• Title/Summary/Keyword: ordering temperature

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Organic Gas Response Characteristics for Temperature of Fatty Acid LB Films (지방산 LB막의 온도에 대한 유기가스 반응특성)

  • 이준호;진철남;장정수;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.353-356
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    • 1999
  • The electrical characteristics of fatty acid LB films were investigated to develop the gas sensor using Langmuir-Blodgett(LB) films which have high ordered orientation and ordering structure. The deposition status of fatty acid LB films were verified by the measurements of UV absorbance. The conductivity of fatty acid LB films for horizontal direction at room temperature was about $10^8[S/cm]$,/TEX>, which was correspond to semiconductor material. The activation energy for fatty acid LB films with respect to variation of temperature was about l.O[eV]. The response characteristics for organic gas were confirmed by measuring the response time, recovery time, and reproducibility of the fatty acid LB films to each organic gas. Also, the penetration and adsorption behavior of gas molecule were confirmed through the organic gas response characteristics of fatty acid LB films with respect to temperature.

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Ordering of manganese spins in photoconducting $Zn_{1-x}Mn_xTe$

  • Kajitani, T.;Kamiya, T.;Sato, K.;Shamoto, S.;Ono, Y.;Sato, T.;Oka, Y.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.39-43
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    • 1998
  • Single crystals of{{{{ { Zn}_{ 1-x} {Mn }_{x }{Te} }}}} with x=0.3-0.6 were prepared by the standard Bridgeman method. Diffuse neutron diffraction intensities due to the short range magnetic ordering is found in the vicinities of 1 1/2 0 reciprocal point and its equivalent point, indicating that the magnetic correlation of the clusters is the type III antiferromangetic one do the F-type Bravais class crystals, being identical with that of {{{{{ Cd}_{ 1-x} {Mn }_{x }Te }}}}. Neutron inelastic scattering measure-ment has been performed for {{{{{ Zn}_{ 0.6} { Mn}_{ 0.4}Te }}}} sample using the cold neutron spectrometer. AGNES. High resolution measurement with the energy resolution of {{{{ TRIANGLE E= +- .01meV}}}} was carried out in the temperature range from 10K to the ambient. Critical scattering, closely related with the spin glass transition, has been observed for the first time in this semimagnetic semi-conductor. The critical scattering is observed at temperatures in the vicinity of the spin glass transition temperature, 17K. The scattering is observed as a kind of quasielastic scattering in the reciprocal range where the elastic magnetic diffuse scattering has been observed, e.g., 11/20 reciprocal point, indicating the spin fluctuation has dynamic components in this material. Photoconductivity has been discovered below 150K in {{{{{ Zn}_{ 0.4} {Mn }_{0.6 } Te}}}}. The electric AC conductivity has been increased dramatically under the laser light with the wave lengths of {{{{ lambda =6328,5145 and4880 }}}}$\AA$ ,respectively. After the light was darkened, the conductivity was reduced to the original level after about 2000 seconds at 50K, being above the spin glass transition temperature. This phenomenon is the typical persistent photoconductivity; PPC which was similarly found in {{{{ { Zn}_{ 1-x} { Mn}_{x} Te}}}}.

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Magnetic Semiconductors Thin Films-Unidirectional Anisotropy

  • Lubecka, M.;Maksymowicz, L.J.;Szymczak, R.;Powroznik, W.
    • Journal of Magnetics
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    • v.4 no.1
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    • pp.33-37
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    • 1999
  • Unidirectional magnetic anisotropy field ($H_an$) was investigated for thin films of $CdCr{2-2x}In_{2X}Se_4 (0$\leq$x$\leq$0.2). This anisotropy originates from the microscopic anisotropic Dzyaloshinskii-Moriya (DM) interaction which arise from the spin-orbit scattering of the conduction electrons by the nonmagnetic impurities. This interaction maintains the remanent magnetization in the direction of the initial applied field. Then the single easy direction of the magnetization is parallel to the direction of the magnetic field. The anisotropy produced by field cooling is unidirectional I.e. the spins system deeps some memory of the cooling field direction. The chalcogenide spinel of$ CdCr_{2-2x}In){2X}Se_4$belongs to the class of the magnetic semiconductors. The magnetic disordered state is obtained when ferromagnetic structure is diluted by In. Then we have the mixed phase characterised by coexistence the magnetic long range ordering (IFN-infinite ferromagnetic network) and the spin glass order (Fc-finite clusters). The total magnetic anisotropy energy depends on the state of magnetic ordering. In our study we concentrated on the magnetic state with reentrant transition and spin glass state. The polycrystalline $ CdCr_{2-2x}In){2X}Se_4$ thin films were obtained by rf sputtering technique. We applied the ferromagnetic resonance (FMR) and M-H loop techniques for determining the temperature composition dependencies of Han. From the experimental data, we have found that Han decreases almost linearly when temperature is increased and in the low temperature is about three times bigger at SG state with comparison to the state with REE.

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A Study on the Microstructure and Mechanical properties of Fe Aluminide alloys (Fe-Aluminide합금의 미세조직과 기계적 특성에 관한 연구)

  • Jo, Jong-Chun;Lee, Do-In;Lee, Seong-Jae;Choe, Byeong-Hak;Kim, Hak-Min
    • 연구논문집
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    • s.22
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    • pp.115-125
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    • 1992
  • Mechanical properties and microstructure were investigated on vacuum induction melted $Fe_3A1$base alloys of $DO_3$ structure. Specal emphasis were put on the effect of alloy chemistry, grain size and process(rolling, directional solidification) on mechanical properties of Fe-22.5-39at.%Al at elevated temperature between room temperature and $800^{\circ}C$. grain size of as-cast alloys is refined by rolling from 1mm to $80\mum$. Tensile strength of Fe-24.lat.%AI was about 404MPa at the critical ordering temperature, and the fracture strain of the alloy was 1-2% at room temperature. An inverse temperature dependence of the strength is noticed as-cast $Fe_3A1$. The presence of Cr and Zr do not affect the room temperature ductility and high temperature strength. Fracture strain of directionally solidified(DS) $Fe_3A1$ is about 1%at room temperature, but is about 60%at. $T_C$(550^{\circ}C)$. Tensile strength of DS alloy is lower than that of as-cast alloy at $530^{\circ}C$ and $430^{\circ}C$. Failure mode at room temperature varies from transgranular fracture to intergranular fracture with the addition of Al. the failure mode also varies from mixed(transgranular+ intergranular) mode between room temperature and $500^{\circ}C$ to intergranular mode above $550^{\circ}C$

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Preparation and Characterization of $(Ba_{0.5}La_{0.5}) (Mg_0.5}Mo_{0.5})O_3$ ($(Ba_{0.5}La_{0.5}) (Mg_0.5}Mo_{0.5})O_3$의 합성 및 특성연구)

  • 최진호
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.25-28
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    • 1985
  • The new compound $(Ba_{0.5}La_{0.5}) (Mg_0.5}Mo_{0.5})O_3$ is synthesized under the $H_2$-atmosphere and reveals to have a cation ordering between Mg and Mo in cubic lattic of ordered perovskite (a0=8.009(2)$\AA$) and obeys Curie-Weiss law below the room temperature with the effective magnetic moment of 1.60(5) Bohr Magneton.

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Synthesis and Microwave Dielectric Properties of $La(Zn_{1/2}Ti_{1/2})O_3$ ($La(Zn_{1/2}Ti_{1/2})O_3$의 합성 및 고주파 유전특성)

  • 서명기;조서용;홍국선;박순자
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.1019-1023
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    • 1996
  • The dielectric properties at microwave frequencies of B site complex perovskite La(Zn1/2Ti1/2)O3 which has +3 ion in A site were investigated. maximum Q*F value of the specimens was 59000 dielectric constant 34, temperature coefficient of resonant frequency -52 ppm/$^{\circ}C$. XRD pattern of the sintered specimen shows (111) ssuperlattice reflection which indicates Zn and Ti cation ordering.

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Two-dimensional Antiferromagnetism in the Perovskite-type Layered Compounds $(C_nH{2n+1}NH_3)_2MnCl_4$

  • Lee, Kyu Won;Lee, Chang Hoon;Lee, Cheol Eui;Kang, J.K
    • Journal of Magnetics
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    • v.5 no.1
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    • pp.13-15
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    • 2000
  • We have investigated the finite temperature magnetic ordering in the quasi-two-dimensional Heisenberg antiferromagnetic system $(C_nH{2n+1}NH_3)_2MnCl_4$ with various chain lengths n. Our results far the transition temperatures and the exchange energies for long chain compounds are in marked contrast to previous expectations.

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Emission of spin-polarized light in GaN-based spin LEDs (GaN계 스핀 발광소자의 스핀편극된 빛의 발광)

  • Ham, Moon-Ho;Yoon, Suk-Ho;Park, Yong-Jo;Myoung, Jae-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.150-152
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    • 2005
  • We investigated the fabrication and characteristics of spin-polarized LEDs based on GaN using (Ga,Mn)N as spin injection source. (Ga,Mn)N thin films were found to exhibit the ferromagnetic ordering above room temperature and the negative MR up to room temperature. The electrical characteristics in spin LEDs did not degraded in spite of the insertion of (Ga,Mn)N films. In EL spectra of spin LEDs, it is confirmed that spin LEDs emit the strong light at 7 K as well as room temperature. These results suggest that it is possible to emit spin-polarized light in our spin LEDs.

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Analysis of microstructural evolutions during advanced ceramics processing : I. Phase behavior of colloidal dispersion (세라믹 제조시 미세구조 변화의 해석 : I. 콜로이드 분산의 상거동)

  • Kim, Hern
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.599-609
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    • 1997
  • The phase behavior and dynamics of colloid suspensions and the resulting structures and properties of powder compacts were examined by a computer experimental method for cooperative packing processes. A wide range of properties and process conditions such as arbitrary particle size, medium densities, field strength, and temperature could be examined using the Peclet number (Pe). We demonstrated that an optimum range of Peclet number for the ordering of sediments was present and that the phenomena related to the ordering such as the onset of crystallization, the phase behavior, etc. strongly depend on process conditions. The present work appears to be useful to design the processing method of ceramic spherical submicron powders for the preparation of high-density green compacts.

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