• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1207-1210
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• 2003

The effect of solvent structure on the slope in the plot of ln K vs. solute carbon number was examined. It was found that the free energy of methylene group transfer from the gas phase into a solvent was always negative and that the absolute magnitude of interaction free energy between the methylene group and the solvent was always larger than the absolute magnitude of cavity formation free energy of the methylene group in the solvent. Thus, the slope in the plot of ln K vs. solute carbon number was always positive and its value decreases with increase of solvent polarity since the cavity formation energy of the CH₂ unit increases with increase of solvent polarity while the dispersive interaction energy of the CH₂ unit is virtually invariant. We also examined the effect of sequential addition of CH₂ unit to a solvent molecule upon ln K for three homologous series of solvents: n-alkanes, n-alcohols, and n-nitriles. Characteristic trends in the plots of ln K vs. solvent carbon number were observed for individual solvent groups. A decrease of ln K with solvent carbon number was observed for n-alkanes. An abrupt increase in ln K followed by levelling off was observed for n-alcohols while a final slight decrease in ln K after an abrupt increase followed by rapid levelling off was noted for n-nitriles. All of theses phenomena were found related to variation in cavity formation energy. It was clearly shown that a structural change of a polar solvent by sequential addition of CH₂ units causes an abrupt polarity decrease initially, then gradual levelling off, and finally, conversion to a virtually nonpolar solvent if enough CH₂ units are added.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.48 no.9
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• pp.717-724
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• 2020

We study the closing characteristics of a self-sustainable poppet valve which serves as a main oxidizer shut-off valve for liquid rocket engines. Numerical analysis for predicting closing transient responses are presented and the calculated results have been verified by a comparison with experimental data. The effective area of a pilot gas discharge system and the pressure distribution of passage flow around the valve moving part are shown to be main parameters in determining the closing characteristics for dry and cryogenic conditions, respectively. Moreover, it is presented that the passage flow pressure at the valve closing moment as well as the valve closing velocity can be effectively adjusted by the appropriate employment of the pilot gas.

• Biomedical Science Letters
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• v.8 no.3
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• pp.143-154
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• 2002

The effect of cardiopulmonary bypass (CPB) on cerebral physiology during heart surgery remains incompletely understood. This study was carried out to investigate changes of cerebral metabolism and the association between the changes and clinical factors during heart surgery. Seventy adult patients (n=70) scheduled for elective cardiac surgery were participated in the present study. Middle cerebral artery blood flow velocity (V$_{MCA}$), cerebral arteriovenous oxygen content difference (C(a-v)O$_2$), cerebral oxygen extraction (COE), and modified cerebral metabolic rate for oxygen (MCMRO$_2$) were measured during six phases of the operation; Pre-CPB, CPB-10 min, Rewarm-1 (nasopharyngeal temperature 34$^{\circ}C$), Rewarm-2 (nasopharyngeal temperature 37$^{\circ}C$), CPB-off, and Post-OP (at skin closure after CPB-off). Each relationship of age, arterial blood gas parameters, or other variables to V$_{MCA}2$, C(a-v)O$_2$, COE, or MCMRO$_2$ was evaluated. V$_{MCA}$ increased (P<0.0001) whereas C(a-v)O$_2$ decreased (P<0.01) throughout the five phases of the operation compared to Pre-CPB value (control). COE diminished at CPB-10, Rewarm-1, and CPB-off (P<0.05) while MCMRO$_2$ reduced at CPB-10 and Rewarm-1 (P<0.05) compared to Pre-CPB value. Positive correlation was found between age and cerebral metabolic parameters (V$_{MCA}$, C(a-v)O$_2$, COE, or MCMRO$_2$) during CPB (range r=0.24 to 0.38, p<0.05). Four cerebral metabolic parameters had partially negative or positive correlation with arterial blood gas parameters and other variables (arterial blood pH, $O_2$ tension, $O_2$ content, $CO_2$ tension, blood pressure, blood flow, temperature, or hematocrit) during the operation. In conclusion, CPB led to marked alterations of cerebral metabolism and age, pH, and $CO_2$ tension profoundly influenced the changes during cardiac surgery.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.12 no.6
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• pp.582-590
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• 2019

As Korea's low fertility and aging progress, Korea is facing a social change such as an increase of one generation by entering an aging society that has raised 14% of the population. An effective way to prevent a gas fire accident caused by an increase in one generation in an aging society is to install a control valve to forcibly shut off the gas after a set time. In this study, we developed a valve that can be opened and closed by rotating the valve left and right by transmitting power to the worm gear and the helical gear by using a motor by pressing the switch. It is easy to assemble and inspect by developing a dedicated valve that is easy to attach and detach. It was developed to enhance competitiveness by reducing cost by reducing the number of parts and product size. In addition, through endurance test, it was developed to be used for more than 9 years by repeating ON / OFF once every 12 seconds so that it can operate stably for 10,000 times for 34 hours. The instrument and PCB were designed using solid works and Altium Designer tools. Firmware development was developed in IAR Embedded Workbench environment.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.3
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• pp.269-274
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• 2010

As a preliminary study on a SOFC-GT hybrid system integrated a with coal-gasification system, the influence of the concentrations of $H_2$ and CO in syngas on the performance characteristics of the hybrid system is investigated. It is expected that the differences in the heating values of fuels with different compositions trigger the off-design operation of the gas turbine and result in different performance characteristics of the overall hybrid system. Syngas compositions are found to affect the SOFC performance. Performance of hybrid system with carbon monoxide is poorer than the case with hydrogen. In the case of part-load performance with syngas, performance degradation at part-load operating conditions with hydrogen is more dominant than the case with carbon monoxide.

• Journal of the Korean Institute of Gas
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• v.12 no.1
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• pp.31-35
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• 2008

Natural gas vehicles are being applied to city buses for improving air quality in metropolitan and have proved the effective way to reduce the pollutant emissions. Liquified Natural Gas(LNG) has also attempted a vehicle fuel in order to raise the fuel storage density that is a disadvantage of Compressed Natural Gas(CNG). This paper described insulation characteristic of a LNG storage tank. From the results, adiabatic coefficient of a tested tank was around $40J/h{\cdot}^{\circ}C{\cdot}m^2$ and it was the lower level than gas safety regulation limit. Two experimental methods were adopted to justify the evaluation results and they were revealed that the results were very similar to each other. Also, through testing relief valve operation characteristic it was investigated venting amount of boiled off gas.

• Journal of the Korean Electrochemical Society
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• v.9 no.3
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• pp.118-123
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• 2006

Degradation of polymer electrolyte membrane fuel cell (PEMFC) that is facilitated by on/off cycles is one of the most important issues for commercialization of fuel cell vehicles. When a PEMFC stack is shut down, residual hydrogen and induce high voltage equivalent to open circuit voltage to the cathode side that might cause sintering of Pt catalyst and facilitate formation of hydrogen peroxide at the anode side that might decompose $Nafionc\'{A}$ membrane. In this study, degradation of PEMFC exposed to repetitive on/off cycles was investigated by measuring i-V characteristics, ac impedance, cyclic voltammograms, gas leak, cross-sectional SEM images, and TEM images. To prevent degradation of PEMFC caused by the residual gases, hydrogen was removed from anode gas channel by gas-purging and by using a dummy resistance, that were found to be a very effective method.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.27 no.2
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• pp.55-62
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• 2021

This study aims to reduce the rancid odor generated during the fermentation process of kimchi by inserting zinc oxide (ZnO) into an inorganic porous material with a high surface area to decompose or adsorb the fermentation odor. ZnO activated by the presence of moisture exhibits decomposition of rancid odors. Mixed with Titanium dioxide (TiO₂), a photocatalyst. To manufacture the packaging liner used in this study, NaOH, ZnCl₂, and TiO₂ powder were placed in a tank with diatomite and water. The sludge obtained via a hydrothermal ultrasonication synthesis was sintered in an oven. After being pin-milled and melt-blended, the powders were mixed with linear low-density polyethylene (L-LDPE) to make a masterbatch (M/B), which was further used to manufacture liners. A gas detector (GasTiger 2000) was used to investigate the total amount of sulfur compounds during fermentation and determine the reduction rate of the odor-causing compounds. The packaging liner cross-section and surface were investigated using a scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS) to observe the adsorption of sulfur compounds. A variety of sulfur compounds associated with the perceived unpleasant odor of kimchi were analyzed using gas chromatography-mass spectrometry (GC-MS). For the analyses, kimchi was homogenized at room temperature and divided into several sample dishes. The performance of the liner was evaluated by comparing the total area of the GC-MS signals of major off-flavor sulfur compounds during the five days of fermentation at 20℃. As a result, Nano-grade inorganic compound liners reduced the sulfur content by 67 % on average, compared to ordinary polyethylene (PE) foam liners. Afterwards SEM-EDS was used to analyze the sulfur content adsorbed by the liners. The findings of this study strongly suggest that decomposition and adsorption of the odor-generating compounds occur more effectively in the newly-developed inorganic nanocomposite liners.

• Membrane Journal
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• v.31 no.6
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• pp.456-470
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• 2021

In this study, polyetherimide-based hollow fiber membranes were manufactured using the NIPS (nonsolvent induced phase separation) method. THF, Ethanol, and LiNO₃ were used as additives to control the morphology of the PEI-hollow fiber membranes. Furthermore, for the development of a high hydrogen separation membrane, the spinning conditions were optimized through the characterization of SEM and gas permeance. As a result, as the content of THF increased, the hydrogen/carbon dioxide selectivity increased. However, the permeance decreased due to the trade-off relationship. When ethanol was added, a finger-like structure was shown, and when LiNO₃ was added, a sponge structure was shown. In particular, in the case of a hollow fiber membrane with an optimized PDMS coating layer, the permeance was 40 GPU and the hydrogen/carbon dioxide selectivity was 5.6.

• Journal of the Korean Institute of Gas
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• v.22 no.4
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• pp.74-81
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• 2018

The Korean Government has proceeded petroleum gas pipeline construction business since 2014 for rural districts. The operating pressure of petroleum gas pipeline are from 25kPa to 75kPa which are different from that of natural gas pipeline. Petroleum gas pipeline pressure is ten or forty times higher than natural gas operating pressure. For this reason, petroleum gas pipeline has higher probability of accident occurrence from massive gas leakage. Korea Gas Safety Corporation begins to development excess flow valves and their performance testing equipment since 2017. The excess flow valves stop the gas flow when a overflow happened in gas pipeline. The excess flow valves are generally not installed in main pipeline, because that may block massive gas supply. So, the valves are installed in starting points of branch pipes. According to the number of house and amount of gas use, a shut-off point of exxcess flow valve is determined called as Trip Flow. The trip point is the most important thing of excess flow valve, so, it is required a equipment testing the performances of excess flow valve as trip point.