• Polymer(Korea)
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• v.28 no.1
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• pp.24-34
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• 2004

Transient sorption experiments were conducted among several combinations of fluoropolymers and various organic solvents. Fully fluorinated polymer tended to exhibit ideal sorption behavior, while partially fluorinated polymers showed anomalous sorption behaviors with a drastic acceleration at the final stage of uptake. Minimization of least-squares of the measured and predicted fractional uptake, which indicated the increasing degree of deviation from Fickian diffusion, gave values of 3.0${\times}$10$\^$-4/, 1.75${\times}$10$\^$-3/, 8.68${\times}$10/sup-3/, 1.75${\times}$10$\^$-2/, respectively, for perfluoroalkoxy copolymer, poly(ethylene-co-tetrafluoroethylene), poly(vinylidene fluoride), poly(ethylene-co-chlorotrifluoroethylene). From stress-strain tests, it was confirmed that non-Fickian diffusion is closely related to the significant variation of mechanical properties (such as modulus and tensile strength) of swollen polymer. Anomalous sorption behavior stemmed from non-Fickian diffusion caused by nonlinear disruption of polar inter-segmental bonds due to solvent-induced plasticization. Thus, it is imperative to investigate the diffusion behavior of swelling solvents in partially fluorinated polymers, especially for the application to barrier materials or perm-selective membranes.

• The Korean Journal of Rheology
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• v.11 no.1
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• pp.18-27
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• 1999

Predicting the deformation behaviors of sheets in thermoforming processes has been a daunting challenge due to the strong nonlinearities arising from very large deformations, mold-polymer contact condition and hyperelasticity constitutive equations. Nonlinear numerical analysis is always required to face this challenge especially for realistic processing conditions. In this study a 3-D algorithm and the membrane approximation are developed for thermoforming processes. The constitutive equation is expressed in terms of the 2nd Piola-Kirchhoff stress tensor and the Cauchy-Green deformation tensor. The 2-term Mooney-Rivlin model is used for the material model equation. The algorithm is established by the finite element formulation employing the total Lagrangian coordinate. The deformation behavior and the stress distribution results of 3-D algorithm with various point boundary conditions are compared to those of the membrane approximation algorithm. Also, the slip boundary condition and the no-slip boundary condition are applied for the systems that have molds. Finally, the effect of sheet temperatures on the final thickness distribution is investigated for the ABS material.

• Journal of the Korea Concrete Institute
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• v.28 no.4
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• pp.473-480
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• 2016

The purpose of this study is to provide analytical method to reasonably evaluate the complicated failure behaviors of shear friction of reinforced concrete shear wall specimens using grade 500 MPa high-strength bars. A total of 16 test specimens with a variety of variables such as aspect ratio, friction coefficient of interface in construction joint, reinforcement details, reinforcement ratio in each direction, material properties were selected and the analysis was performed by using a non-linear finite element analysis program (RCAHEST) applying the modified shear friction constitutive equation in interface based on the concrete design code (KCI, 2012) and CEB-FIP Model code 2010. The mean and coefficient of variation for maximum load from the experiment and analysis results was predicted 1.04 and 17% respectively and properly evaluated failure mode and overall behavior characteristic until failure occur. Based on the results, the analysis program that was applied modified shear friction constitutive equation is judged as having a relatively high reliability for the analysis results.

• Composites Research
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• v.16 no.5
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• pp.45-53
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• 2003

The experimental and numerical investigations on the failure characteristics of the secondary bonded composite single-lap joints were performed. The initiations and growths of cracks were observed using CCD camera and acoustic emission sensor during the tension tests of the joint specimens. The structural behaviors of the specimens were predicted by the geometric nonlinear two-dimensional finite element analysis. The three types of observed initial cracks were included in each finite element models and the strain energy release rates of each specimen models were calculated by VCCT(Virtual Crack Closure Technique) technique. The tension tests showed that the initial cracks occurred in the 60∼90% of final failure loads and the major failure modes of the specimens were adhesive failure and the delamination between the 1st and 2nd ply of laminate. The specimens with the thicker bondline had earlier crack initiation loads but higher crack propagation resistance and eventually better loading capability. The delaminations were mostly observed in the thicker bondline specimens. The mode I values of calculated strain energy release rates were higher than the mode II values in the all specimen models considering the three types of initial cracks. The mode I and total strain energy release rates were calculated as higher values in the order of initial crack in the edge interface, comer interface and delamination between the plies of laminate.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.3
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• pp.195-206
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• 2011

The capacity spectrum method(CSM) has been more frequently used as a tool to evaluate the seismic capacity of the structure. Many formulas of strength reduction factors(SRF) have been proposed and adopted to generate the inelastic demand spectrum for the CSM. This study evaluates the impacts of the type of the SRF on the inelastic demand spectrum and finally on the seismic response displacement of curved bridge. For the purpose, the several existing formulas of SRFs were comparatively investigated through the case study. Curved bridges with different subtended angles were selected and the displacements of the bridge piers were estimated by using the different formulas of SRFs. Nonlinear time history analyses were also performed for the validation purpose of the CSM results. According to study results, the CSM may generate the larger displacement responses than the actual behaviors for the curved bridge with larger subtended angles. Though many methods have been suggested to generate the inelastic demand spectrum for CSM, they might not give noticeable differences in inelastic displacement of the bridge pier.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.1
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• pp.1-7
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• 2017

In general, the large loads which are applied from explosion, impact, earthquake and wind at a short time caused the materials of structures to large deformations, rotations and strains locally. If such phenomena will be analyzed, hydrocodes which can be considered fluid-structure interaction under computational continuum mechanics are inevitably needed. Also, the explosion mechanism is so complicated, it is reasonable that the behaviors of structure are predicted through explosion analyses and experiment at the same time. But, unfortunately, it is true that explosion experiments are limited to huge cost, large experiment facilities and safety problems. Therefore, in this study, it is shown that the results of explosion analyses using the AUTODYN are agreed with those of existing explosion experiments for reinforced concrete slabs within reasonable error limits. And the explosion damage of the same reinforced concrete slab are assessed for quite different reinforcement arrangement spacings, concrete cover depths, and vertical reinforcements. From the explosion analyses, it is known that the more the ratio of slab thickness to reinforcement arrangement spacing is increased, and small-diameter reinforcements are used than large-diameter reinforcements on the same reinforcement ratio, and vertical reinforcements are used, the more the anti-knock capacities are improved.

• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.587-594
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• 2005

The purpose of seismic design is to ensure the serviceability of buildings against earthquake, which might be occurred during the service life of buildings, and to minimize the loss of life by preventing their failure under strong earthquake. The lack resistance of walls resulting from a tendency toward high-rise apartment buildings with shear walls and use of piloti would lead to a concentration of inelastic behaviors in their weak story. In this study, the seismic performance of reinforced concrete shear wall buildings haying piloti was analyzed by using the evaluation techniques which was proposed by FEMA 273 and ATC-40. The results from comparison with these two techniques are summarized as follows.; The results of elastic analysis method for seismic performance evaluation show that the effect of piloti and building height decrease performance index. In case of shear wall building, the state of insufficient shear stress governs their overall performance and it becomes evident in the case of the buildings with more than 25 stories. For the buildings of piloti, the change of mass, weak story, as well as insufficient shear stress, decrease the performance index rapidly compared with the performance index of the buildings without piloti. The results, obtained from the nonlinear static analysis using capacity spectrum method, indicate that the performance Point increases for the structure having Piloti and high story. Also, deformation limits of buildings satisfy the allowable criteria at the life safety level, but the immediate occupancy level is exceeded in buildings which have more than 25 stories.

• Journal of the Korean Ceramic Society
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• v.40 no.11
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• pp.1078-1084
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• 2003

In order to develop a new type of nonlinear optical materials or photocatlaysts, Na$_2$O-Nb$_2$ $O_{5}$-Te $O_2$ glasses were prepared using conventional melt quenching method, and the crystallization behaviors and optical properties of these glasses was investigated. The optical and physical properties for Na$_2$O-Nb$_2$ $O_{5}$-Te $O_2$ glasses are: refractive index, n=2.04$\pm$0.04; density, p (g/㎤)=4.87$\pm$0.58; optical energy band of the transmission cut-off wavelength, E$_{0}$ (eV)=3.14$\pm$0.04. The transparent glass ceramics consisting of the nanocrysatls were obtained when the Na$_2$O-Nb$_2$ $O_{5}$-Te $O_2$ glass was first heat-treated at 3$50^{\circ}C$ for 1 h and than at 40$0^{\circ}C$ for 1 h. A cubic crystalline phase consisting of the nano-crysatls transforms into a stable phase at temperature above 47$0^{\circ}C$ for 1 h.

• Journal of the Korean Geosynthetics Society
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• v.13 no.4
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• pp.97-107
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• 2014

Finite element modelling and analysis were conducted for the roll-type steel mats which were placed on loose sand and subjected to a standard truck wheel load in this study. The roll-type steel mats mean that the steel mats can be folded as a circle shape for the carrying to fields in cold regions where workability is limited and are developed for a rapid rehabilitation method for roadway across soft ground which is caused by thawing during the summer season in cold regions. The model is composed of link elements to simulate nonlinear behavior of connections between steel mats, thick shell elements to have flexural stiffness of the steel mats, and springs to simulate characteristics of foundation soils. The structural behaviors of the shell, link elements, and springs were verified at each modelling step through experiment and analysis. Beam and shell analysis without the link elements were conducted and compared to results obtained from the model presented in this study. Significant vertical displacement is shown in the shell model with hinge connections. Therefore, the results demonstrate that the analysis model for the roll-type steel mats on loose sand needs further detail parametric studies.

• Journal of Soil and Groundwater Environment
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• v.9 no.3
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• pp.12-19
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• 2004

Binding mechanisms of polycyclic aromatic hydrocarbons (PAHs) with a purified Aldrich humic acid (PAHA) and its ultrafiltration (UF) size fractions were investigated. Organic carbon normalized binding coefficient ($K_oc$) values were estimated by both a conventional Stern-Volmer fluorescence quenching technique and a modified fluorescence quenching method. Pyrene $K_oc$ values depended on PAHA concentration as well as freely dissolved pyrene concentration. Such nonlinear sorption-type behaviors suggested the existence of specific interactions. Smaller molecular size PAH (naphthalene) exhibited higher $K_oc$ value with medium-size PAHA UF fractions whereas larger size PAH (pyrene) had higher extent of binding with larger PAHA UF fractions. The inconsistent observation for naphthalene versus pyrene was well explained by size exclusion effect, one of the previously suggested specific mechanisms for PAH binding. In general, the extent of pyrene binding increased with lower pH likely due to the neutralization of acidic functional groups in HS and the subsequent increase in hydrophobic HS region. However, pyrene $K_oc$ results with a large UF fraction (>100K Da) corroborated the existence of the size exclusion effect as demonstrated by an increase in $K_oc$ values at a certain higher pH range. The size exclusion effect appears to be effective only for the specific conditions (HS size or pH) that render HS hole st겨ctures to fit a target PAH.