• Bulletin of the Korean Chemical Society
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• v.35 no.1
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• pp.93-97
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• 2014

A kinetic study is reported on nucleophilic substitution reactions of 4-nitrophenyl X-substituted-2-methylbenzoates (5a-e) with a series of cyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. The Hammett plots for the aminolysis of 5a-e are nonlinear, e.g., substrates possessing an electron-donating group (EDG) in the benzoyl moiety deviate negatively from the linear line composed of substrates bearing no EDG. In contrast, the Yukawa-Tsuno plots for the same reactions exhibit excellent linear correlations with ${\rho}_X$ = 0.30-0.59 and r = 0.90-1.15, indicating that the nonlinear Hammett plots are caused by stabilization of the substrates possessing an EDG through resonance interactions but are not due to a change in the rate-determining step (RDS). The Br${\phi}$nsted-type plots are linear with ${\beta}_{nuc}$ = 0.66-0.82. Thus, the aminolysis of 5a-e has been suggested to proceed through a stepwise mechanism in which departure of the leaving group occurs at the RDS. The ${\rho}_X$ and ${\beta}_{nuc}$ values for the aminolysis of 5a-e increase as the reactivity of the substrates and amines increases, indicating that the reactivity-selectivity principle is not applicable to the current reactions.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.24 no.2
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• pp.177-184
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• 2011

In this paper the nonlinear analysis that include time-dependent characteristics of materials and geometric nonlinearity of elements for the cable-stayed PSC bridges is presented. Analysis models for finite element method were developed based on the flexibility based fiber beam-column model originally proposed by Spacone et al.(1996). The developed analysis model implemented in general purpose object-oriented finite element analysis program named HFC(Cho 2009). The performance of proposed analysis models is evaluated by comparing with the former results of the design data. The deflection of time dependent analysis is larger than time ignored analysis on construction sequences, and the bridge is destructed at a smaller deflection than the time ignored analysis on failure behavior.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.4
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• pp.91-99
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• 2020

Post-installed anchors were widely used due to its workable benefits. Regarding the resistance performance of anchors, the critical edge distance is presented to minimize the impact of concrete splitting. In the case of actual anchors, however, it is difficult to obtain the ideal edge distance. The purpose of this study is to identify resistance performance and behavior characteristics that contain complex elements such as concrete crack occurring under tensile load. Tensile tests were conducted based on the standard method. Failure shape and the resistance characteristics that do not have the critical edge distance were derived by tensile load. Parametric analysis according to the boundary condition was performed to simulate the actual tensile behavior, through a nonlinear finite element model based on the specimen. Consequently therefore, verifying analysis results the resistance mechanism can be applied through boundary conditions.

• Journal of the Earthquake Engineering Society of Korea
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• v.1 no.4
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• pp.21-28
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• 1997

The aseismic capacity of a traditional three-bay-straw-roof wooden house for soft soil site condition is quantitatively estimated. One 1/4 scale model was tested for the Imperial Valley Earthquake up to failure. The natural frequency of the wooden house measured in elastic range is 1.66 Hz and 1.76 Hz in the longitudinal and transversal direction, respectively. Damping ratio of the house measured in elastic range is 7%. The peak horizontal acceleration response of the house was reduced compared with input motion due to the nonlinear inelastic characteristics of the wooden frame. The horizontal displacement response was significantly increased as the level of input motion was increased. The model was collapsed at 0.25g due to the low frequency contents of the input motion. The results of nonlinear seismic analysis were compared with the test results.

• Structural Engineering and Mechanics
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• v.14 no.2
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• pp.171-190
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• 2002

Two cases of design are performed for the hyperbolic paraboloid saddle shell (Lin-Scordelis saddle shell) and the hyperbolic cooling tower (Grand Gulf cooling tower) to check the design strength against a consistent design load, therefore to verify the adequacy of the design algorithm. An iterative numerical computational algorithm is developed for combined membrane and flexural forces, which is based on equilibrium consideration for the limit state of reinforcement and cracked concrete. The design algorithm is implemented in a finite element analysis computer program developed by Mahmoud and Gupta. The amount of reinforcement is then determined at the center of each element by an elastic finite element analysis with the design ultimate load. Based on ultimate nonlinear analyses performed with designed saddle shell, the analytically calculated ultimate load exceeded the design ultimate load from 7% to 34% for analyses with various magnitude of tension stiffening. For the cooling tower problem the calculated ultimate load exceeded the design ultimate load from 26% to 63% with similar types of analyses. Since the effective tension stiffening would vary over the life of the shells due to environmental factors, a degree of uncertainty seems inevitable in calculating the actual failure load by means of numerical analysis. Even though the ultimate loads are strongly dependent on the tensile properties of concrete, the calculated ultimate loads are higher than the design ultimate loads for both design cases. For the cases designed, the design algorithm gives a lower bound on the design ultimate load with respect to the lower bound theorem. This shows the adequacy of the design algorithm developed, at least for the shells studied. The presented design algorithm for the combined membrane and flexural forces can be evolved as a general design method for reinforced concrete plates and shells through further studies involving the performance of multiple designs and the analyses of differing shell configurations.

• Computers and Concrete
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• v.2 no.6
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• pp.423-437
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• 2005

In this study two single-bay, three-storey space frames, one with brick masonry infill in the second and third floors representing a soft-storey frame and the other without infill were designed and their 1:3 scale models were constructed according to non-seismic detailing and the similitude law. The models were excited with an intensity of earthquake motion as specified in the form of response spectrum in Indian seismic code IS 1893-2002 using a shake table. The seismic responses of the soft-storey frame such as fundamental frequency, mode shape, base shear and stiffness were compared with that of the bare frame. It was observed that the presence of open ground floor in the soft-storey infilled frame reduced the natural frequency by 30%. The shear demand in the soft-storey frame was found to be more than two and a half times greater than that in the bare frame. From the mode shape it was found that, the bare frame vibrated in the flexure mode whereas the soft-storey frame vibrated in the shear mode. The frames were tested to failure and the damaged soft-storey frame was retrofitted with concrete jacketing and, subjected to same earthquake motions as the original frames. Pushover analysis was carried out using the software package SAP 2000 to validate the test results. The performance point was obtained for all the frames under study, therefore the frames were found to be adequate for gravity loads and moderate earthquakes. It was concluded that the global nonlinear seismic response of reinforced concrete frames with masonry infill can be adequately simulated using static nonlinear pushover analysis.

• Structural Engineering and Mechanics
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• v.17 no.1
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• pp.51-68
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• 2004

Since the linear elastic fracture analysis has been proved to be insufficient in predicting the failure of strain hardening materials, a number of fracture concepts have been studied which remain applicable in the presence of plasticity near a crack tip. This work thereby presents a new finite element model to predict the elastic-plastic crack-tip field and fatigue life of center-cracked panels(CCP) with ductile fracture under large-scale yielding conditions. Also, this study has been carried out to investigate the path-dependence of J-integral within the plastic zone for elastic-perfectly plastic, bilinear elastic-plastic, and nonlinear elastic-plastic materials. Based on the incremental theory of plasticity, the p-version finite element is employed to account for the accurate values of J-integral, the most dominant fracture parameter, and the shape of plastic zone near a crack tip by using the J-integral method. To predict the fatigue life, the conventional Paris law has been modified by substituting the range of J-value denoted by ${\Delta}J$ for ${\Delta}K$. The experimental fatigue test is conducted with five CCP specimens to validate the accuracy of the proposed model. It is noted that the relationship between the crack length a and ${\Delta}K$ in LEFM analysis shows a strong linearity, on the other hand, the nonlinear relationship between a and ${\Delta}J$ is detected in EPFM analysis. Therefore, this trend will be depended especially in the case of large scale yielding. The numerical results by the proposed model are compared with the theoretical solutions in literatures, experimental results, and the numerical solutions by the conventional h-version of the finite element method.

• Journal of Korean Society of Steel Construction
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• v.23 no.2
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• pp.169-177
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• 2011

This paper presents the results of the systematic finite element analysis of the in-plane bending moment of T-joints subjected to cyclic loadings. T-joints were fabricated using high-strength, circular, hollow sections. Three-dimensional, nonlinear finite element models of the welded T-joints were constructed to investigate the strength, rotational-stiffness characteristics, and failure modes. A wide scope of structural behaviors explain the influence of the joint geometric parameters, such as the chord and brace wall slenderness ratios and the ratio of the brace to the chord diameter, as well as the yield strength ratios and compressive-chord-stress effects on the ultimate in-plane bending moment capacity of the T-joint.

• Structural Engineering and Mechanics
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• v.72 no.1
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• pp.43-60
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• 2019

This paper presents a finite element model which can simulate the axial compression behavior of steel reinforced recycled concrete (SRRC) filled square steel tube columns using the ABAQUS software. The analytical model was established by selecting the reasonable nonlinear analysis theory and the constitutive relationship of material in the columns. The nonlinear analysis of failure modes, deformation characteristics, stress nephogram, and load-strain curves of columns under axial loads was performed in detail. Meanwhile, the influences of recycled coarse aggregate (RCA) replacement percentage, profile steel ratio, width thickness ratio of square steel tube, RAC strength and slenderness ratio on the axial compression behavior of columns were also analyzed carefully. It shows that the results of finite element analysis are in good agreement with the experimental results, which verifies the validity of the analytical model. The axial bearing capacity of columns decreased with the increase of RCA replacement percentage. While the increase of wall thickness of square steel tube, profile steel ratio and RAC strength were all beneficial to improve the bearing capacity of columns. Additionally, the parameter analysis of finite element analysis on the columns was also carried out by using the above numerical model. In general, the SRRC filled square steel tube columns have high bearing capacity and good deformation ability. On the basis of the above analysis, a modified formula based on the American ANSI/AISC 360-10 was proposed to calculate the nominal axial bearing capacity of the columns under axial loads. The research conclusions can provide some references for the engineering application of this kind of columns.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.44 no.1
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• pp.26-36
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• 2021

The topic of this study is the field of humanitarian logistics for disaster response. Many existing studies have revealed that compliance with the golden time in response to a disaster determines the success or failure of relief activities, and logistics costs account for 80% of the disaster response cost. Besides, the agility, responsiveness, and effectiveness of the humanitarian logistics system are emphasized in consideration of the disaster situation's characteristics, such as the urgency of life-saving and rapid environmental changes. In other words, they emphasize the importance of logistics activities in disaster response, which includes the effective and efficient distribution of relief supplies. This study proposes a mathematical model for establishing a transport plan to distribute relief supplies in a disaster situation. To determine vehicles' route and the amount of relief for cities suffering a disaster, it mainly considers the urgency, effectiveness (restoration rate), and uncertainty in the logistics system. The model is initially developed as a mixed-integer nonlinear programming (MINLP) model containing some nonlinear functions and transform into a Mixed-integer linear programming (MILP) model using a logarithmic transformation and piecewise linear approximation method. Furthermore, a minimax problem is suggested to search for breakpoints and slopes to define a piecewise linear function that minimizes the linear approximation error. A numerical experiment is performed to verify the MILP model, and linear approximation error is also analyzed in the experiment.