• Title/Summary/Keyword: organic fluorescent materials

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Highly Sensitive Fluorescence Probes for Organic Vapors: On/off and Dual Color Fluorescence Switching

  • An, Byeong-Kwan;Kwon, Soon-Ki;Park, Soo-Young
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1555-1559
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    • 2005
  • High-performance fluorescent probes which exhibit either on/off or dual color fluorescence switching in response to the presence of organic vapors with a rapid response, a high sensitivity and a high-contrast on/off signaling ratio were demonstrated on the basis of the vapor-controlled AIEE phenomenon.

The Optimization of Efficient White Organic Light-Emitting Diodes Using a Blue Fluorescent and a Red Phosphorescent Dopant

  • Seo, Ji-Hoon;Kim, Jun-Ho;Seo, Ji-Hyun;Hyung, Gun-Woo;Park, Jung-Hyun;Lee, Kum-Hee;Yoon, Seung-Soo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1470-1473
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    • 2007
  • We have demonstrated the optimization of white organic light-emitting diodes with two separated emissive layers using a blue fluorescent and a red phosphorescent dopant. The maximum luminous efficiency of the devices showed 7.93, 9.70, 11.8, and 14.3 cd/A. The $CIE_{xy}$ coordinates also showed (x = 0.33, y = 0.36), (x = 0.33, y = 0.35), (x =0.31, y = 0.35), and (x = 0.29, y = 0.36) at 6V, respectively.

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Synthesis and Properties of Novel Rhodamine 6G Fluorescent Dye Compound

  • Kim, Hyung-Joo;Wang, Sheng;Son, Young-A
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.153-157
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    • 2012
  • One of organic dye materials which have been long lasting investigated is rhodamine 6G dye series. This dye has been attracted with considerable interests due to the reason of its promising photochemical properties. In this study, a novel fluorescent dye compound based on rhodamine 6G derivative was synthesized through the reaction of rhodamine 6G hydrazide and indole-3-carboxaldehdyde. Absorption and fluorescent emission spectra of this dye were determined with the properties of solvatofluorochromism. Related electron energy states of the dye compound were also characterized by computational calculations.

Synthesis and Optical Properties of Poly(hydroxyphenylbenzoxazole): A Colorimetric and Fluorescent Sensor for Ionic Species

  • Lee, Jin-Koo;Kim, Tae-Hyun;Kim, Young-shin;Gang Li;Park, Won-Ho;Lee, Taek-Seung
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.23-24
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    • 2003
  • We synthesized a poly[2-(2'-hydroxyphenyl) benzoxazole] under the two step procedures of Suzuki coupling polymerization with corresponding monomers followed by the deprotection of benzyl group. The polymer in DMF solution is applicable to colorimetric sensing fluoride anion, which shows a color change from colorless to yellow. High sensitivity to fluoride anion compared to other anions such as phosphate, chloride, and sulfate is ascribed to the high coordination ability of the 2-(2'-hydroxy phenyl)benzoxazole moiety in the polymer chain. Emission shift by metal cations, which can be applied to fluorescent sensing w as also observed in the polymer solution.

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Chromogenic and Fluorogenic Polymer Systems for Optical Sensing and Patterning

  • Lee, Taek-Seung;Kim, Tae-Hyeon;Kim, Tae-Hoon;Choi, Moon-Soo;Kim, Hyung-Jun;Kwak, Chan-Gyu;Lee, Jung-Hyo;Lee, Chi-Han
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.175-175
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    • 2006
  • Considering the number of chemosensors that have been developed for the sensing of metal ions, only a few chemosensors for fluoride anion have been described in the literature that are based on fluorescent or chromogenic responses. We performed colorimetric anion sensing based on the binding of anion analytes with hydrogen donor group in polymer backbone resulting in naked-eye color change and fluorescent quenching. Our challenges using hydrogen donor moiety was designed effectively are continuing in order for high selectivity and sensitivity for ultimate applications such as fluid solution sensing in biomolecules and gas vapor sensing.

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Synthesis and Photoluminescent Property of Diheteryl-substituted Triphenylamine Compound (Diheteryl-substituted triphenylamine 화합물의 합성과 형광 특성)

  • Kim, Byung-Soon;Kim, Sung-Hoon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.6
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    • pp.35-38
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    • 2007
  • FTriphenylamine dye compound having diheteryl moiety was synthesized and its photoluminescent property was investigated. Organic luminescent materials have received great attentions due to potential application subjects onto full color image displays. In this context, the dye (III) for light emitting materials was synthesized using 2-(4-amino-2-hydroxyphenyl)benzoxazole (I) and 4,4'-diformyltriphenylamine (II). It is well known that the amino groups of compound (I) react with carbonyl groups, especially an aldehyde, to afford azomethine linkages. The dye shows bulish-green fluorescence property, which is anticipated for the light-emitting material for display devices. In this context, our aim is to synthesize diheteryl-substituted triphenylamine fluorescent dye as an emitting material. The spectroscopic characteristics and the fluorescent properties of this dye molecule were examined and determined.

Multilayer White Organic Light-Emitting Diodes with Blue Fluorescent and Red Phosphorescent Materials

  • Seo, Ji-Hoon;Kim, Jun-Ho;Lee, Kum-Hee;Kim, You-Hyun;Kim, Woo-Young;Yoon, Seung-Soo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1067-1070
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    • 2006
  • We have demonstrated highly efficient WOLED with two separated emissive layers using a blue fluorescent dye and a red phosphorescent dye. The maximum luminous efficiency of the device was 11.2 cd/A at $20\;mA/cm^2$ and $CIE_{x,y}$ coordinates varied from (x = 0.33, y = 0.37) at 6V to (x = 0.25, y = 0.33) at 14V.

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Novel transport materials for high-performance fluorescent and phosphorescent OLEDs

  • Bohm, E.;Anemian, R.;Busing, A.;Fortte, R.;Heil, H.;Kaiser, J.;Krober, J.;Leu, S.;Mujica-Fernaud, T.;Parham, A.;Pflumm, C.;Voges, F.
    • Journal of Information Display
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    • v.12 no.3
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    • pp.141-144
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    • 2011
  • To improve the performance of blue fluorescent and green phosphorescent organic light-emitting diode devices, Merck developed novel green phosphorescent host and electron-transporting materials. The newly developed electron-transporting material improves the external quantum efficiency of blue fluorescent devices up to 8.7%, with an excellent lifetime. In combination with the newly developed host materials, the efficiency of green phosphorescent devices can be improved by a factor of 1.7, and the lifetime by a factor of 7.