• Title/Summary/Keyword: oil species

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Effects of Oil Unsaponifiables and Plant Extracts on the Thermal Oxidation of Oils at $180^{\circ}C$ (유지 불검화물과 식물체 추출물이 식용유의 $180^{\circ}C$ 가열 산화에 미치는 효과)

  • Jung, Mun-Yhung;Yoon, Suk-Hoo;Kim, Seong-Yeol;Lee, Jee-Hyeun
    • Korean Journal of Food Science and Technology
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    • v.29 no.5
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    • pp.860-868
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    • 1997
  • The effects of oil unsaponifiables (8 species) and methanolic plant extracts (53 species) on the thermal oxidation of oils during 14 or 16 hour heating at $180^{\circ}C$ were studied by analyzing the fatty acid composition of soybean oil or cottonseed oil. All the unsaponifiables tested did not show any antioxidative activities on the thermal oxidation of soybean oil. However, among the 53 species of methanolic plant extracts, some species (Rheum undulatum L., Chelidonium majus L. var. asiaticum and Eugennia caryopyllata T.) showed very strong antioxidative activities on the thermal oxidation of cottonseed oil. The antioxidative activities of methanolic extracts of these 3 species on thermal oxidation of cottonseed oil during an extended heating period were also studied by heating cottonseed oils for 7 hours a day for 8 days at $180^{\circ}C$. The methanolic extracts of Chelidonium majus L. v. asiaticum and Eugennia caryopyllata T. greatly reduced both polymer formation and linoleic acid decomposition after the 8 day heating at $180^{\circ}C$. However, the methanolic extracts of Rheum undulatum L. was effective for the reduction of polymer formation, but not for the reduction of linoleic acid decomposition.

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A Complete, Reductive Depolymerization of Concentrated Sulfuric Acid Hydrolysis Lignin into a High Calorific Bio-oil using Supercritical Ethanol

  • Riaz, Asim;Kim, Jaehoon
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.3
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    • pp.447-452
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    • 2016
  • It is imperative to develop an effective pathway to depolymerize lignin into liquid fuel that can be used as a bioheavy oil. Lignin can be converted into liquid products either by a solvent-free thermal cracking in the absence air, or thermo-chemical degradation in the presence of suitable solvents and chemicals. Here we show that the solvent-assisted liquefaction has produced promising results in the presence of metal-based catalysts. The supercritical ethanol is an efficient liquefaction solvent, which not only provides better solubility to lignin, but also scavenges the intermediate species. The concentrated sulfuric acid hydrolysis lignin (CSAHL) was completely liquefied in the presence of solid catalysts (Ni, Pd and Ru) with no char formation. The effective deoxy-liquefaction nature associated with scEtOH with aid hydrodeoxygenation catalysts, resulted in significant reduction in oxygen-to-carbon (O/C) molar ratio up to 61%. The decrease in oxygen content and increase in carbon and hydrogen contents increased the calorific value bio-oil, with higher heating value (HHV) of $34.6MJ{\cdot}Kg^{-1}$. The overall process is energetically efficient with 129.8% energy recovery (ER) and 70.8% energy efficiency (EE). The GC-TOF/MS analysis of bio-oil shows that the bio-oil mainly consists of monomeric species such as phenols, esters, furans, alcohols, and traces of aliphatic hydrocarbons. The bio-oil produced has better flow properties, low molecular weight, and high aromaticity.

Molecular Species of Triglycerides in Sunflower Seed Oil (해바라기씨 기름의 triglyceride분자종에 관한 연구)

  • Cheon, Seok-Jo;Park, Yeung-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.16 no.4
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    • pp.311-316
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    • 1987
  • From the results of triglyceride composition and the fatty acid at ${\beta}-position$ of glycerol, triglyceride molecular species of sunflower seed oil were found to be 26 kinds. The major triglyceride molecular species in sunflower seed oil were identified to PLL; 10.4%, OLL; 22.3%, and characterized that LLL species existed more than 31% of the total triglyceride molecular specie.

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Concentrations of Essential Metals in Tissues of Oiled Loons (유류에 오염된 아비류 (Loons)의 체내 조직 중 필수원소 농도)

  • Kim Sang-Jin;Lee Jong-Nam;Lee Doo-Pyo
    • Environmental Analysis Health and Toxicology
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    • v.21 no.3 s.54
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    • pp.267-273
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    • 2006
  • Concentrations of four essential metals (Fe, Cu, Mn and Zn) were determined in apparently oil-polluted dead or near-dead three loon species collected in the Busan coast, Korea. Fe, Cu, Mn and Zn concentrations were generally high in liver, and also, Mn and Zn were high in bone. There were significant differences in some tissue concentrations of Fe, Cu, Mn and Zn among three species, but did not show any consistent evidence of species-specific accumulation. Mean concentration of Fe was 11,635$\pm$4010 $\mu$g/g, Cu 64.3$\pm$30.7 $\mu$g/g, Mn 13.1$\pm$2.32 $\mu$g/g, and Zn 121$\pm$24.8 $\mu$g/g in liver of all three species examined. Mn and Zn levels in this study were similar to those of normal loons and other seabirds reported from different countries. However, Fe and Cu liver levels were extraordinarily higher than those of reported. This result suggests that unusual accumulations of essential metals such as Fe and Cu may partially arise from long-term starvation due to oil pollution.

Isolation and Identification of Rice Bran Oil Assimilating Yeast (미강유 자화효모의 분리 및 동정)

  • 이정윤;이은숙
    • The Korean Journal of Food And Nutrition
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    • v.1 no.1
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    • pp.3-6
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    • 1988
  • For the purpose of the production of yeast cell protein from rice bran oil, it's assimillating yeast(E222) was isolating from soil and the resulting of identification was shown that it was belonging to Candida aibican species Total free amino acids from yeast cells were shown 0.05% per gram. Nine other species of amino acids as well as glycine, glutamic acid, alanine, leucine and aspartic acid were produced from yeast cells.

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Property of Yeast Cell Protein from Rice Bran Oil (미강유를 이용한 효모균체 단백질의 특성)

  • 안태영
    • The Korean Journal of Food And Nutrition
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    • v.3 no.1
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    • pp.35-38
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    • 1990
  • For the purpose of the production of single cell protein from rice bran oil, yeast was isolating from soil. It was belonging to Candida albicans Species. These experiments were conducted to find out the property on yeast cell from rice bran oil Molecular weight for the main protein on yeast cell protein from rice bran oil separated by 1% SDS polyacrylamide gel electrophorosis was 22, 000.

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A study on the effect of solid materials on the streaming electrification of insulating oil (절연유의 유동대전에 미치는 고체재질의 영향에 관한 연구)

  • 김용운;임헌찬;김영일;김영봉;이덕출
    • Electrical & Electronic Materials
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    • v.7 no.3
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    • pp.236-242
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    • 1994
  • In this paper, the streaming electrification characteristics of insulating oil were examined when the oil is contacted with solid materials in a circulating system. The streaming current($I_s$) increases with increasing oil velocity and temperature, and electrification properties depend on species of metal materials. $I_s$ in the gauze-contained electrification apparatus increases with increasing oil temperature below the temperature of 43[>$^{\circ}C$], but decreases above 43[>$^{\circ}C$]. On the other hand, $I_s$ is positive electrificated for the pipe of Fe, Cu, while it is negative electrificated for Sus. When insulating oil flows through a car fuel filter, $I_s$ increases linearly with increasing oil temperature.

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Effect of replacement feed ingredients of Micropterus salmoides in exotic species

  • Min-Gi Han;Ran Lee;Hyun Jung Park;Kyung Hoon Lee;Hyuk Song
    • Journal of Animal Reproduction and Biotechnology
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    • v.38 no.4
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    • pp.225-235
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    • 2023
  • Background: Largemouth bass (Micropterus salmoides) is introduced species that has caused aquatic ecology activity both in vitro and in vivo were investigated for the possibility of application of the bass extract as an alternative feed ingredient. Methods: The bass oil was extracted using a 1-L supercritical extractor, while the protein was extracted from 250 g of bass dry matter, which was dissolved in 1 mL of H2O at 50℃. Both oil and protein extracts were evaluated antioxidant activities and the level of DPPH radical scavenging assay and nitric oxide (NO) production assay with lipopolysaccharide response. Oral administration of 6.6 µL/g bass protein and 5.38 µL/g bass oil conducted for investigating serological and physiological effect. Results: DPPH radical scavenging showed similar radical scavenging ability of 50 µM of ascorbic acid at 200 ㎍ of protein and 10% of oil treatment. NO concentration was diminished by the treatment of bass oil. Oral administration of both bass oil and proteins to mice showed that the body weight increase rate of the bass oil treated group was significantly reduced by 1.55 g compared to the other groups. The number of white blood cells (WBC) was increased by 4.52 k/µL in the bass protein-treated group and 4.44 k/µL in the bass oil-treated group compared to the control group. However, the serum IgG level did not show a significant difference between the bass extract-treated groups and the control group. Conclusions: These studies demonstrate that both bass oil and proteins extracted from the bass not only provide excellent effects of antioxidant and immune activity but can also be used as functional food supplements.

Characterization of Basic Nitrogen-Containing Compounds in the Products of Lube Base Oil Processing by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

  • Li, Xiaohui;Zhu, Jianhua;Wu, Bencheng
    • Bulletin of the Korean Chemical Society
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    • v.35 no.1
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    • pp.165-172
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    • 2014
  • The distribution of basic nitrogen-containing compounds in three vacuum gas oils (VGOs) with different boiling ranges and their dewaxed oils from the lube base oil refining unit of a refinery were characterized by positive-ion electrospray ionization (ESI) Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR MS). It turned out that the composition of basic nitrogen compounds in the samples varied significantly in DBE and carbon number, and the dominant basic N-containing compounds in these oil samples were N1 class species. $N_1O_1$, $N_1O_2$, and $N_2$ class species with much lower relative abundance were also identified. The composition of basic nitrogen compounds in VGOs and dewaxed VGOs were correlated with increased boiling point and varied in DBE and carbon numbers. The comparison of the analytical results between VGOs and dewaxed VGOs indicated that more basic N-containing compounds in VGO with low carbon number and small molecular weight tend to be removed by solvent refining in lube base oil processing.

A Study on Long-term Monitoring of Seaweed Flora and Community Structure at Hakampo, Western Coast of Korea (한국 서해안 학암포 해조상 및 군집구조의 장기모니터링 연구)

  • Heo, Jin Suk;Han, Su Jin;Choi, Han Gil;Nam, Ki Wan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.6
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    • pp.969-976
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    • 2015
  • Macroalgal community structure was seasonally examined at Hakampo (Taean) in western coast of Korea from February 2007 to October 2010. Also, the effects of "Hebei Spirit" oil spill on the seaweed community structure were evaluated. A total of 101 macroalgal species were identified, comprising 12 green, 18 brown and 71 red algae. Species richness ranged 58-65 species with maximal in 2008 and minimal in 2009. Seaweed biomass ranged $75.81-102.06g\;dry\;wt./m^2$ (mean, $88.78g/m^2$) with maximal in 2008 and minimal in 2010. Vertical distribution from the high to low intertidal zone was Neorhodomela aculeata and Polyopes affinis; Corallina pilulifera and Chondrus ocellatus; Sargassum thunbergii and Ulva australis. Coarsely-branched seaweeds comprised the highest proportion of biomass ($37.17g/m^2$, or 41.86% of the total biomass) and ecological state group I (ESG I) seaweed biomass was between 81.67-85.44%. Also, ephemeral macroalgae including Ulva species sharply increased in species number and biomass within 1-2 year from the "Hebei Sprit" oil spill in the mid and low intertidal zone. Hakampo rocky shore is still good condition as evaluated based on macroalgal species number, biomass, and composition in functional form and ESG I seaweeds.