• Title/Summary/Keyword: organic acid (formic acid

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Nitrogen Retention and Chemical Composition of Urea Treated Wheat Straw Ensiled with Organic Acids or Fermentable Carbohydrates

  • Sarwar, M.;Khan, M. Ajmal;Nisa, Mahr-un
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.11
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    • pp.1583-1591
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    • 2003
  • The influence of varying levels of urea and additives on nitrogen (N) retention and chemical composition of wheat straw was studied. The wheat straw was treated with 4, 6 and 8% urea and ensiled with 1.5, 2 and 2.5% of acetic or formic acid and 2, 4 and 6% of corn steep liquor (CSL) or acidified molasses for 15 days. The N content of wheat straw was significantly different across all treatments. The N content of urea treated wheat straw was increased with the increasing level of urea. The N content was higher in urea treated wheat straw ensiled with acetic or formic acid as compared to urea treated wheat straw ensiled without these organic acids. The N content of urea treated wheat straw was further enhanced when it was ensiled with CSL or acidified molasses. This effect was significant across all levels of urea used to treat the wheat straw. Nitrogen retention in urea treated wheat straw was decreased linearly as the urea level was increased to treat the wheat straw. The N content was increased linearly when higher levels of CSL or acidified molasses were used to ensile the urea treated wheat straw. Most of the N in urea treated wheat straw was held as neutral detergent insoluble N (NDIN). The NDIN content was increased linearly with the increasing levels of urea and additives. The neutral detergent fiber (NDF) contents were higher in urea treated wheat straw ensiled with acetic or formic acid as compared to urea treated wheat straw ensiled without additive. The NDF content further increased in urea treated wheat straw ensiled with CSL and acidified molasses. The entire increase in NDF content was because of fiber bound N. The hemicellulose content of urea treated wheat straw ensiled with CSL or acidified molasses was higher as compared to urea treated wheat straw ensiled with acetic or formic acid. The acid detergent fiber content of urea treated wheat straw ensiled with or without additives remained statistically non-significant. The cellulose contents of wheat straw was linearly reduced when urea level was increased from 4 to 6 and 8% to treat the wheat straw. This effect was further enhanced when urea treated wheat straw was ensiled with different additives. The results of the present study indicated that fermentable carbohydrates might improve the Nitrogen retention and bring the favorable changes in physiochemical nature of wheat straw. However, biological evaluation of urea treated wheat straw ensiled with fermentable carbohydrates is required.

Investigation of the Effect of Acidity and Polyethylene Glycol on Electrochemical Deposition of Trivalent Chromium Ions

  • Phuong, N.V.;Kwon, S.C.;Lee, J.Y.;Kim, M.;Lee, Y.I.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.47-48
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    • 2011
  • The effect of solution acidity and organic additives, polyethylene glycol (PEG), on the trivalent chromium electroplating was systematically investigated in the view point of solution stability, electroreduction of trivalent chromium ions and characterization of deposition layer. It was found that, the concentration of fraction chromium complexes in the trivalent chromium bath containing formic acid is strongly depended on pH value. PEG molecules were stable in trivalent chromium bath containing formic acid via studies on electrospray ionization mass spectrometry (ESI-MS) and UV-Vis. However, the presence of PEG molecules decreased the reductive current of hydrogen evolution, increasing of current efficiency higher about 10 % compared with solutions without PEG. Moreover, PEG additives developed the nodular morphology during electroreduction of trivalent chromium ions with the increase of solution acidity and enhanced its current efficiency by maintaining the consumption of complexant, formic acid, at a low speed. In this study, the effect of solution acidity was emphasized important, there, it controlled the formation of complexes in the solution, cathodic film (CF) during deposition, and properties of deposited layer. By electrochemical quartz crystal microbalance (EQCM), studies show that chromium electrodeposition occurs via the formation of intermediate complexes and adsorption on the cathode surface, which hinder the penetration of ions from bulk solution to the cathode surface.

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Antibacterial Activity by Lactobacillus bulgaricus SP5 against Pathogenic Bacteria (병원성 미생물에 대한 Lactobacillus bulgaricus SP5의 항균활성)

  • Kim, Woan-Sub;Yang, A-Reum
    • Korean Journal of Organic Agriculture
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    • v.24 no.3
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    • pp.497-510
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    • 2016
  • This study was carried out to get basic resources for the industrial use of Lactobacillus bulgaricus SP5. The antibacterial activity of the supernatant obtained from Lactobacillus bulgaricus SP5 was tested against the pathogenic bacteria such as Escherichia coli KCCM 11234, Salmonella enteritidis KCCM 3313, Salmonella enteritidis KCCM 12021, and Salmonella typhimurium KCCM 40253. The supernatant of L. bulgaricus SP5 showed antibacterial activity against tested pathogenic bacteria. The antibacterial activity was examined after adjusting pH and heat treatment of supernatant. Heat treatment of supernatant had antibacterial activity against pathogenic bacteria at all temperature. However, pH changes showed no antibacterial activity. Antibacterial activity of the supernatant was confirmed to be due to organic acids (lactic, acetic, phosphoric, succinic, pyroglutamic, citric, malic, and formic acid).

Changes of Organic Acids and Free Fatty Acids During the Ripening of Emmental Cheese (에멘탈치즈의 숙성 중 유기산과 유리지방산의 변화)

  • Shin, Yong-Kook;Oh, Nam-Su;Nam, Myoung-Soo
    • Food Science of Animal Resources
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    • v.31 no.6
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    • pp.928-934
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    • 2011
  • The objective of this study was to characterize the lactate metabolism and lipolysis in Emmental cheese made of Korean raw milk throughout the ripening periods; 14 d at $10^{\circ}C$, 42 d at $23^{\circ}C$, and 30 d at $4^{\circ}C$. Emmental cheese was made using a commercial starter culture with propionic acid bacteria (PAB) and without PAB as a control on the pilot plant scale. Changes in the contents of five organic acids (citric, lactic, formic, acetic, and propionic acid) and individual free fatty acids (FFAs) were measured using HPLC/PDA and GC/FID. As a result of propionic fermentation by PAB, the concentration of acetic acid and propionic acid increased up to 1.5 and 6.1 g/kg, respectively and the most dramatic increased occurred when incubated in the hot room ($23^{\circ}C$). Lactic, citric, and formic acid contents were 2.6, 2.5 and 0.8 g/kg at the end of ripening, respectively. As a result of lipolysis, the amount of total FFAs was 6,628.2 mg/kg. Compared to the control, levels of individual FFAs from butyric (C6:0) to linoleic (C18:2) acids increased significantly (p<0.05) during the ripening period. Especially, 65.1% of total FFAs was released in the $23^{\circ}C$ room and the most abundant FFAs were palmitic (C16:0), stearic (C18:0) and oleic acid (C18:1). These results demonstrated that the lipolysis of Emmental cheese was strongly affected by bacterial lipase from PAB.

Change of Flavor Components and Organic Acids during Maturation of Korean Apricot (매실의 성숙중 향기 성분과 유기산의 변화)

  • 손영아;신승렬;김광수
    • Food Industry And Nutrition
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    • v.7 no.2
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    • pp.40-44
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    • 2002
  • 매실의 향기성분은 50여종 중 알콜류가 benzyl alcohol, linalool, 1,6-octadien-3-ol, n-haxanol 등 10종, aldehyde류가 2-hexenal, benzaldehyde, n-hexanal 등 3종, acid류가 butandeionic acid, acetic acid, 2종, 2-iodo-hexane 등 hydrocarbon류가 5종, butanedioic acid-diethyl estet를 포함한 ester류가 3종, B-ionone을 포함한 ketone류가 3종 그리고 기타 성분이 2종이었다. 매실이 성숙함에 따라 향기성분의 수가 증가하고 그 함량도 증가하는 경향이었다. 매실의 비휘발성 유기산의 조성은 succinic, fumaric, oxalic, malic, tartaric 및 citric acid이었다. 매실이 비휘발성 유기산은 성숙 초기에는 malic acid와 oxalic acid의 함량이 높았다. Citric acid의 함량이 증가한 반면에 대부분의 유기산은 감소하는 경향이었다. 휘발성 유기산은 성숙중에 formic acid함량은 감소하고 butyric acid의 함량은 증가하는 경향이었다. 총 유기산의 함량은 매실 성숙에 현저히 감소하는 경향이었다.

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Antioxidative Components and Anti-Oralmicrobial Effect of Bamboo (Phyllostachys nigra var. henonis Stapf) Leaves (죽엽(솜대)의 항산화 성분 및 구강세균에 대한 항균 효과)

  • Park, Kyung Lan;Kang, Sung Tae;Kim, Min Ju;Oh, Hee Kyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.9
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    • pp.1265-1272
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    • 2016
  • The objective of this study was to investigate the antioxidative components and anti-oralmicrobial effect of bamboo (Phyllostachys nigra var. henonis Stapf) leaves. The moisture, crude protein, crude fat, crude ash, and carbohydrate contents were 6.30%, 5.10%, 1.73%, 10.61%, and 76.26%, respectively. Vitamin C content was higher than Vitamin A and E contents. Among organic acids, citric acid content was the most abundant organic acid, followed by succinic acid, acetic acid, malic acid, and formic acid. Total polyphenol and flavonoid contents were 21.66 mg/g and 42.78 mg/g, respectively. Minimum inhibitory concentrations (MICs) of extracts of bamboo leaves for Streptococcus mutans and Streptococcus sobrinus were determined to be 0.04% and 0.16%, respectively. MICs of extracts of bamboo leaves for Porphyromonas gingivalis and Prevotella intermedia were determined to be 0.02%. Extract of bamboo leaves had strong antimicrobial activity against S. mutans, S. sobrinus, P. gingivalis, and P. intermedia at a concentration of 0.32%. At this concentration, extract of bamboo leaves inhibited growth of these pathogenic bacteria up to 60 h. The results of the present study demonstrate the antimicrobial effects of bamboo leaves ethanol extract against oral pathogenic bacteria, suggesting that bamboo leaves could be an effective natural agent for oral hygiene.

Characteristics of Sucrose Thermal Degradation with High Temperature and High Pressure Treatment

  • Woo, Koan-Sik;Hwang, In-Guk;Lee, Youn-Ri;Lee, Jun-Soo;Jeong, Heon-Sang
    • Food Science and Biotechnology
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    • v.18 no.3
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    • pp.717-723
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    • 2009
  • Thermal degradation characteristics of sucrose was investigated. A 20% sucrose solution was heated to temperatures of $110-150^{\circ}C$ for 1-5 hr. Chromaticity, pH, organic acids, 5-hydroxymethylfurfural (HMF), free sugars, electron donating ability (EDA), and ascorbic acid equivalent antioxidant capacity (AEAC) of the heated sucrose solutions were evaluated. With increasing temperatures and times, the L-, a-, and b-values decreased; however, total color difference (${\Delta}E_{ab}$) increased. The pH and sucrose contents decreased, and fructose and glucose contents increased with increasing heating temperature and time. Organic acids, such as formic acid, lactic acid, and levulinic acid, and HMF contents increased with increasing heating temperatures and times. EDA (%) and the AEAC of the heated sucrose solutions increased with increasing heating temperature and time. The heated sucrose solution was more effective than unheated sucrose solution, having higher EDA (90 fold), and AEAC (13 fold).

Isolation and Characterization of Hydrogen Producing Bacterium (수소생산균 Enterobacter cloacae YJ -1의 분리 및 특성)

  • 이기석;강창민;정선용
    • KSBB Journal
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    • v.18 no.2
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    • pp.149-154
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    • 2003
  • The hydrogen-producing bacterium was isolated from fresh water and identified as Enterobacter cloacae. The isolated was named Enterobacter cloacae YJ-1. In batch culture, The optimum cultivation temperature and pH of strain YJ-1 was 35℃ and 7.5, respectively. All of the added glucose was consumed completely during fermentation even though pH was not controlled. Amount of hydrogen produced on each condition of 2% glucose, 4% sucrose and 5% fructose was 950, 1000 and 948 mL/L, respectively and resulted in increasing hydrogen production approximately 2.5-times more than controlled condition. The maximum hydrogen production was obtained when 50 mM phosphate was added. In repeated-batch culture, hydrogen gas of 1920 mL/L was totally produced for 48. The maximum hydrogen was produced on the condition of 0.5% yeast extract, but the production amount was not changed on the condition of over 0.5%. Most of the organic acids produced during the fermentation were formic and acetic acid, and propionic acid was moiety also generated.

A Study on Physicochemical Properties and Components of Bamboo oil from Phyllostachys nigra var. henonis by refining process (정제과정에 따른 대나무기름의 물리화학적 특성 및 성분에 관한 연구)

  • Na, Myung-Sun;Choi, Hyun-Suk;Lee, Myung-Yul;Ryu, Seong-Ryeol;Park, Seung-Kyu;Choe, Yong Deok;Piao, Yu Lan;Choi, DuBok;Shin, Dae-Yewn
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.129-132
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    • 2008
  • The purposes of this study were to investigate the physicochemical properties and component values of bamboo oil from Phyllostachys nigra var. henonis obtained by refining process. The tar concentration in the refined bamboo oil (RBO) was decreased to about 78% compared to crude Bamboo oil (CBO). The chromaticities of light, red, and yellow in RBO were 92.4 and 3.0, respectively. This result indicates that the chromaticity of light was increased with the decrease in the tar concentration in the Bamboo oil. The total concentrations of organic acid and phenolics compound in RBO were decreased to about 63% and 80%, respectively. The total concentration of free sugars was decreased to about 78% in RBO and the concentration of free sugar was in the order of lactose, fructose, and glucose. The palmitoleic acid and stearic acid concentrations were higher than that of other fatty acids. The concentration of total organic acid was decreased to about 88% through RBO. Among the various organic acids, the formic acid concentration was highest in the RBO. The minerals concentrations in the CBO were in the order of Ca, K, Na, and Fe. On the other hand, in the case of RBO, it was in the order of Ca, Fe, K, and Na.

Synthesis of Hydroxypropyl Chitin and Its Liquid Crystalline Character (히드록시프로필 키틴의 합성과 액정형성)

  • Kim, Seon Jeong;Lee, Young Moo
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.516-521
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    • 1992
  • Hydroxypropyl chitin (HPCH) was prepared by reacting chitin with propylene oxide. HPCH showed the improved solubility in several organic solvents compared with chitin. It showed the remarkable solubility in formic acid. Form the results of polarized microscopic observatoin of HPCH solution in formic acid, finger-print pattern was observed in concentrations over 30 wt% solution. Since no typical thermogram was observed in DSC scan, the HPCH showed a lyotropic cholestric liquid crystallinity.

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