• Journal of Electrochemical Science and Technology
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• v.1 no.2
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• pp.85-91
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• 2010

We have studied the origin of an additional plateau of $Li_{4+x}Ti_5O_{12}$ (LTO) observed at 0.7 V (vs. Li/$Li^+$). Some LTO has to be discharged down to below 1.0 V forming two-stage plateau (1.5 V and 0.7 V) in order to obtain most of capacity while others could achieve the same level of capacity at higher potential (1.0 V vs. Li/$Li^+$) forming one plateau (1.5 V). The particle size effect has been investigated as a possible reason of this. The 0.7 V plateau was gradually elongated with increasing the particle size. The structural variations and kinetic behaviors during discharge were carefully examined by in-situ XRD technique and OCV measurement. According to structural and electrochemical verifications, the kinetic limitation of $Li^+$ insertion is responsible primarily for the two-stage plateau which is related to the particle size of LTO rather than the formation of new intermediate phase during discharge. Herein, we propose a possible reaction model to elucidate this abnormal behavior of LTO below 1.0 V (Li/$Li^+$).

• Earthquakes and Structures
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• v.8 no.3
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• pp.761-778
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• 2015

The objective of this paper is to report the result of an experimental program conducted on the strengthening of nonductile RC frames by using external mesh reinforcement and plaster application. The main objective was to test an alternative strengthening technique for reinforced concrete buildings, which could be applied with minimum disturbance to the occupants. Generic specimen is two floors and one bay RC frame in 1/2 scales. The basic aim of tested strengthening techniques is to upgrade strength, ductility and stiffness of the member and/or the structural system. Six specimens, two of which were reference specimens and the remaining four of which had deficient steel detailing and poor concrete quality were strengthened and tested in an experimental program under cyclic loading. The parameters of the experimental study are mesh reinforcement ratio and plaster thickness of the infilled wall. The effects of the mesh reinforced plaster application for strengthening on behavior, strength, stiffness, failure mode and ductility of the specimens were investigated. Premature and unexpected failure mode has been observed at first and second specimens failed due to inadequate plaster thickness. Also third strengthened specimen failed due to inadequate lap splice of the external mesh reinforcement. The last modified specimen behaved satisfactorily with higher ultimate load carrying capacity. Externally reinforced infill wall composites improve seismic behavior by increasing lateral strength, lateral stiffness, and energy dissipation capacity of reinforced concrete buildings, and limit both structural and nonstructural damages caused by earthquakes.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.6
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• pp.85-91
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• 2011

This study aims at evaluating feasibility of Bottom ash-mixed Foam Cement Banking(BFCB) Method on the enhancement of soft soil, which is developed to reduce self-weight of banking by applying bottom ash and foam. to cement slurry. In order to measure the behavior of soil when BFCB layer was covered to soft ground, a testing equipment for mock-up test was fabricated and phased loads were applied up to measurement of yielding and ultimate strengths as well as movement of ground particles. In addition, these measured values such as settlement and heaving were compared with ones of surface-hardening method prevailing on soil improvement. As the result through mock-up test, BFCB showed lower values of ground deformation, while wider range of deformation was observed in compare to the other method. And settlement and heaving were measured lower, which implies the method developed is very effective to applicability of soft ground.

• Korean Journal of Materials Research
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• v.18 no.1
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• pp.38-44
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• 2008

The micro-structural changes, strength characteristics, and micro-fractural behaviors at the joint interface between a Sn-4.0wt%Ag-0.5wt%Cu solder ball and UBM treated by isothermal aging are reported. From the reflow process for the joint interface, a small amount of intermetallic compound was formed. With an increase in the isothermal aging time, the type and amount of the intermetallic compound changed. The interface without an isothermal treatment showed a ductile fracture. However, with an increase in the aging time, a brittle fracture occurred on the interface due mainly to the increase in the size of the intermetallic compounds and voids. As a result, a drastic degradation in the shear strength was observed. From a microshear test by a scanning electron microscope, the generation of micro-cracks was initiated from the voids at the joint interface. They propagated along the same interface, resulting in coalescence with neighboring cracks into larger cracks. With an increase in the aging time, the generation of the micro-structural cracks was enhanced and the degree of propagation also accelerated.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.35 no.6
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• pp.381-386
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• 2022

This paper details the analytical and experimental studies performed to propose a steel damper based on the flexural yielding mechanism. The damper is composed of a set of damping plates that are designed to yield in flexure. The comparison of experimental and finite element analysis results indicate that the analytical approach adopted in this study should be appropriate to perform sensitivity studies on the geometries of the damping plates. Although the damper is originally proposed to work based on the flexural mechanism, it is observed that the contribution of the tensile behavior of the damping plate could be considerable. As the thickness of the damping plate increases, the plastic energy due to the flexural yield increases. As the thickness of the damping plate decreases, the contribution of the tensile behavior increases, and the shape of the hysteresis loop distorts.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.1A
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• pp.15-26
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• 2010

Quasi-static tests were conducted to evaluate structural performance of precast piers prestressed by bonded prestressing steels. Combinations of prestressing bars and normal reinforcing bars, embedded steel tubes and prestressing strands were used as continuous steels crossing the joints of a precast pier. Main design parameters were steel ratio, magnitude of prestress force, and section details. Flexural strength and energy dissipation capacity of precast columns with higher steel ratio showed better performance due to continuous steels after opening of the joints. Precast piers with embedded members showed stable behavior after reaching maximum loads resulting in higher displacement ductility and energy dissipation capacity increased as the introduced prestress increased. Self-centering behavior at early stages and stress increase of confining reinforcements were observed from highly prestressed columns. Combination of prestressing steels and normal reinforcing bars should be used in design to prevent rapid strength degradation after reaching the maximum load.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.6
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• pp.193-200
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• 2023

This paper investigates the effect of directional alignment of steel fibers using an electromagnetic field on the flexural fracture behavior of steel fiber reinforced concrete. A specially designed and manufactured solenoid, capable of aligning steel fibers in the longitudinal direction of the beam specimen, was employed for this purpose. Beam specimens with a design strength of 30 MPa were produced, and failure tests were conducted on specimens exposed to electromagnetic fields and those without exposure. Experimental variables included the mixing ratio and aspect ratio of steel fibers. The results of the experiments revealed a slight increase in flexural strength and crack mouth opening displacement at the maximum load for specimens exposed to the electromagnetic field. Notably, a significant enhancement in fracture energy was observed.

• Structural Engineering and Mechanics
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• v.33 no.1
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• pp.31-46
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• 2009

An anisotropic damage mechanics approach is introduced which models the static and dynamic behavior of mass concrete in 3D space. The introduced numerical approach is able to model non-uniform cracking within the cracked element due to cracking in Gaussian points of elements. The validity of the proposed model is considered using available experimental and theoretical results under the static and dynamic loads. No instability and stress locking is observed in the conducted analyses. The Morrow Point dam is analyzed including dam-reservoir interaction effects to consider the nonlinear seismic behavior of the dam. It is found that the resulting crack profiles are in good agreement with those obtained from the smeared crack approach. It is concluded that the proposed model can be used in nonlinear static and dynamic analysis of concrete dams in 3D space and enables engineers to define the damage level of these infrastructures. The performance level of the considered system is used to assess the static and seismic safety using the defined performance based criteria.

• Bulletin of the Korean Chemical Society
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• v.27 no.3
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• pp.403-406
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• 2006

The surface structure and electrochemical behavior of self-assembled monolayers (SAMs) formed by aromatic thiols on Au(111) were investigated by scanning tunneling microscopy (STM) and cyclic voltammetry. Benzenethiol (BT) forms disordered phases on Au(111) which are composed of many bright domains, while benzyl mercaptan (BM), with a methylene unit between the aromatic group and sulfur atom, forms twodimensional ordered SAMs on Au(111). In addition, two phase-separated domains consisting of disordered and ordered phases were observed in binary SAMs formed from a 1 : 1 mixed ethanol solution of BT and BM. From STM and CV measurements, we found that the blocking efficiency of aromatic thiol SAMs coated on an Au(111) electrode for an electron transfer reaction decreases as the structural order of the SAMs increases. Molecular-scale STM and CV results obtained here will be very useful in designing functional SAMs for further applications, such as the improvement of corrosion passivation of Au(111) on an aromatic thiolmodified Au(111) surface.

• Structural Engineering and Mechanics
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• v.61 no.6
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• pp.785-794
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• 2017

This paper is concerned with the comparative numerical and experimental study on the natural behavior and the motion responses of a 1/75 moored scale model of a 2.5 MW spar-type floating offshore wind turbine subject to 1-D regular wave. Heave, pitch and surge motions and the mooring tensions are investigated and compared by numerical and experimental methods. The upper part of wind turbine which is composed of three rotor blades, hub and nacelle is modeled as a lumped mass and three mooring lines are pre-tensioned by means of linear springs. The numerical simulations are carried out by a coupled FEM-cable dynamics code, while the experiments are performed in a wave tank equipped with the specially-designed vision and data acquisition system. Using the both methods, the natural behavior and the motion responses in RAOs are compared and parametrically investigated to the fairlead position, the spring constant and the location of mass center of platform. It is confirmed, from the comparison, that both methods show a good agreement for all the test cases. And, it is observed that the mooring tension is influenced by all three parameters but the platform motion is dominated by the location of mass center. In addition, from the sensitivity analysis of RAOs, the coupling characteristic of platform motions and the sensitivities to the mooring parameters are investigated.