• Title/Summary/Keyword: non-metal

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Design and Analysis of IPMC Actuator-driven ZNMF Pump for Air Flow Control of MAV's Wing (IPMC 작동기로 구동되는 초소형 비행체 날개의 공기흐름 조절용 ZNMF(zero-net-mass-flux) 펌프의 예비설계 및 해석)

  • Lee, Sang-Gi;Kim, Gwang-Jin;Park, Hun-Cheol
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.3
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    • pp.22-30
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    • 2006
  • In this paper, a systematic design method on an IPMC(ionic polymer-metal composite)-driven ZNMF(zero-net-mass-flux) pump is introduced for the flow control of an MAV's (micro air vehicle) wing. Since the IPMC is able to generate a large deformation under a low input voltage along with its ability to operate in air, and is easier to be manufactured in a small size, it is considered to be an ideal material of the actuating diaphragm. Through the numerical methods, an optimal shape of the IPMC diaphragm was found for maximizing the stroke volume. Based on the optimal IPMC diaphragm, a proto-type ZNMF pump with a slot, was designed. By using the flight speed of the MAV considered in this work, the driving frequencies(~ 40 Hz) of IPMC diaphragm, and the flow velocity through the pump's slot, the calculated non-dimensional frequency and the momentum coefficient ensure the feasibility of the designed ZNMF pump as a flow control device.

Preparation of WO3-TiO2 Photocatalyst and Evaluation of Its Photo-activity in the Visible Light Range (가시광 활성 WO3-TiO2 복합체 광촉매의 제조 및 이의 특성 평가)

  • Yeo, In-Chul;Kang, In-Cheol
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.474-478
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    • 2013
  • The most general photocatalyst, $TiO_2$ and $WO_3$, are acknowledged to be ineffective in range of visible light. Therefore, many efforts have been directed at improving their activity such as: band-gap narrowing with non-metal element doping and making composites with high specific surface area to effectively separate electrons and holes. In this paper, the method was introduced to prepare a photo-active catalyst to visible irradiation by making a mixture with $TiO_2$ and $WO_3$. In the $TiO_2-WO_3$ composite, $WO_3$ absorbs visible light creating excited electrons and holes while some of the excited electrons move to $TiO_2$ and the holes remain in $WO_3$. This charge separation reduces electron-hole recombination resulting in an enhancement of photocatalytic activity. Added Ag plays the role of electron acceptor, retarding the recombination rate of excited electrons and holes. In making a mixture of $TiO_2-WO_3$ composite, the mixing route affects the photocatalytic activity. The planetary ball-mill method is more effective than magnetic stirring route, owing to a more effective dispersion of aggregated powders. The volume ratio of $TiO_2(4)$ and $WO_3(6)$ shows the most effective photocatalytic activity in the range of visible light in the view point of effective separation of electrons and holes.

Volume Reduction of the Radioactive Solid Wastes in Hot Cell (핫셀 방사성 고체폐기물 감용)

  • 양송열;서항석;이형권;이은표;권형문;민덕기;김길수;조일제;전용범
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.109-116
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    • 2003
  • The amount of radioactive waste is expected to be increased continuously because of the rapid growth of the domestic nuclear industry, full power operation of the HANARO reactor and the increased research activities of the nuclear fuel cycle. Accordingly the efforts are focused to achieve the handling of radioactive waste in safe and reduce the volume of radioactive waste. The PIEF is carrying out the PIE (post irradiation examination) of spent fuel rods related to the identification of cause defect and evaluation of integration safety. This study describes the technologies and experiences of compaction, shredding and cutting of the solid radioactive waste used in the PIE. The quantity of the high level waste was reduced by 1/12 using the 100-ton compressor installed in hot-cell. Also middle and low level waste was reduced by 1/8 using the 60-ton compressor installed in intervention area. Plastic drums were shredded by crusher to be compacted in the ratio of 1/5, used filters in the ratio of 1/6 and the number of drum is also reduced by cutting procedure for the non-volatile materials such as metal.

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Determination of Transuranic Elements in Radwaste Samples from Nuclear Power Plant (원전발생 방사성폐기물 시료 중 초우란원소의 정량)

  • 조기수;김태현;전영신;지광용;김원호
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.351-357
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    • 2003
  • Transuranic elements such as Pu, Am and Cm in synthetic solution of spent nuclear fuel samples were determined by electrodeposition followed by alpha-spectrometry after separation using anion exchange and extraction chromatography in order to determine the transuranic elements in radwaste samples from nuclear power plants. Plutonium was separated by 12M HC1-0.1M HI as an eluent on anion exchange column. As a second step Am and Cm were separated in a group by DTPA-Lactic acid as the eluent on HDEHP coated column. The nuclides of $^{239}Pu$, $^{241}Am$$^{244}Cm$ separated were determined by alpha-spectrometry after electrodeposition in 0.1M $NaHSo_4$-0.53M $Na_2SO_4$buffer solution as an electrolyte. The recovery yields of $^{239}Pu$, $^{241}Am$$^{244}Cm$ were 83.8%, 85.2% and 86.3%, respectively, from the synthetic solution containing uranium and non-radioactive metal elements.

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Effect on the Growth of Chinese Cabbage and Chemical Composition of the Liquid Piggery Slurry Digested Anaerobically in Biogas Plant (바이오가스 프랜트에서 혐기 소화시킨 돈사 Slurry의 화학적 특성 및 배추생육 시용효과에 관한 연구)

  • Jeong, Chan-Seong;Bak, Jeong-Geun;Roh, Ahn-Sung;Cho, Woong-Gi;Lee, Sung-Sill;Moon, Yea-Hwang
    • Journal of Animal Environmental Science
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    • v.20 no.3
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    • pp.125-132
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    • 2014
  • This study was conducted to investigate the effects on chemical properties of soil and yield of chinese cabbage when the piggery liquid slurry (ADS) digested anaerobically in the biogas plant was sprinkled to the soils. Treatments were composed of non-nitrogen plot (PK), chemical fertilizer plot (NPK) and ADS plot, and were arranged by randomized block design with 3 replications. The ADS was an alkali (pH 8.6) fertilizer containing 0.55% of total nitrogen, optimal levels of phosphorus, potassium and other components. When based (100%) on the yield of chinese cabbage in the NPK, those of the ADS and the PK were 114% and 43%, respectively. The nitrogen absorption of chinese cabbage at 50-d after transplant was significantly greater (p<0.05) in the ADS than other treatment. Heavy metal contents of soil were not difference between before and after experiment. With supplementing phosphorus and potassium sources in it, the ADS should be an excellent fertilizer in cabbage culture.

Distributions of Organic Matter and Trace Metals in Sediment around a Tidal-flat Oyster Crassostrea gigas Farming Area on the Taean Peninsula, Korea (태안반도 갯벌 참굴(Crassostrea gigas) 양식장 주변 퇴적물의 유기물 및 미량금속 분포)

  • Hwang, Dong-Woon;Lee, In-Seok;Choi, Minkyu;Choi, Hee-Gu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.47 no.6
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    • pp.1014-1025
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    • 2014
  • We measured the concentrations of various geochemical parameters [grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and trace metals (Fe, Cu, Cd, Pb, Cr, Mn, As, Zn, and Hg)] in the surface sediments of two intertidal oyster Crassostrea gigas farming areas (Iwon and Mongsan tidal flats) on the Taean Peninsula, Korea, to evaluate the pollution level of organic matter and trace metals in sediment. The intertidal sediments in the study region comprise mostly sand with a mean grain size of 2.5-3.5 Ø. The concentrations of IL, COD, AVS, and trace metals in the sediment of two study regions were either similar or lower in oyster farming areas relative to non-farming areas, apparently due to biological uptake or physical and biological sediment reworking. Based on the results for the pollution evaluation of organic matter and trace metals derived from sediment quality guidelines, enrichment factor, and geoaccumulation index, our results suggest that the sediment in these two intertidal oyster farming regions is not polluted by organic matter and trace metals.

Formation of SiC Particle Reinforced Al Metal Matrix Composites by Spray Forming Process(I. Microstructure) (분사성형법에 의한 SiC입자강화 알루미늄 복합재료의 제조 I. 미세조직에 대한 고찰)

  • Park, Jong-Sung;Kim, Myung-Ho;Bae, Cha-Hurn
    • Journal of Korea Foundry Society
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    • v.13 no.4
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    • pp.369-381
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    • 1993
  • Aluminum alloy(AC8A) matrix composites reinforced with SiC particles(10% in vol.) were fabricated by Centrifugal Spray Deposition(CSD) process. The microstructures were investigated in order to evaluate both the mixing mode between aluminum matrix and SiC particles, and the effect of SiC particles on the cooling behaviours of droplets during flight and preforms deposited. A non-continuum mathematical calculation was performed to explain and to quantify the evolution of microstructures in the droplets and preforms deposited. Conclusions obtained are as follows; 1. The powders produced by CSD process showed, in general, ligament type, and more than 60% of the powders produced were about 300 to 850 um in size. 2. AC8A droplets solidified during flight showed fine dendritic structure, but AC8A droplets mixed with SiC particles showed fine equiaxed grain structure, and eutectic silicon were formed to crystallize granularly between fine aluminum grains. 3. SiC particles seem to act as a nucleation sites for pro-eutectic silicon during solidification of AC8A alloy. 4. The microstructure of composite powders formed by CSD process showed particle embedded type, and resulted in dispersed type microstructure in preforms deposited. 5. The pro-eutectic silicon crystallized granularly between fine aluminum grains seem to prohibit grains from growth during spray deposition process. 6. The interfacial reactions between aluminum matrix and SiC particles were not observed from the deposit performs and the solidified droplets. 7. The continuum model seem to be useful in connecting the processing parameters with the resultant microstructures. From these results, it was concluded that the fabrication of aluminum matrix composites reinforced homogeneously with SiC particles was possible.

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Three-dimensional accuracy of different correction methods for cast implant bars

  • Kwon, Ji-Yung;Kim, Chang-Whe;Lim, Young-Jun;Kwon, Ho-Beom;Kim, Myung-Joo
    • The Journal of Advanced Prosthodontics
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    • v.6 no.1
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    • pp.39-45
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    • 2014
  • PURPOSE. The aim of the present study was to evaluate the accuracy of three techniques for correction of cast implant bars. MATERIALS AND METHODS. Thirty cast implant bars were fabricated on a metal master model. All cast implant bars were sectioned at 5 mm from the left gold cylinder using a disk of 0.3 mm thickness, and then each group of ten specimens was corrected by gas-air torch soldering, laser welding, and additional casting technique. Three dimensional evaluation including horizontal, vertical, and twisting measurements was based on measurement and comparison of (1) gap distances of the right abutment replica-gold cylinder interface at buccal, distal, lingual side, (2) changes of bar length, and (3) axis angle changes of the right gold cylinders at the step of the post-correction measurements on the three groups with a contact and non-contact coordinate measuring machine. One-way analysis of variance (ANOVA) and paired t-test were performed at the significance level of 5%. RESULTS. Gap distances of the cast implant bars after correction procedure showed no statistically significant difference among groups. Changes in bar length between pre-casting and post-correction measurement were statistically significance among groups. Axis angle changes of the right gold cylinders were not statistically significance among groups. CONCLUSION. There was no statistical significance among three techniques in horizontal, vertical and axial errors. But, gas-air torch soldering technique showed the most consistent and accurate trend in the correction of implant bar error. However, Laser welding technique, showed a large mean and standard deviation in vertical and twisting measurement and might be technique-sensitive method.

Osteoblastic behavior to zirconium coating on Ti-6Al-4V alloy

  • Lee, Bo-Ah;Kim, Hae-Jin;Xuan, Yun-Ze;Park, Yeong-Joon;Chung, Hyun-Ju;Kim, Young-Joon
    • The Journal of Advanced Prosthodontics
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    • v.6 no.6
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    • pp.512-520
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    • 2014
  • PURPOSE. The purpose of this study was to assess the surface characteristics and the biocompatibility of zirconium (Zr) coating on Ti-6Al-4V alloy surface by radio frequency (RF) magnetron sputtering method. MATERIALS AND METHODS. The zirconium films were developed on Ti-6Al-4V discs using RF magnetron sputtering method. Surface profile, surface composition, surface roughness and surface energy were evaluated. Electrochemical test was performed to evaluate the corrosion behavior. Cell proliferation, alkaline phosphatase (ALP) activity and gene expression of mineralized matrix markers were measured. RESULTS. SEM and EDS analysis showed that zirconium deposition was performed successfully on Ti-6Al-4V alloy substrate. Ti-6Al-4V group and Zr-coating group showed no significant difference in surface roughness (P>.05). Surface energy was significantly higher in Zr-coating group than in Ti-6Al-4V group (P<.05). No difference in cell morphology was observed between Ti-6Al-4V group and Zr-coating group. Cell proliferation was higher in Zr-coating group than Ti-6Al-4V group at 1, 3 and 5 days (P<.05). Zr-coating group showed higher ALP activity level than Ti-6Al-4V group (P<.05). The mRNA expressions of bone sialoprotein (BSP) and osteocalcin (OCN) on Zr-coating group increased approximately 1.2-fold and 2.1-fold respectively, compared to that of Ti-6Al-4V group. CONCLUSION. These results suggest that zirconium coating on Ti-6Al-4V alloy could enhance the early osteoblast responses. This property could make non-toxic metal coatings on Ti-6Al-4V alloy suitable for orthopedic and dental implants.

Investigation of a Pseudo Capacitor with Polyacrylonitrile based Gel Polymer Electrolyte

  • Harankahawa, Neminda;Weerasinghe, Sandaranghe;Vidanapathirana, Kamal;Perera, Kumudu
    • Journal of Electrochemical Science and Technology
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    • v.8 no.2
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    • pp.107-114
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    • 2017
  • Pseudo capacitors belong to one group of super capacitors which are consisted with non carbon based electrodes. As such, conducting polymers and metal oxide materials have been employed for pseudo capacitors. Conducting polymer based pseudo capacitors have received a great attention due to their interesting features such as flexibility, low cost and ease of synthesis. Much work has been done using liquid electrolytes for those pseudo capacitors but has undergone various drawbacks. It has now been realized the use of solid polymer electrolytes as an alternative. Among them gel polymer electrolytes (GPEs) are in a key place due to their high ambient temperature conductivities as well as suitable mechanical properties. In this study, composition of a polyacrylonitrile (PAN) based GPE was optimized and it was employed as the electrolyte in a pseudo capacitor having polypyrrole (PPy) electrodes. GPE was prepared using ethylene carbonate (EC), propylene carbonate (PC), sodium thiocyanate (NaSCN) and PAN as starting materials. The maximum room temperature conductivity of the GPE was $1.92{\times}10^{-3}Scm^{-1}$ for the composition 202.5 PAN : 500 EC : 500 PC : 35 NaSCN (by weight). Performance of the pseudo capacitor was investigated using Cyclic Voltammetry technique, Electrochemical Impedance Spectroscopy (EIS) technique and Continuous Charge Discharge (GCD) test. The single electrode specific capacity (Cs) was found out to be 174.31 F/g using Cyclic Voltammetry technique at the scan rate of 10 mV/s and within the potential window -1.2 V to 1.2 V. The same value obtained using EIS was about 84 F/g. The discharge capacity ($C_d$) was 69.8 F/g. The capacity fade over 1000 cycles was rather a low value of 4%. The results proved the suitability of the pseudo capacitor for improving the performance further.