• 제목/요약/키워드: organic insulator

검색결과 192건 처리시간 0.029초

절연물질이 코팅된 활성탄의 벤젠 흡착특성 및 마이크로파에 의한 탈착에 관한 연구 (A Study on Adsorption Characteristics of Benzene over Activated Carbons Coated with Insulating Materials and Desorption by Microwave Irradiation)

  • 김기중;안호근
    • 공업화학
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    • 제19권4호
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    • pp.445-451
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    • 2008
  • 마이크로파를 이용하여 휘발성유기화합물(VOCs; Volatile Organic Compounds)로 오염된 활성탄을 재생하기 위하여, 절연물질로서 활석(Talc)과 Ni-Zn ferrite를 각각 활성탄에 코팅하여 벤젠의 흡착 및 탈착 특성을 조사하였다. 절연물질이 코팅된 활성탄의 물리적 특성 및 표면상태는 질소가스 흡착장치와 주사전자현미경(SEM)을 이용하여 각각 확인하였다. 비표면적과 벤젠에 대한 흡착량은 비례관계를 보였고, 활성탄에 활석이나 Ni-Zn ferrite를 코팅하면 마이크로파에 의한 불꽃방전을 억제할 수 있었다. 활성탄에 절연물질을 코팅하기 위해 사용한 바인더는 PS (potassium silicate)가 벤젠에 대한 흡착성능이 가장 우수한 것으로 나타났다. 마이크로파 출력에 따른 탈착량은 출력에 비례하는 경향을 보였고, 연속되는 흡착과 탈착과정이 5회 반복되더라도 재현성이 충분히 나타났다. 결과적으로 VOCs로 오염된 폐활성탄의 재생방법으로서, PS를 바인더로 사용하여 활석이나 Ni-Zn ferrite를 활성탄에 코팅하여 마이크로파로 탈착시키면 효과적임을 알 수 있었다.

유기물과 유무기 혼합 폴리머 게이트 절연체를 사용한 유기 박막 트랜지스터의 특성 (Characteristics of Organic Thin Film Transistors with Organic and Organic-inorganic Hybrid Polymer Gate Dielectric)

  • 배인섭;임하영;조수헌;문송희;최원석
    • 한국전기전자재료학회논문지
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    • 제22권12호
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    • pp.1009-1013
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    • 2009
  • In this study, we have been synthesized the dielectric layer using pure organic and organic-inorganic hybrid precursor on flexible substrate for improving of the organic thin film transistors (OTFTs) and, design and fabrication of organic thin-film transistors (OTFTs) using small-molecule organic semiconductors with pentacene as the active layer with record device performance. In this work OTFT test structures fabricated on polymerized substrates were utilized to provide a convenient substrate, gate contact, and gate insulator for the processing and characterization of organic materials and their transistors. By an adhesion development between gate metal and PI substrate, a PI film was treated using $O_2$ and $N_2$ gas. The best peel strength of PI film is 109.07 gf/mm. Also, we have studied the electric characteristics of pentacene field-effect transistors with the polymer gate-dielectrics such as cyclohexane and hybrid (cyclohexane+TEOS). The transistors with cyclohexane gate-dielectric has higher field-effect mobility, $\mu_{FET}=0.84\;cm^2/v_s$, and smaller threshold voltage, $V_T=-6.8\;V$, compared with the transistor with hybrid gate-dielectric.

유기 TFT로 구동한 유기 인광발광소자의 연구 (Organic Electrophosphorescent Device driven by Organic Thin-Film Transistor)

  • 김윤명;표상우;김준호;심재훈;정태형;김영관;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.312-315
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    • 2001
  • Recently organic electroluminescent devices have been intensively investigated for using in full-color flat-panel display. Since the quantum efficiency of electrophosphorescent device decrease rapidly as the luminance increase, it is desirable to operate the electrophosphorescent display with active matrix rather than passive matrix. Here we report the study of driving electrophosphorescent diode with all organic thin film transistor(OTFT). The structure of electrophosphorescent diode is ITO/TPD/BCP:Ir(ppy)$_3$/BCP/Alq$_3$/Li:Al/Al. In OTFT. polymer is used as an insulator and pentacene as an active layer. Detailed performance of the integrated device will be discussed.

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Development of High-Performance Organic Field-Effect Transistors via Surface-Mediated Molecular Ordering

  • Cho, Kil-Won;Kim, Do-Hwan;Park, Yeong-Don;Jang, Yun-Seok;Hwang, Min-Kyu;Lee, Hwa-Sung;Lim, Jung-Ah
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.147-148
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    • 2005
  • We report on high-performance organic field-effect transistors by promoting surface-mediated two-dimensional molecular ordering in organic semiconductor. To achieve this goal, we have controlled the intermolecular interaction at the interface between organic semiconductor and the insulator substrate.

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유기 TFT로 구동한 유기 인광발광소자의 연구 (Organic Electrophosphorescent Device driven by Organic Thin-Film Transistor)

  • 김윤명;표상우;김준호;심재훈;정태형;김영관;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.312-315
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    • 2001
  • Recently organic electroluminescent devices have been intensively investigated for using in full-color flat-panel display. Since the quantum efficiency of electrophosphorescent device decrease rapidly as the luminance increase, it is desirable to operate the electrophosphorescent display with active matrix rather than passive matrix. Here we report the study of driving electrophosphorescent diode with all organic thin film transistor(OTFT). The structure of electrophosphorescent diode is ITO/TPD/BCP:Ir(ppy)$_3$/BCP/Alq$_3$/Li:Al/Al. In OTFT, Polymer is used as an insulator and pentacene as an active layer. Detailed performance of the integrated device will be discussed.

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Vapor Deposition Polymerization 방법을 이용한 유기 박막 트렌지스터의 제작 (Fabrication of Organic Thin-Film Transistor Using Vapor Deposition Polymerization Method)

  • 표상우;김준호;김정수;심재훈;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.190-193
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    • 2002
  • The processing technology of organic thin-film transistors (Ons) performances have improved fur the last decade. Gate insulator layer has generally used inorganic layer, such as silicon oxide which has properties of a low electrical conductivity and a high breakdown field. However, inorganic insulating layers, which are formed at high temperature, may affect other layers termed on a substrate through preceding processes. On the other hand, organic insulating layers, which are formed at low temperature, dose not affect pre-process. Known wet-processing methods for fabricating organic insulating layers include a spin coating, dipping and Langmuir-Blodgett film processes. In this paper, we propose the new dry-processing method of organic gate dielectric film in field-effect transistors. Vapor deposition polymerization (VDP) that is mainly used to the conducting polymers is introduced to form the gate dielectric. This method is appropriate to mass production in various end-user applications, for example, flat panel displays, because it has the advantages of shadow mask patterning and in-situ dry process with flexible low-cost large area displays. Also we fabricated four by four active pixels with all-organic thin-film transistors and phosphorescent organic light emitting devices.

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고분자막을 점착층으로 사용한 유기 박막 트랜지스터의 안정성 (Stability of Organic Thin-Film Transistors Fabricated by Inserting a Polymeric Film)

  • 형건우;표상우;김준호;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.61-62
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    • 2006
  • In this paper, it was demonstrated that organic thin- film transistors (OTFTs) were fabricated with the organic adhesion layer between an organic semiconductor and a gate insulator by vapor deposition polymerization (VDP) processing. In order to form polymeric film as an adhesion layer, VDP process was also introduced instead of spin-coating process, where polymeric film was co-deposited by high-vacuum thermal evaporation from 6FDA and ODA followed by curing. The saturated slop in the saturation region and the subthreshold nonlinearity in the triode region were c1early observed in the electrical output characteristics in our organic thin film transistors using the staggered-inverted top-contact structure. Field effect mobility, threshold voltage, and on-off current ratio in 15-nm-thick organic adhesion layer were about $0.5\;cm^2/Vs$, -1 V, and $10^6$, respectively. We also demonstrated that threshold voltage depends strongly on the delay time when a gate voltage has been applied to bias stress.

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소스/드레인 전극의 두께변화에 따른 TIPS-pentacene 트랜지스터의 전기적 특성 연구 (Study on die electric characteristics of TIPS-pentacene transistors with variation of electrode thickness)

  • 양진우;형건우;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.323-324
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    • 2009
  • We investigated the electrical properties of tris-isopropylsilylethynyl (TIPS)-pentacene organic thin-film transistors (OTFTs) employing Ni/Ag source/drain electrodes. The gap height between the gate insulator and S/D electrode was controlled by changing the thickness of Ag under-layer(20, 30, 40 and 50nm). After evaporating the Ni under-layer, TIPS pentacene channel material was dropping the gap between the gate insulator and SID electrodes. The electrical proprieties of OTFT such as filed-effect mobility, on/off ratio, threshold voltage and subthreshold slope were significantly influenced by the gap height.

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Surface Treatment Effect on Electrical Characteristics of Ink-Jet Printed Pentacene OTFTs Employing Suspended Source/Drain Electrode

  • Park, Young-Hwan;Kim, Yong-Hoon;Kang, Jung-Won;Oh, Myung-Hwan;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1312-1314
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    • 2007
  • The effect of gate insulator surface treatment on electrical characteristics of bottom contact (BC) and suspended source/drain (SSD) organic thinfilm transistors (OTFTs) was studied. Triisopropylsilylethynyl pentacene was used as an active material and was printed by ink-jet printing method. In case of the BC OTFTs, threshold voltage was shifted from positive to near zero, and the fieldeffect mobility was increased when the gate insulator surface was treated with hexamethyldisilazane. However, in case of SSD OTFT, threshold voltage shift was not observed and the field-effect mobility was decreased.

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Performance Improvement of Organic Thin Film Transistors with Self-Assembled Monolayer Formed by ALD

  • Kim, Hyun-Suck;Park, Jae-Hoon;Bong, Kang-Wook;Kang, Jong-Mook;Kim, Hye-Min;Choi, Jong-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1166-1169
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    • 2006
  • In this study, the effects of SAMs on the performance of OTFTs have been investigated. ALD technique was applied for the deposition of SAMs, which is an ultra-thin film deposition technique based on sequences of self-limiting surface reactions enabling thickness control on atomic scale. According to our investigation results, it is observed that the surface properties of the gate insulator was changed by SAMs, which allow pentacene molecules to be deposited in the upright direction on the gate insulator and hence the performance of OTFTs could be improved. These results will be discussed

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