• Title/Summary/Keyword: non-polar oil

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A Study on the Mutagenicity of Thermally Oxidized Safflower Oil (가열산화 홍화유의 돌연변이원성에 관한 연구)

  • 안명수;이진영
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.1
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    • pp.120-127
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    • 2000
  • Deep-fat frying is a common cooking practice. There has been considerable concern regarding the mutagenic and carcinogenic potential of thermally oxidized oils. Studies on deep-fried foods so far have revealed not much on the mutagenicity of the oils in the foods. Therefore, in the present study, it was attempted to investigate the mutagenicity ofthe thermally oxidized safflower oil. Oil was heated in a home-fryer at a temperature of 180$\pm$3$^{\circ}C$ for 48 hours. Oil samples were taken at 0, 8, 16, 24, 32, 40 and 48 hours of heating, respectively. Each sample was used to study the changes in peroxide value (POV), acid value (AV), iodine value (IV), conjugated dienoic acid (CDA) content, %, and fatty acid composition. Another series of samples were fractionated into non-polar and polar fractions by column chromatography. The mutagenicity of the samples taken from the thermally oxidized oils, as well as the non-polar and polar fractions of the thermally oxidized oils, was investigated with the Ames test. The Ames test was carried out with and without metabolic activation. Bacterial tester strains used in the present study were the histidine auxotrophic strains of Salmonella typhimurium TA100, TA1535 and TA102 were used for the detection of base pair mutations, and TA98 and TA1537 for frame shift mutations. Each series of samples was dissolved in tetraphydrofuran (inhibitor-free) and tested at doses ranging from 0.05 to 5 mg/plate. None of the oil samples taken during the 48 hour oxidation period showed any mugagenic activity. This was the case, even after the activaton with 59 mix. Also, none of the polar and non-polar fractions showed any mutagenic activity on all the strains tested.

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A Study on the Stability of Emulsion by Polyglycerol Ester (폴리글리세롤 에스터를 이용한 안정한 에멀젼의 제조연구)

  • Kang, Ki-Chun;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.152-159
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    • 2013
  • Experiments of emulsion particles state of using polyglycerol ester emulsifier and the stability in accordance with the change of time were conducted using several oil. Experimental results confirmed that there is little difference in the stability and particle size depending on the type of oil. Most stable oil with polyglycerol ester is polar oil of silicon series and fatty acid ester oil, hydrocarbon oil of the nonpolar oil (Mineral oil, squalane, polydecene) was the most unstable state. And vegetable oils showed the stable form of particles with polyglycerol ester emulsifier.

Simultaneous Extraction and Separation of Oil and Azadirachtin from Seeds and Leaves of Azadirachta indica using Binary Solvent Extraction

  • Subramanian, Sheela;Salleh, Aiza Syuhaniz;Bachmann, Robert Thomas;Hossain, Md. Sohrab
    • Natural Product Sciences
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    • v.25 no.2
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    • pp.150-156
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    • 2019
  • Conventional extraction of oil and azadirachtin, a botanical insecticide, from Azadirachta indica involves defatting the seeds and leaves using hexane followed by azadirachtin extraction with a polar solvent. In order to simplify the process while maintaining the yield we explored a binary extraction approach using Soxhlet extraction device and hexane and ethanol as non-polar and polar solvents at various ratios and extraction times. The highest oil and azadirachtin yields were obtained at 6 h extraction time using a 50:50 solvent mixture for both neem leaves (44.7 wt%, $720mg_{Aza}/kg_{leaves}$) and seeds (53.5 wt%, $1045mg_{Aza}/kg_{leaves}$), respectively.

The DNA Damage of Fish Oil Peroxidation Products 2. DNA Damage by the Peroxidation Products of Polar and Non-polar Lipid Fractionated from Mackerel Lipid (어유산화생성물의 DNA손상작용 2. 극성 및 비극성지질획분산화생성물의 DNA 손상작용)

  • KANG Jin-Hoon;Do Jung-Roung;KIM In-Soo;KIM Seon-Bong;PARK Young-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.4
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    • pp.300-307
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    • 1987
  • The present study was investigated on the DNA damage by the peroxidation of polar and non-polar lipid fractionated from mackerel lipid to elucidate the DNA damage mechanism by fish oil peroxidation. The degree of DNA damage by polar lipid peroxidation became greater with the increase of its concentration, and such DNA damage was induced below 100 millieq./kg in POV for 4 days incubation. Among the polar lipid peroxidation products, singlet oxygen $^1O_2$ and superoxide anion ${\cdot}O_2^-$ greatly affected to the DNA damage than hydrogen peroxide $H_2O_2$ and hydroxyl radical ${\cdot}OH$. Non-polar lipid peroxidation also induced the DNA damage with the increase of its concentration, but such effect was lower than the case of total lipid and polar lipid. And, the effects of active crygens on the DNA damage by non-polar lipid peroxidation was the same as in the case of total and polar lipid peroxidation.

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Studies on Antioxidant Activity of Ethanol Extracts from Defatted Perilla Flour (탈지들깨박 Ethanol 추출물의 항산화 효과)

  • Yoon, Suk-Kwon;Kim, Jung-Han;Kim, Ze-Uk
    • Korean Journal of Food Science and Technology
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    • v.25 no.2
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    • pp.160-164
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    • 1993
  • The antioxidant activity of ethanol extracts from defatted perilla flour was investigated by measuring peroxide value of perilla oil during storage at $45^{\circ}C$. The antioxidant activity of ethanol extracts was also compared with BHA, BHT and tocopherol. Anti-oxidant activity of ethanol extracts was also examined in corn oil and lard. The ethanol extracts contents of defatted perilla flour and the original perilla seed were 7.69 and 4.56% respectively. The antioxidant activity of ethanol extracts was superior to that of 0.02% BHT, BHA and tocopherol in the perilla oil substrate, merely in concentration of one-twentieth as much as that contained in original perilla oil seeds. The fractions of non-polar solvent (hexane and chloroform) obtained from silicic acid column chromatography are less effective than that of polar solvent as an antioxidant. Antioxidant activity of partially purified ethanol fraction is slightly inferior to that of original crude ethanol extracts. Ethanol extracts were also effective in corn oil and lard almost same as in perilla oil. The total phenolic compound contents of crude ethanol extracts and partially purified ethanol fraction were 9.3, 6.4%, respectively.

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Performance and Emission Studies in a DI Diesel Engine Fuelled with Diesel-Pyrolysis Oil Emulsion (디젤-열분해유 유상액을 사용하는 직접분사식 디젤 엔진의 엔진성능 및 배기특성에 관한 연구)

  • Lee, Seokhwan;Kim, Hoseung;Kim, Taeyoung;Woo, Sejong;Kang, Kernyong
    • Journal of ILASS-Korea
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    • v.19 no.2
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    • pp.55-63
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    • 2014
  • Pyrolysis oil (PO), also known as Bio crude oil (BCO), has the potential to displace significant amounts of fuels that are currently derived from petroleum sources. PO has been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of PO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the PO. One of the easiest way to adopt PO to diesel engine without modifications is emulsification of PO with the fuels that has higher cetane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel. Thus, to stabilize a homogeneous phase of diesel-PO blends, a proper surfactant should be used. In this study, a DI diesel engine operated with diesel and diesel-PO emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by diesel-PO emulsions were examined. Results showed that stable engine operation was possible with the emulsions and engine output power was comparable to diesel operation.

High Performance Size Exclusion Chromatographic Analysis of Polymerization Products in Used Frying Oil (High Performance Size Exclusion Chromatography 를 이용한 튀김유의 중합체 분석)

  • Kim, In-Whan;Kim, Chul-Jin;Shin, Hyun-Kyung
    • Korean Journal of Food Science and Technology
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    • v.22 no.1
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    • pp.33-37
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    • 1990
  • A simple and rapid method, based on separation of a flying oil into monomeric, dimeric and oligomeric triglyceride by means of high performance size exclusion chromatography on Ultrastyragel column (500 A), is proposed for evaluation of the quality of used frying oil. The relative area of the monomeric triglyceride was decreased with frying time increase, however, the decrease rate was significantly reduced by treatment of a composited powder (porous rhyorite/citric acid 40/56/4). This measurement showed good linear relationship with change in polar component measurement. There were no significant differences between the slopes of regression lines in both treated and non-treated frying oil system for relationship between monomeric triglyceride and polar component. By this method, it was found that a frying oil habe to be discarded if the content monomeric triglyceride decreased to 71%, which was corresponed to 27% polar component.

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Impregnation of Castanea creanata Wood by Hydrophobic Oil

  • Ahmed, Sheikh Ali;Lee, Kyoung-Min;Chun, Su-Kyoung
    • Journal of the Korea Furniture Society
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    • v.19 no.1
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    • pp.91-96
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    • 2008
  • This paper investigates the penetration of essential oil into radial and longitudinal directions of Castanea crenata. Present study was performed to know the essential oil penetration depth in radial and longitudinal direction of Castanea crenata. Essential oil penetration depth was found higher in longitudinal direction than in radial direction and it was about 53 times high at 15.0 second of penetration. In early wood, fiber conducted oil more than that of large vessel. In heartwood, fiber had played an important role for the conduction of oil. But in sapwood, small vessel conducted oil deeper than wood fiber, which was also significantly different from large. On the other hand, large vessel in heartwood had statistically lower penetration depth than that of fiber and small vessel. At the beginning of penetration the speed was high and gradually decreased in course of time.

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Numerical Analysis of Helical Pile Behavior Varying Number and Diameter of Helices (헬릭스 개수 및 직경에 따른 헬리컬 파일 거동의 수치해석적 분석)

  • Bak, Jongho;Lee, Kicheol;Choi, Byeong-Hyun;Kim, Dongwook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.39 no.1
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    • pp.211-217
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    • 2019
  • Oil extraction from oil sands, a non-traditional crude oil resource, is attracting attention as the oil price fluctuates due to recent economical and political issues. Many oil sands sites are mainly located in the polar regions. For plant construction to extract crude oil from oil sands in harsh environment of the polar regions, fast and simple installation of plant foundation is necessary. However, typically-used conventional foundations such as drilled shafts and driven piles are not suitable to construct under cold temperature and organic surface layers. In this study, helical piles enabling rapid and simple constructions using small rotary equipment without driving or excavation was considered. The helical pile consists of steel shaft and several helices attached to the steel shaft; therefore, the behavior of the helical pile depends on the number and shape of the helices. The effect of the helices' configuration (number and diameter of helices) on helical pile behavior was analyzed based on the numerical analysis results.

Effect of chemical and physical structure on partitioning behavior of representative printing ink solvents and various food ingredients (식품 성분과 식품 포장용 인쇄 잉크 용매의 화학적 구조가 분배작용에 미치는 영향)

  • An, Duek-Jun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.10 no.1
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    • pp.7-14
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    • 2004
  • Migration behavior of selected solvents and food samples showed differences of the chemical structures and polarities, the food samples which have similar polar expresses more higher affinity than different polar degrees. Water which is polar has a highest partitioning coefficient values on polar isopropanol, and oil which is nonpolar has highest partitioning value on non-polar toluene. The increasing order of partitioning values was accord with increasing water contents in food samples. It is showed that the wheat flour with 13.2% moisture content has the highest partitioning coefficient values on the isopropanol with -OH. Kp value of sugar showed remarkable lower partitioning coefficient values than other food samples due to high degree crystallinity. This phenomenon can be predictable with ${\delta}$ values, because order of partitioning coefficient values which comes out through the experiment and the sequence of Hildebrand solubility parameter value difference between food sample and printing ink solvent correspond almost. This Hildebrand solubility parameter value can be easily applied to the food package industry because the effect of food-safety can be considered without passing through complicated steps by using this method.

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