• Title/Summary/Keyword: nonequilibrium state

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Prediction of NOx Formation Characteristics in Turbulent Nonpremixed Hydrogen-Air Jet Flames (비예혼합 수소-공기 난류제트화염내의 NOx 생성특성 예측)

  • Kim, S.K.;Kim, Y.M.;Ahn, K.Y.;Oh, K.S.
    • 한국연소학회:학술대회논문집
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    • 1998.10a
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    • pp.165-170
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    • 1998
  • Turbulent nonpremixed $H_2$-air jet flames are numerically investigated using the joint PDF model. The reaction progress variable is derived by assuming the radicals 0, H, and OH to be in partial equilibrium and additional species $HO_2$ and $H_2O_2$ in steady state. The model is extended to npnadiabatic flame by introducing additional variable for the transport of enthalpy and radiative source term is calculated using a local, geometry independent model. In terms of flame structure and NO formation, the predicted results are favorably agreed with experimental data. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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Three-Temperature Modeling of Carrier-Phonon Interactions in Thin GaAs Film Structures Irradiated by Picosecond Pulse Lasers

  • Lee Seong-Hyuk;Lee Jung-Hee;Kang Kwan-Gu;Lee Joon-Sik
    • Journal of Mechanical Science and Technology
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    • v.20 no.8
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    • pp.1292-1301
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    • 2006
  • This article investigates numerically the carrier-phonon interactions in thin gallium arsenide (GaAs) film structures irradiated by subpicosecond laser pulses to figure out the role of several recombination processes on the energy transport during laser pulses and to examine the effects of laser fluences and pulses on non-equilibrium energy transfer characteristics in thin film structures. The self-consistent hydrodynamic equations derived from the Boltzmann transport equations are established for carriers and two different types of phonons, i.e., acoustic phonons and longitudinal optical (LO) phonons. From the results, it is found that the two-peak structure of carrier temperatures depends mainly on the pulse durations, laser fluences, and nonradiative recombination processes, two different phonons are in nonequilibrium state within such lagging times, and this lagging effect can be neglected for longer pulses. Finally, at the initial stage of laser irradiation, SRH recombination rates increases sufficiently because the abrupt increase in carrier number density no longer permits Auger recombination to be activated. For thin GaAs film structures, it is thus seen that Auger recombination is negligible even at high temperature during laser irradiation.

Thermal transport in thorium dioxide

  • Park, Jungkyu;Farfan, Eduardo B.;Enriquez, Christian
    • Nuclear Engineering and Technology
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    • v.50 no.5
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    • pp.731-737
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    • 2018
  • In this research paper, the thermal transport in thorium dioxide is investigated by using nonequilibrium molecular dynamics. The thermal conductivity of bulk thorium dioxide was measured to be 20.8 W/m-K, confirming reported values, and the phonon mean free path was estimated to be between 7 and 8.5 nm at 300 K. It was observed that the thermal conductivity of thorium dioxide shows a strong dependency on temperature; the highest thermal conductivity was estimated to be 77.3 W/m-K at 100 K, and the lowest thermal conductivity was estimated to be 4.3 W/m-K at 1200 K. In addition, by simulating thorium dioxide structures with different lengths at different temperatures, it was identified that short wavelength phonons dominate thermal transport in thorium dioxide at high temperatures, resulting in decreased intrinsic phonon mean free paths and minimal effect of boundary scattering while long wavelength phonons dominate the thermal transport in thorium dioxide at low temperatures.

Prediction of a Strong Effect of a Wek Magnetic Field on Diffusion Assisted Reactions in Non Equilibrium Conditions

  • Kipriyanov, Alexey A. Jr.;Purtov, Peter A.
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.1009-1014
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    • 2012
  • The influence of magnetic fields on chemical processes has long been the subject of interest to researchers. For this time numerous investigations show that commonly the effect of a magnetic field on chemical reactions is insignificant with impact less than 10 percent. However, there are some papers that point to the observation of external magnetic field effect on chemical and biochemical systems actually having a significant impact on the reactions. Thus, of great interest is an active search for rather simple but realistic models, that are based on physically explicit assumptions and able to account for a strong effect of low magnetic fields. The present work theoretically deals with two models explaining how an applied weak magnetic field might influence the steady state of a non-equilibrium chemical system. It is assumed that external magnetic field can have effect on the rates of radical reactions occurring in a system. This, in turn, leads to bifurcation of the nonequilibrium stationary state and, thus, to a drastic change in the properties of chemical systems (temperature and reagent concentration).

Modeling of Hydrodynamic Processes at a Large Leak of Water into Sodium in the Fast Reactor Coolant Circuit

  • Perevoznikov, Sergey;Shvetsov, Yuriy;Kamayev, Aleksey;Pakhomov, Ilia;Borisov, Viacheslav;Pazin, Gennadiy;Mirzeabasov, Oleg;Korzun, Olga
    • Nuclear Engineering and Technology
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    • v.48 no.5
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    • pp.1162-1173
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    • 2016
  • In this paper, we describe a physicomathematical model of the processes that occur in a sodium circuit with a variable flow cross-section in the case of a water leak into sodium. The application area for this technique includes the possibility of analyzing consequences of this leak as applied to sodium-water steam generators in fast neutron reactors. Hydrodynamic processes that occur in sodium circuits in the event of a water leak are described within the framework of a one-dimensional thermally nonequilibrium three-component gas-liquid flow model (sodium-hydrogen-sodium hydroxide). Consideration is given to the results of a mathematical modeling of experiments involving steam injection into the sodium loop of a circulation test facility. That was done by means of the computer code in which the proposed model had been implemented.

Theoretical and Practical Aspects of Pb-Sn Alloy Plating (Pb-Sn 합금도금의 이론 및 실제적 경향)

  • Paik, Young-Nam
    • Journal of the Korean institute of surface engineering
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    • v.12 no.3
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    • pp.161-166
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    • 1979
  • Theoretical and practical aspects are investigated for electrochemical behavious, plating processes and the structures of electrodeposit of Pb-Sn binary alloy plating through numerous literatures in this report. The anodic and cathodic electrode reaction mechanisms of Pb and Sn could co-deposit and make Pb-Sn alloy deposit from the results of cathode current density-cathode potential curves of Pb, Sn and Pb-Sn alloys in fluoborate solutions. The compositions of the best alloy plating solutions are obtained for the purpose of bearing, anticorrosion and solder plating. In general, the casting anodes of Pb-Sn alloys are used, but separated anodes of Pb and Sn pure metal are used in order to obtain the fine compositions of Pb-Sn alloy deposits. The electrodeposits of Pb-Sn alloy are in nonequilibrium state and saturated solid solutions. Thus, ${\beta}$-phase (Sn-phase) is precipitated by heat treatment. The texture and structure of the electrodeposit are associated with the surface energies of deposit lattice planes and with the cathode polarization. The electrodeposit of Pb-Sn alloy is shown as lamellar structure.

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A Dynamic Method for Boundary Conditions in Lattice Boltzmann method

  • Suh, Yong-Kweon;Kang, Jin-Fen;Kang, Sang-Mo
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2797-2802
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    • 2007
  • It has been confirmed that implementation of the no-slip boundary conditions for the lattice-Boltzmann method play an important role in the overall accuracy of the numerical solutions as well as the stability of the solution procedure. We in this paper propose a new algorithm, i.e. the method of the dynamic boundary condition for no-slip boundary condition. The distribution functions on the wall along each of the links across the physical boundary are assumed to be composed of equilibrium and nonequilibrium parts which inherit the idea of Guo's extrapolation method. In the proposed algorithm, we apply a dynamic equation to reflect the computational slip velocity error occurred on the actual wall boundary to the correction; the calculated slip velocity error dynamically corrects the fictitious velocity on the wall nodes which are subsequently employed to the computation of equilibrium distribution functions on the wall nodes. Along with the dynamic selfcorrecting process, the calculation efficiently approaches the steady state. Numerical results show that the dynamic boundary method is featured with high accuracy and simplicity.

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A Study on the Ram Accelerator Performance Improvement Using Numerical Optimization Techniques (수치 최적화 기법을 이용한 램 가속기 성능 향상 연구)

  • Jeon Yong-Hee;Lee Jae-Woo;Byun Yung-Hwan
    • 한국전산유체공학회:학술대회논문집
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    • 1999.11a
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    • pp.77-84
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    • 1999
  • Numerical design optimization techniques are implemented for the improvement of the ram accelerator performance. The design object is to find the minimum ram tube length required to accelerate projectile from initial velocity $V_0$ to target velocity $V_e$. The premixture is composed of $H_2,\;O_2,\;N_2$ and the mole numbers of these species are selected as design variables. The objective function and the constraints are linearized during the optimization process and gradient-based Simplex method and SLP(Sequential Linear Programming) have been employed. With the assumption of two dimensional inviscid flow for internal flow field, the analyses of the nonequilibrium chemical reactions for 8 steps 7 species lave been performed. To determined the tube length, ram tube internal flow field is assumed to be in a quasi-steady state and the flow velocity is divided into several subregions with equal interval. Hence the thrust coefficients and accelerations for corresponding subregions are obtained and integrated for the whole velocity region. With the proposed design optimization techniques, the total ram tube length had been reduced $19\%$ within 7 design iterations. This optimization procedure can be directly applied to the multi-stage, multi-premixture ram accelerator design optimization problems.

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Passive control of condensation shock wave in supersonic nozzles (초음속 노즐에서 발생하는 응축충격파의 피동제어)

  • Kim, Hui-Dong;Gwon, Sun-Beom;Setoguchi, Toshiaki
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.12
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    • pp.3980-3990
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    • 1996
  • When a moist air is rapidly expanded in a supersonic nozzle, nonequilibrium condensation occurs at a supersaturation state. Condensation shock wave appears in the nozzle flow if the releasing latent heat due to condensation goes beyond a critical value. It has been known that self-excited oscillations of the condensation shock wave generate in an air or a steam nozzle flow with a large humidity. In the present study, the passive control technique using porous wall with a cavity underneath was applied to the condensation shock wave. The effects of the passive control on the steady and self-excited condensation shock waves were experimentally investigated by Schlieren visualization and static pressure measurements. The result shows that the present passive control is a useful technique to suppress the self-excited oscillations of condensation shock wave.