quality, fertility, and fertilizer prescription. In addition, soil organic carbon may impact on greenhouse gas effects and global warming. Because of that, the management of soil organic carbon is increasingly important not only for improving soil quality but also for managing soil as a greenhouse gas source. Both wet and dry combustion have been used to determine soil organic carbon. Many benefits, such as automation and less labor, could the dry combustion method become more popular. Inorganic form of carbon could overestimate soil organic carbon when the dry combustion method was applied. Determination of soil inorganic carbon may contribute to the improved accuracy of soil organic carbon analysis using dry combustion method. Objectives of this research were 1) to develop soil inorganic carbon determination method using modified digital pressure calcimeter and 2) to evaluate soil organic carbon from calcareous soils using the dry and wet combustion method. Results showed that the significant linear relationship was found between soil inorganic carbon content and pressure calcimeter output. Inorganic carbon ranged from 22% to 28% of total carbon in the calcareous soil samples. Soil organic carbon content by dry combustion for calcareous soil was determined by subtracting inorganic carbon measured by the digital pressure calcimeter from total carbon. Soil organic carbon determined by dry combustion method was significantly correlated with that by wet combustion method. In conclusion, the digital pressure calcimeter may use to improve soil organic carbon determination for the calcareous soils by subtracting of soil inorganic carbon from total carbon determined by dry combustion method.

Effect of Template Removal on Synthesis of Organic-Inorganic Hybrid Mesoporous MCM-48

  • Zhao, Ya Nan;Li, San Xi;Han, Chong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3196-3202
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    • 2012
  • Post-synthesis is used to synthesize organic hybrid inorganic mesoporous sieves. In this method, the activity and structure of the base sieve are crucial to obtain the definable hybrid materials. The chemical and physical properties of the base can be largely changed either by the final step of its synthesizing processes, by template removal which is accomplished with the oxidative thermal decomposition (burning) method or by solvent extraction method. In this paper we compared two methods for the post-synthesis of organic hybrid MCM-48. When the template was extracted with HCl/alcohol mixture, the final product showed larger pore size, larger pore volume and better crystallinity compared to the case of the thermal decomposition. The reactivity of the surface silanol group of template free MCM-48 was also checked with an alkylsilylation reagent $CH_2=CHSi(OC_2H_5)_3$. Raman and $^{29}Si$ NMR spectra of MCM-48 in the test reaction indicated that more of the organic group was grafted to the surface of the sample after the template was removed with the solvent extraction method. Direct synthesis of vinyl-MCM-48 was also investigated and its characteristics were compared with the case of post-synthesis. From the results, it was suggested that the structure and chemical reactivity can be maintained in the solvent extraction method and that organic grafting after the solvent extraction can be a good candidate to synthesize a definable hybrid porous material.

Nanotransfer Printing for Large-Scale Integrated Nanopatterns of Various Single-Crystal Organic Materials

  • Baek, Jang-Mi;Park, Gyeong-Seon;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.361.2-361.2
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    • 2016
  • The manufacture of organic electronic circuits requires effective heterogeneous integration of different nanoscale organic materials with uniform morphology and crystallinity in a desired arrangement on a substrate. Herein, we present a new direct printing method, which enables monolithic integration of crystalline nanowire arrays with a diverse range of organic materials. In this method, we use a nanoscale patterned soft mold, which contains an assembly of simple nanoline patterns but, in combination with droplet of various organic inks, can produce a large-scale integration of various nanopatterns with multiple kinds of organic materials. The morphology of organic nanowires can controlled by nanoconfinement in nanoline of mold. And mutual alignment of nanopatterns can be controlled by adjusting the ink droplet size, number of droplets, ink deposition locations.

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The Study of Gas Sensor Using Rheological Properties of Polymeric Sensitive LB Films (고분자감응성 LB막의 유변학적인 특성을 이용한 가스센서 연구)

  • 강현욱;김정명;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.198-201
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    • 1997
  • The new system for identification of organic vapours and analysis method of mechanism between organic vapours and sensitive materials were attempted using the resonant resistance and resonant frequency of Quartz Crystal Analyzer (Q. C. A.). The resonant resistance shift means rheological changes in sensitive LB films occurred by the adsorption of organic vapours, while the resonant frequency shift represent the mass of organic vapour loaded in or on the sensitive LB films. It is thought that we can obtain more accurate response mechanism of organic vapour using the resonant frequency and resonant resistance diagram. The polymeric sensitive material were quantitively depositied using the LB method. In the experimental results, the adsorption behavior of organic vapour response can be decided by two type ; surface adsorption and penetration into sensitive material. Organic vapours had different positions in the Frequency-Resistance (F-R) diagram as to the kinds and concentrations of organic vapours. Thus F-R diagram can be applied to the development of one channel gas sensing system using the Quartz Crystal Analyzer.

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Pesticidal Activity of Environment friendly agricultural materials (EFAMs)

  • Park, J.H.;Han, E.J.;Hong, S.J.;Ahn, N.H.;Kim, Y.K.;Jee, H.J.
    • Korean Journal of Organic Agriculture
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    • v.19 no.spc
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    • pp.287-290
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    • 2011
  • Environment friendly agricultural material products (EFAMs) in current market were evaluated for their insecticidal or acaricidal activities. EFAMs were evaluated against Tetranychus urticae, Plutella xylostella, Myzus persicae and Nilaparvata lugens in spray method. Several EFAMs indicated high control value in spray method. Hatchability of T. urticae was relatively high after EFAM treatment. some materials show high insecticidal activities against P. xylostella larvae but not against eggs. Few mete rials showed more than 80% insecticidal activities against M. persicae and N. lugen. The control value of more than half the materials for pest control was lower than 60%. EFAMs containing S. flavescens, neem oil and Rape showed higher control value.