• Title/Summary/Keyword: organic dye

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Effects of Doping in Organic Electroluminescent Devices Doped with a Fluorescent Dye

  • Kang, Gi-Wook;Ahn, Young-Joo;Lee, Chang-Hee
    • Journal of Information Display
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    • v.2 no.3
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    • pp.1-5
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    • 2001
  • The effect of doping on the energy transfer and charge carrier trapping processes has been studied in organic light-emitting diodes (OLEDs) doped with a fluorescent laser dye. The devices consisted of N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1-biphenyl-4,4'-diamine (TPD) as a hole transporting layer, tris(8-hydroxyquinoline) aluminum ($Alq_3$) as the host, and a fluorescent dye, 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1 H,5H-benzo[i,j]quinolizin-8-yl) vinyl]-4H-pyran) (DCM2) as the dopant. Temperature dependence of the current-voltage-luminescence (I-V-L) characteristics, the electroluminescence (EL) and photoluminescence (PL) spectra are studied in the temperature ranging between 15 K and 300 K. The emission from DCM2 was seen to be much stronger compared with the emission from $Alq_3$, indicative of efficient energy transfer from $Alq_3$ to DCM2. In addition, the EL emission from DCM2 increasd with increasing temperature while the emission from the host $Alq_3$ decreased. The result indicates that direct charge carrier trapping becomes efficient with increasing temperature. The EL emission from DCM2 shows a slightly sublinear dependence on the current density, implying the enhanced quenching of excitons at high current densities due to the exciton-exciton annihilation.

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Dyeing Properties of Acid and Reactive Dye for Super Soft Angora / PET, Nylon Blended Fabric (앙고라 섬유소재 / PET, Nylon 교직물의 염착 특성 : 산성염료와 반응성염료의 적용특성)

  • Kim, Young-Sung;Lee, Seok-Jang;Son, Young-A
    • Textile Coloration and Finishing
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    • v.22 no.4
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    • pp.332-340
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    • 2010
  • Nowadays natural textile materials should cope with the global warming. Soft, thin and light angora fibers which have two components. One is spiky hair and the other is soft hair. The spiky hairs have a disadvantage of pilling out. The soft hairs have promising properties comparable to cashmere goat hairs, which is cheap compared to very expensive cashmere goat hairs. In this study, we investigated the dyeing properties of angora/PET, Nylon blend fabrics to acid dyes and reactive dyes including various series of acid dyes and reactive dyes for the dyeing of the blended super soft angora fabrics and their potential for deep shade dyeing effects. Our focus is to get a relation between various kind of blend and their dyeability.

Adsorption Behavior of Organic Dye on Granular Clay (입상점토광물에 대한 염료폐수의 흡착)

  • Lee, Tack-Hyuck;Youn, Guk-Jung;Kim, Seon-Tae
    • The Journal of Natural Sciences
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    • v.13 no.1
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    • pp.35-50
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    • 2003
  • Granular clay minerals for adsorption of the organic dye prepared a Na-Bentonite and optimum condition calcined temperature $700^{\circ}C$ and polyvinyl alcohol quantity was 25%. Granular clay mineral stable range was pH3 to pH9 and specific area was $83m^2/g$. The adsorption of the organic dye on the Granular clay mineral showed result good adsorption with acid medium and then enthalpy was -3.36 ~ -0.84 kcal/mol. It was exhibit typical physical adsorption.

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Dyeing Properties of Askin Fabric with Indigo (인디고를 이용한 아스킨 섬유의 염착특성)

  • Kim, Su-Ho;Kim, Young-Sung;Hong, Jin-Pyo;Yoon, Seok-Han;Son, Young-A
    • Textile Coloration and Finishing
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    • v.21 no.2
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    • pp.1-6
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    • 2009
  • Recently, polyester is widely used in textile fabrics due to its application potentials in various fields. It is known that askin fabric is prepared with mainly polyester and is enjoyed with various end uses such as marine clothing, underwear, shirts, swimming suits and so on. For this purpose, color fastness should be considered with great importance during its wet processing step. In this context, vat dyes were very much attracted due to the advantage of superior fastness property. Thus, we have used indigo dye towards askin fabric dyeings and investigated corresponding properties namely, dyeing temperature, concentration of dye, reducing agent amount and alkali amount. The results showed that higher color strengths of indigo dyeing on askin fabric were obtained at $110^{\circ}C$, 8% o.w.f, 3g/l, 5g/l, respectively. The color fastness to washing was considerable generally.

Reduction Cleaning and Thermomigration Effects on Micro Polyester SUEDE (극세 폴리에스테르 스웨드의 환원세정과 열이행의 영향)

  • Choi, Kyung-Yeon;Han, Sam-Sook;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.12-21
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    • 2009
  • The dyeing property of direct-spinning type and seaisland type 0.2D micro polyester nonwoven fabrics was characterized by three disperse dyes (Dorosperse Red KFFB, Blue KGBR, Yellow KRL) at $120^{\circ}C$ and $130^{\circ}C$. Before and after reduction cleaning, dyeing fastness was evaluated and the thermomigaration after heat setting at $180^{\circ}C$ for 60 min were also evaluated. Direct-spinning type fabric showed better dyeing property, wash fastness, and light fastness, but worse rub fastness than seaisland type fabric. The dyeing property and fastness of direct-spinning type fabric increased at higher dyeing temperature, whereas seaisland type fabric exhibited lower dyeing fastness and the increase of thermomigration at higher dyeing temperature. Non-fixed dye in fiber surface was removed by reduction cleaning process, then dyeing fastness was improved and thermomigration decreased. The higher dye uptake of direct-spinning type non-woven fabric caused the increase of dye molecule migration from fiber internal to fiber surface, so this fabric showed larger thermomigration than seaisland type non-woven fabric.

Two Manganese Peroxidases and a Laccase of Trametes polyzona KU-RNW027 with Novel Properties for Dye and Pharmaceutical Product Degradation in Redox Mediator-Free System

  • Lueangjaroenkit, Piyangkun;Teerapatsakul, Churapa;Sakka, Kazuo;Sakka, Makiko;Kimura, Tetsuya;Kunitake, Emi;Chitradon, Lerluck
    • Mycobiology
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    • v.47 no.2
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    • pp.217-229
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    • 2019
  • Two manganese peroxidases (MnPs), MnP1 and MnP2, and a laccase, Lac1, were purified from Trametes polyzona KU-RNW027. Both MnPs showed high stability in organic solvents which triggered their activities. Metal ions activated both MnPs at certain concentrations. The two MnPs and Lac1, played important roles in dye degradation and pharmaceutical products deactivation in a redox mediator-free system. They completely degraded Remazol brilliant blue (25 mg/L) in 10-30 min and showed high degradation activities to Remazol navy blue and Remazol brilliant yellow, while Lac1 could remove 75% of Remazol red. These three purified enzymes effectively deactivated tetracycline, doxycycline, amoxicillin, and ciprofloxacin. Optimal reaction conditions were $50^{\circ}C$ and pH 4.5. The two MnPs were activated by organic solvents and metal ions, indicating the efficacy of using T. polyzona KU-RNW027 for bioremediation of aromatic compounds in environments polluted with organic solvents and metal ions with no need for redox mediator supplements.

Relationship between the porosity of the nanostructured $TiO_2$ electrode and Dye Loading for Dye-sensitized Solar Cells (염료감응태양전지를 위한 $TiO_2$ 분말 기공도와 염료 흡착량의 관계)

  • Hwang, Seongjin;Jung, Hyunsang;Jeon, Jaeseung;Kim, Hyungsun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.68.2-68.2
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    • 2010
  • Dye-sensitized solar cells (DSSC) show great promise as an inexpensive alternative to conventional p-n junction solar cells. Investigations into the various factors influencing the photovoltaic efficiency have recently been intensified. The conventional absorber electrode in DSSC is composed of compacted or sintered $TiO_2$ nanopowder that carries an anchored organic dye. The absorbance of incident light in the DSC is realized by specifically engineered dye molecules placed on the semiconductor electrode surface ($TiO_2$). The dye absorbs light at wavelengths up to about 920nm, the energy of the exited state of the molecule should be about 1.35eV above the electronic ground state corresponding to the ideal band gap of a single band gap solar cell. The dye molecules ar adhered onto the nanostrutured $TiO_2$ electrode by immersing the sintered electrode into a dye solution, typically 3mM in alcohol, for a long enough period to fully impregnate the electrode. However, the concentrations of the dye is slightly changed due to the evaporation of the alcohol. The dye is more expensive than other materials in DSSC and related to the efficiency of DSSC. Therefore, the concentrations of the dye should be carefully measured. In this study, we investigated to the dye loading on fired $TiO_2$ powder as a function of temperature by the TG-DTA and the dye solution by UV-visible spectroscopy after the impregnation process. The dye loading is related to the porosity of the nanostructured $TiO_2$ electrode.

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Synthesis of Novel Quinacridone Dyes and Their Photovoltaic Performances in Organic Dye-sensitized Solar Cells

  • SaKong, Chun;Kim, Se-Hun;Yuk, Sim-Bum;Kim, Jeong-Yun;Park, Se-Woong;Ko, Min-Jae;Kim, Jae-Pil
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2553-2559
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    • 2011
  • Two novel quinacridone (QNC) dyes with thiophene or benzene-conjugated bridge and cyanoacrylic acid acceptor were first designed and synthesized for use in dye-sensitized solar cells (DSSCs). The absorption spectra, electrochemical and photovoltaic properties of these dyes were investigated. Under simulated AM 1.5G irradiation conditions, the solar cell based on the quinacridone dye containing thiophene as a bridge unit had a short-circuit photocurrent density of 8.51 $mA{\cdot}cm^{-2}$, an open-circuit voltage of 643.6 mV, and a fill factor of 0.70, corresponding to an overall conversion efficiency of 3.86%.

Study of Dye Encapsulated Microcapsule Polymerization Using Polyurethane Prepolymer Synthesis and Textile Finishing (폴리우레탄 프리폴리머 합성을 통한 색소 담지 마이크로캡슐 제조 및 섬유가공)

  • Kim, Ji Yeon;Woo, Ji Yun;Min, Mun Hong;Yoon, Seok Han;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.27 no.3
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    • pp.184-193
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    • 2015
  • In this study, dye encapsulated microcapsules were produced by polyurethane prepolymer synthesis method using hexamethylene diisocyanate, ethylene glycol and methyl ethyl ketone. The study showed that the average size of microcapsules were $4.697{\mu}m$ in normal distribution. These microcapsules were induced red color by thermochromic fluoran red dye with showing color change as temperature. After the textile finishing of microcapsules, durability of microcapsules were checked as crocking times and lightfastness. The microcapsules were pressed at protrusion of textile weave in 10 crocking times which meant that the microcapsules not fallen off. Lightfastness was acceptable giving rating 4. It means that the polyurethane microcapsules not affect to light durability.

A Study on Electrical and Optical Properties of Dye Doped Organic Electroluminescent Devices (색소 Dopant에 의한 청색 발광 소자의 전기적, 광학적 특성 연구)

  • 이무상;최상건;노병규;오환술
    • Proceedings of the IEEK Conference
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    • 2000.11b
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    • pp.269-272
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    • 2000
  • In this paper, we was fabricated and analyzed a blue organic electroluminescent devices with the organic dye, such as 1,1,4,4-Tetraphenyl-1,3-butadi-ene(TPB). The device was made by simultaneously co-depositing two materials. The device structure was composed of the ITO glass, TPD, Alq$_3$doped TPB, and aluminum(A1) electrode. Carrier injection from the two electrodes was significant]y observed and the blue light in EL spectrum, with an emission maximum at 462nm, was triggered at a driving voltage of 11V.

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