• 한국염색가공학회지
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• 제20권1호
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• pp.36-43
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• 2008

False twist texturing uses the thermoplastic property of synthetic yarn and produces a bulk and a stretch by giving the filament a permanent crimp. This study investigated the effects of false twist texturing parameters, disk/yarn(D/Y) and heater temperature, on the physical properties of nylon textured yarn. D/Y was a primary determinant of twist numbers of filaments and was proportionally increased with the twist numbers of filaments, resulting in an increase of crimp rigidity of the textured yarn. Heater temperature, a determinant of the heat setting of transformed filaments, was proportionally increased with the increase of crimp rigidity. Nylon 6 was partially melted at $190^{\circ}C$. This study consequently suggested the optimal parameters of nylon 6 85d/68f full-dull POY.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1997년도 춘계학술발표회 논문집
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• pp.26-31
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• 1997

유리섬유/nylon 6 복합재료의 계면결합강도를 증가시키기 위하여 r-APS(r-Aminopropyltriethoxysilane)로 유리섬유의 표면을 처리 하였다. 이때 표면처리의 최적 조건을 찾기위해서 처리후 기기분석과 계면결합강도 측정 등을 하였다. 농도, pH, 처리시간, 온도를 변화시키면서 표면처리를 한 후 흡착량을 살펴본 결과 처리 농도에 의해서는 흡착량이 단조증가하였으며 처리시간에 따라서는 5분정도에서, 처리온도에 의해서는 30C 부근에서 최대 흡착량을 보였다. 또한 pH에 따른 흡착량은 silane의 고유 pH인 10.5부근에서 최대치를 나타냈다. FR-IR 분석에 의하면 NH2의 NH3 bending mode가 1607cm-1, 1575cm-1에서 나타났으며 SiOH의 SiO band는 960cm-1에서 나타났다. XPS를 통해서는 N ls와 Si 2p의 존재를 확인할 수 있었다. 표면처리된 유리섬유와 matrix인 nylon 6를 이용해 단섬유내장시편을 만들어 fragmentation test를 한 결과 계면결합강도는 약 5분의 처리시간과 1%(wt%)의 농도에서 최대값을 보였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.16-20
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• 2003

As the preliminary works for the preparation of exfoliated nanocomposites by reactive extrusion (REX) the modified anionic polymerization proceeded in a flask using an $\varepsilon$-caprolactam, catalyst, initiator, and clay. Polymerization methods were classified with a variation of the clay adding time. Intercalations mechanism of clay layers was investigated by measuring the WAXD peaks of clay with polymerization. In the preparation of nanocomposites, the molecular weight of nylon 6 was affected by the clay content. From the mechanical property measurement, improved properties were obtained in comparison to the neat nylon 6, and these properties were also affected by the molecular weight.

• 한국의류학회지
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• 제23권2호
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• pp.326-334
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• 1999

Polyaniline(PAn)-nylon 6 composite fabrics were prepared by immersing the nylon 6 fabrics in 100% distilled aniline for specified diffusion time and drawn out. Then the excess aniline on the fabric surface was blotted and successive polymerization was initiate by immersing them into oxidant and dopant solution for in situ polymerization of polyaniline. Consequently highly conductive PAn-nylon 6 composite fabrics could be obtained and the conductivity reaches as high as 10-2 S/cm. The maximum conductivity was obtained when the fabric was immersed in 100% aniline at 4$0^{\circ}C$ for 3hours and polymerization was proceeded in 0.25M ammonium peroxydisulfate solution at 5$^{\circ}C$ for 1hour.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2011년도 제45차 학술발표회
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• pp.28-28
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• 2011

최근 초경량 직물에 나일론 Spiral Crimp 신축소재에 많이 사용되어지는 Mechanical 신축성 직물이 시판되고 있으나 신축특성의 저하, 품질 저하의 문제점이 대두되고 있어 아직까지 본격적으로는 상용화되지 못하고 있고 국내외적으로 아직까지 나일론 세섬사 Spiral Crimp 신축소재개발과 관련된 기술개발은 전무한 실정이다. 따라서 본 연구에서는 현재까지 국내외적으로 개발되지 못한 스포츠 아웃도어용 경량직물의 Mechanical 신축성 초경량 직물을 개발하기 위해서 중합단계에서 나일론 개질 폴리머를 개발하고, 수축 특성이 서로 다른 2종의 나일론 폴리머를 이용하여 side by side 형태로 세섬 복합방사와 사가공 및 연신 단계에서 2d급 Spiral Crimp 및 Super Bulky특성이 우수한 신축성 소재를 개발하여 이들의 구조와 물성을 조사 검토하여 이를 실제 현장에 자료를 제공하는 것을 목적으로 하였다.

• Elastomers and Composites
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• 제48권2호
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• pp.172-179
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• 2013

고분자 소재의 충격강도 증대를 위해 충격보강제를 이용하는 경우가 많다. 본 연구에서는 충격보강제가 함유된 나일론6에 대해서 충격보강 원리를 분석하고자 충격시험을 모사하였다. 이를 위해 나일론6에 포함된 충격보강제인 고무 첨가제의 모델링을 시도하였다. 모델링을 토대로 충격시험을 모사하고 충격시편 단면에서의 응력 분포 및 방향을 통해 충격강도 증대 원리를 관찰하였다. 시편 단면에서 충격보강제 유무에 따른 해석을 하여 비교하였고, 충격보강을 위해 사용되는 고무첨가제의 표면처리 여부에 따른 해석도 수행하여 응력을 비교하였다. 해석결과 노치에서 발생한 응력이 내부로 전파되면서 충격보강제 주변으로 경로가 바뀌면서 응력이 감소되는 현상이 나타났다. 특히 충격보강제를 함유한 시편에서 노치부 표면의 응력이 낮았다. 또한, 크랙이 발생하는 방향과 직각인 방향의 주 응력 크기도 충격보강제를 포함한 시편에서 낮게 나타났다. 이로 인해 크랙의 전파가 감소되고 충격강도가 증대되었다고 분석된다. 이러한 컴퓨터모사 방법은 복합재료의 물성 증대 원인을 파악하는데 활용할 수 있다고 판단된다.

• 한국자동차공학회논문집
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• 제10권6호
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• pp.142-149
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• 2002

The frictional properties of nylon can be improved by the impregnation of lubricants like wax, oil or graphite. The inclusion of these lubricants, on the other hand, decreases the mechanical properties of nylon, such as tensile strength, hardness and impact strength. As an attempt to maximize frictional properties, while minimizing a decrease in the mechanical properties, various kinds of nylon containing 3 wt% wax and varying contents of oil or graphite were prepared. It was found that the synergy effects to improve both friction and anti-wear properties is evidenced by impregnating a combination of wax/oil or wax/graphite. The wear rate of a nylon containing 3 wt% of wax and 1.5 wt% of oil turned out to be 1/4 of that of nylon impregnated with 8 wt% wax or 8 wt% oil. The latter showed the lowest wear rate among the nylons prepared with a single lubricant. In addition, the friction coefficient of the developed nylon was found to be very similar to the nylon with 8 wt% wax only.

• 한국염색가공학회지
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• 제26권2호
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• pp.88-98
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• 2014

This study is to assess the photocatalytic degradation of PET and Nylon 6 films containing nano-sized $TiO_2$ powders of anatase and rutile types. The PET and Nylon 6 films containing six kinds of the nanoparticles were prepared by melt casting method using a heating press machine. Reflectance in visible region and water contact angles of the irradiated PET and Nylon 6 composite films decreased with increasing UV/$O_3$ irradiation. Also the enhanced hydrophilicity has a close relationship with the increase in the Lewis base parameter, which indicates more oxidized polymer surfaces. The photocatalytic degradation of the nanocomposite films increased with increasing $TiO_2$ content and UV energy, which is more significant with the anatase types rather than the rutile types. The amide linkages in the Nylon 6 seemed to be more susceptible to the UV light compared to the ester groups in the PET, particularly in the presence of the $TiO_2$ photocatalysts. The photoscission and photodegradation of the polymers in the composites produced more degraded structure assisted by the photocatalytic activity of the $TiO_2$ nanoparticles. Also the composite films can bleach the methylene blue dyes more easily under the UV/$O_3$ irradiation, suggesting the photobleaching activity of the $TiO_2$ nanoparticles.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2001년도 학술발표회 논문집(Proceedings of the Korean Textile Conference) 상
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• pp.355-358
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• 2001

• 한국의류산업학회지
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• 제15권3호
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• pp.437-443
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• 2013

This paper investigates the physical properties of aramid and aramid/nylon hybrid air jet textured filaments for protective garments relative to ATY nozzle diameters. Three types of para-aramids(840d, 1,000d, 1,500d) and nylon(420d) filaments were prepared; in addition, 840d aramid/420d nylon and three kinds of aramid filaments were texturized with a variation of air jet nozzle diameters(0.6, 0.75, 1 and 1.2 mm) on the AIKI air jet texturing machine. The measured physical properties of 16 specimens are as follows. The linear densities of aramid and aramid/nylon hybrid ATY increased with a larger nozzle diameter. The tenacity and initial modulus of aramid and hybrid ATY linearly decreased with a larger nozzle diameter; in addition, the breaking strain increased with the nozzle diameter. The dry and wet thermal shrinkage of hybrid ATY increased with a larger nozzle diameter from 0.6 mm to 1 mm and then decreased at a nozzle diameter of 1.2 mm (which seems to be a critical diameter). The wet and dry thermal shrinkage of aramid/nylon hybrid ATY are influenced by the nylon part of the hybrid yarns because the wet and dry thermal shrinkages of aramid ATY are less than 0.2%. The instabilities of aramid and aramid/nylon hybrid ATY were not influenced by the air jet nozzle diameter; however, they increased with the linear density of ATY.