• Title/Summary/Keyword: oil removal

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Evaluation of Fertilizer Additions to Stimulate Oil Biodegradation in Sand Seashore Mesocosms

  • CHOI, SUNG-CHAN;KAE KYOUNG KWON;JAE HAK SOHN;SANG-JIN KIM
    • Journal of Microbiology and Biotechnology
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    • v.12 no.3
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    • pp.431-436
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    • 2002
  • Effects of fertilizer additions for oil degradation were examined in sand seashore mesocosms. Within 37 days, up to $85\%$ removal was achieved by the addition of slow-release type fertilizer (SRF) with the initial degradation rate of 423.3 mg oil $(kg sand)^-1\;day^-1$. The removal was mostly of biological origin based on the changes of $C_17$ /pristane and $C_18$/phytane ratios from 2.60 to 0.81 and from 3.55 to 1.29, respectively. The addition of oleophilic fertilizer (Inipol EAP22) was less effective and resulted in the removal of $64\%$ of the added oil ($3\%$, v/v) with a lower initial degradation rate. Petroleum-degrading bacteria had achieved a value of $1{\times}10^8$ CFU $(g sand)^-1$ at Day 3 and this peak exactly coincided with the initial degradation in the SRF-treated mesocosm. In this mesocosm, surface tension values were decreased drastically during Days 3 and 8, suggesting that microbially-produced surface-active agents actively enhanced the oil degradation rate and cell proliferation. Although the Inipol-treated mesocosm appeared to show significantly enhanced oil degradation compared to that of the untreated control mesocosm, Inipol was found to be less effective than SRF in enhancing a true oil-degrader when compared under similar experimental conditions.

Experimental Quality Characteristics for Water Removal in Inner Flushing Oil in Process Piping of Offshore Plant (해양플랜트 프로세스 배관 내경 플러싱 오일속에서 수분제거를 위한 실험적 품질 특성)

  • Park, Chang-Soo;Sung, Ki-Young;Han, Seong Jong
    • Journal of the Korean Society of Industry Convergence
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    • v.22 no.6
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    • pp.797-805
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    • 2019
  • An important problem of offshore plant process piping is equipment accidents due to the removal of fine metal debris and foreign substances in the pipes that deliver fluids such as hydraulic oil, lubricating oil and thermal oil. Temporary flushing equipment to remove debris uses fluid equipment of centrifugal pump and gear pump to prevent equipment accident of offshore platform. The equipment manufacturer requires the shipyard to have a cleanliness rating inside the pipe to meet the international standards ISO4406 and NAS1638 quality levels to prevent damage to the equipment sold. The quality of the internal flushing of pipes conforms to the regulations suggested by the equipment manufacturer. In this paper, three types of electric heater capacity, which is a method of evaporating and removing water inside a pipe during an oil flushing process, were compared. In addition, the study was conducted to remove the flushing oil in the pipe and to improve oil quality.

Removal of Oily and Particulate Soils from Silk Fabrics (견직물에 부착한 지용성 오구 및 고형 오구의 제거)

  • Lee, Jeong-Sook
    • Fashion & Textile Research Journal
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    • v.7 no.6
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    • pp.680-688
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    • 2005
  • This study was carried out to investigate on the removal of oily and particulate soils from silk fabrics. Various kinds of solvents were used on the removal of two kinds of soils treated into the silk fabrics. The removal of oily soil was analyzed by liquid scintillation counting method, and the removal of oil and carbon particulate mixed soils was evaluated by measuring of reflectance on the surface of soiled fabrics with/without drysoap in solvent washing by Terg-o-tometer. The surfaces of fabrics were also observed by SEM before and after washing. The results obtained were as follows : oily soils were removed efficiently by various kinds of solvents regardless of kinds of silk fabrics in short washing time. The removal effect of solvents from the soiled silk fabrics were high in the order of isopropyl alcohol>trichloroethane>monochlorobenzene>ethylether>perchloroethylene. Oil and carbon particulate mixed soils could be efficiently removed by adding of drysoap in solvent washing. The removal of mixed soils were increased drastically with rinsing and increased drysoap. The removal of soils was more efficiently removed from degummed silk fabrics than from the raw silk fabrics.

Treatment Performance and Microbial Community Structure in BAC-process Treating Contaminated Groundwater by Water-soluble Cutting Oil (생물활성탄을 이용한 절삭유로 오염된 지하수의 처리특성과 미생물군집구조 해석)

  • Lim Byung-Ran;Bae Ci Ae;Lim Ho-Ju;Cho Chang-Ho
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.71-76
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    • 2006
  • Treatment performance and microbial community structure were investigated in water-soluble cutting oil treatment process using biological activated carbon. DOC removal in BACI column at $15^{\circ}C$ was higher than at $25^{\circ}C$, but those of BAC3 column after 60days was high at$25^{\circ}C$. Also, quinone content of first-step reactors at $25^{\circ}C$ and $15^{\circ}C$ was much the same, but those of the third-step reactor at $25^{\circ}C$ was higher than at $15^{\circ}C$. The dominant type of two apparatus was ubquinone (UQ)-l 0 followed by UQ-8. Menaquinones were detected from $25^{\circ}C$ apparatus and effluent. This suggested that DOC removal at $25^{\circ}C$ was advanced degradation by attached microorganisms on the activated carbon surface. The DOC removal in long-term activated carbon apparatus increased with going in BAC3 column. This indicated the influent of POC was a result of DOC removal efficiency decrease. Integrated DOC removal from start point in experiment to break point and quinone content were showed a tendency of increasing with going last-step activated carbon apparatus. Therefore, the biological activated carbon apparatus used by this study was effective treatment process in contaminated groundwater by water-soluble cutting oil.

A Study on Treatment of a Contaminated Soil by Oil using Continuous System of High Temperature Heating Element and Microwave (마이크로웨이브와 고온발열체를 이용한 연속식 공정의 유류오염토양 처리에 관한 연구)

  • Ha, Sang-An;You, Mi-Young
    • Journal of Soil and Groundwater Environment
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    • v.17 no.1
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    • pp.8-12
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    • 2012
  • This study is maintains the condition of high temperature (above $600^{\circ}C$) within a short time using on microwave and high temperature heating elements. And removal characteristics according to changes in soil moisture, microwave power and temperature through the decomposition of the contaminated soil by oil. The difficulty resolvability material was sort of lubricating oil having long carbocyclic (C18-C50) and TPH removal rate reached 85.2% at 6 kW and $700^{\circ}C$ and thus the contaminant was removed 1,788 mg/kg within a process time of 40 minutes. In the case of light oil, gasoline contaminated soil, the removal amount showed 567 mg/kg and the treatment rate reached 98.4% at 6 kW, $500^{\circ}C$ and 20 minute. In the case of non-resolvability reached TPH concentrations on 2,000 mg/kg of worrisome level of soil contamination in the 3 zones at 6 kW, $700^{\circ}C$ and 30 minute. At the time, showed up processing costs 8,173 won per ton.

Effect of Lubricant Additives on the Surface Fatigue Performance of Gear Oils

  • Hong, Hyun-Soo;Huston, Michael E.;Stadnyk, Nicholas M.
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.136-143
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    • 1995
  • The effect of additive chemistry on the serface fatigue of gears was investigated using the FZG gear tester and fluids based on an API GL-5 grade oil. Surface fatigue lives were determined as a function of load and additive chemistry. At 1.52 GPa, the removal of the primary extreme pressure additive (EP) from the fully formulated gear oil decreased the fatigue life of gears slightly (4%), however, the removal of the primary antiwear additive (AW) decreased the fatigue life of gears significantly (83%). At 1.86 GPa, the removal of the EP additive from the fully formulated gear oil decresed the gear fatigue life 27%, however, the removal of the primary AW additive decreased the fatigue life of gears significantly (75%). Micropitting was the dominant surface morphology in the dedendum of gears tested With two oils at load stage: one using the complete additive package, and a second where the EP additive has been removed. However, spalling is the primary failure mode of gears tested without an AW additive independent of whether an EP agent was present. Surface analysis of pinion gears showed the formation of a mixed phosphate/phosphite-oxide layer on the surface of gears tested with fluids containing an AW. Formation of this layer seems to be key to long fatigue life.

Optimization of nutrients requirements for bioremediation of spent-engine oil contaminated soils

  • Ogbeh, Gabriel O.;Tsokar, Titus O.;Salifu, Emmanuel
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.484-494
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    • 2019
  • This paper presents a preliminary investigation of the optimum nutrients combination required for bioremediation of spent-engine oil contaminated soil using Box-Behnken-Design. Three levels of cow-manure, poultry-manure and inorganic nitrogen-phosphorus-potassium (NPK) fertilizer were used as independent biostimulants variables; while reduction in total petroleum hydrocarbon (TPH) and total soil porosity (TSP) response as dependent variables were monitored under 6-week incubation. Ex-situ data generated in assessing the degree of biodegradation in the soil were used to develop second-order quadratic regression models for both TPH and TSP. The two models were found to be highly significant and good predictors of the response fate of TPH-removal and TSP-improvement, as indicated by their coefficients of determination: $R^2=0.9982$ and $R^2=1.000$ at $p{\leq}0.05$, respectively. Validation of the models showed that there was no significant difference between the predicted and observed values of TPH-removal and TSP-improvement. Using numerical technique, the optimum values of the biostimulants required to achieve a predicted maximum TPH-removal and TSP-improvement of 67.20 and 53.42%-dry-weight per kg of the contaminated soil were as follows: cow-manure - 125.0 g, poultry-manure - 100.0 g and NPK-fertilizer - 10.5 g. The observed values at this optimum point were 66.92 and 52.65%-dry-weight as TPH-removal and TSP-improvement, respectively.

Discussion on the Criterion for the Determination of On-Water Oil Removal Resource Requirement in Korea (우리나라 기름오염 방제능력 확보기준의 타당성)

  • Kang Seong-Gil;Sung Hong-Gun;Lee Moonjin;Choi Hyuek-Jin;Yu Jeong-Seok;Kang Chang-Gu
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.5 no.4
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    • pp.3-18
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    • 2002
  • The present study was carried out to discuss the suitability of the criterion for the determination of the on-water oil removal resource requirement in Korea by comparison with the US criterion. According to the present criterion in Korea, the on-water response operation against the worst case discharge assuming the oil spillage of 60,000 ton from the accident of DWT 300,000 tanker requires the oil recovery capacity of 19,425 kl/hr (on-water recovery volume 20,000 ton). Under the US criterion, the recovery capacity of 16,667 kl/hr is required to respond to oil spill accident of the worst case discharge from the DWT 300,000 tanker. The result shows that resource requirement from the Korean criterion is 16% higher than US criterion, indicating that thc Korean criterion is reasonable.

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Ultrasonic flushing 기법에 의한 유류오염토양의 복원에 관한 실험연구

  • Jeong, Ha-Ik;Oh, In-Gyu;Kim, Sang-Geun;Lee, Yong-Su;Yoo, Jun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.13-17
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    • 2002
  • Ultrasonic waves have several mechanical, chemical, and biological effects on a saturated soil medium. Their mechanical effects, popularly known as cavitation. Cavitation is the rapid and repeated formation, and resulting implosion, of imcrobubbles in a liquid, resulting in the propagation of microscopic shock waves. In a soil-liquid system, their mechanical effects generate high differntial fluid-particle velocities and microscopic shock waves. The velocity perturbations are capable of dislodging oil in the system by overcoming the forces binding oil to sand particles. In this study, a series of laboratory experiments involving the simple flushing and ultrasonic flushing were carried out. An increase in permeability and oil removal rate were observed in ultrasonic flushing tests. Some practical implications of these results are discussed in terms of technical feasibility of in situ implementation of ultrasonics.

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Treatment of ground waters in a hollow-fibre liquid membrane contactor for removal of ions

  • Hossain, Md. M.
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.95-108
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    • 2013
  • Metal ions exist in seawater, groundwater and industrial wastewaters. These source waters can be recycled if their concentrations are reduced. A number of processes can be applied for this purpose. Liquid-liquid extraction is one of the promising methods. In this paper, experimental results are presented on the removal of Cr(VI) using Aliquat-336, a reactive carrier, in sunflower oil (a non-toxic solvent). The performance of this new system is compared with those of kerosene (a toxic solvent). The extent of removal of Cr(VI) from samples with high and low concentrations are presented. The process was upgraded to a bench-scale module that can selectively remove about 50-90% Cr(VI) from samples of groundwater. Thus this process can produce water within the acceptable range for recycling and for use in secondary purposes such as irrigation.