• Title/Summary/Keyword: non-metal

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Electrodeposition Characteristics of Corrosion Resistant Tantalum Coating Layer for Hydrogen Production Sulfide-Iodine Process (수소생산을 위한 Sulfide-Iodine 공정장치용 초내식 탄탈코팅층 전착특성)

  • Lee, Youngjun;Kim, Daeyoung;Han, Moonhee;Kang, Keangsoo;Bae, Gigwang;Lee, Jonghyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.6
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    • pp.573-580
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    • 2012
  • Corrosion resistance and basic physical properties of solid tantalum are not comparable to most of the structural metallic materials. The relative high cost and melting temperature of tantalum are obstacles to be widely applied to general engineering processes. Electrodeposition in molten salt enables compact and uniform tantalum coating. In this study, Ta was coated onto base metal (SUS316L) with different current densities (0.5, 5, $20mA/cm^2$) by using MSE (Molten Salt Electrodeposition). In this study, it showed that deposition efficiency and microstructure of Ta coating layer were strongly depended on current density. In the case of the current density of $5mA/cm^2$, densest microstructure was obtained. The current density above $5mA/cm^2$ caused non-uniform microstructure due to rapid deposition rate. Dense microstructure and intact coating layer contributed to significant corrosion resistance enhancement.

Cathodic Electrochemical Deposition of Highly Ordered Mesoporous Manganese Oxide for Supercapacitor Electrodes via Surfactant Templating

  • Lim, Dongwook;Park, Taesoon;Choi, Yeji;Oh, Euntaek;Shim, Snag Eun;Baeck, Sung-Hyeon
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.148-154
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    • 2020
  • Highly ordered mesoporous manganese oxide films were electrodeposited onto indium tin oxide coated (ITO) glass using sodium dodecyl sulfate (SDS) and ethylene glycol (EG) which were used as a templating agent and stabilizer for the formation of micelle, respectively. The manganese oxide films synthesized with surfactant templating exhibited a highly mesoporous structure with a long-range order, which was confirmed by SAXRD and TEM analysis. The unique porous structure offers a more favorable diffusion pathway for electrolyte transportation and excellent ionic conductivity. Among the synthesized samples, Mn2O3-SDS+EG exhibited the best electrochemical performance for a supercapacitor in the wide range of scan rate, which was attributed to the well-developed mesoporous structure. The Mn2O3 prepared with SDS and EG displayed an outstanding capacitance of 72.04 F g-1, which outperform non-porous Mn2O3 (32.13 F g-1) at a scan rate of 10 mV s-1.

Yonsei Evolutionary Population Synthesis for Old Stellar Systems

  • Chung, Chul
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.31.2-31.2
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    • 2012
  • We present the Yonsei Evolutionary Population Synthesis (YEPS) models for spectroscopic and photometric evolutions of simple and composite stellar populations. The models are based on the most up-to-date Yonsei-Yale stellar evolutionary tracks and BaSel 3.1 flux libraries, and provide integrated spectroscopic quantities of Lick/IDS system including high-order Balmer absorption-lines. Special care has been taken to incorporate the systematic variation of horizontal branch (HB) morphology as functions of metallicity, age, alpha-element mixture, and helium abundance of simple stellar populations. Our models for normal-helium stellar populations indicate that the realistic modeling of HB and alpha-element brings about 5 Gyr and 0.1 dex differences in age and metallicity estimations, respectively, compared to those without these effects. The HB effect does not depend on the specific choice of stellar libraries and alpha-element enhancements, and this effect is non-negligible even in the metal sensitive absorption indices, such as Mg2 and Mg b. Comparison of the models to observations reveals that the HB and alpha-element effects are critical in understanding otherwise inexplicable phenomena found in globular cluster systems in the Milky Way and nearby galaxies, including the observed bimodality of the line strengths of globular clusters in massive galaxies. In addition, we found that helium-enhanced stellar populations, which are the major sources of extreme HB stars, bring about increased FUV, NUV fluxes, and thus the model colors of those filters become extremely blue. Age dating based on the YEPS model with normal-helium stellar populations reveals that the evidence for 'downsizing' of elliptical galaxies is found not only in the local field but also in Coma cluster, and that the mean age of elliptical galaxies in Coma cluster is about 1.4 Gyr younger than the mean age of those in the local field. We also find that our models with helium-enhanced subpopulations can naturally reproduce the strong UV-upturns observed in giant elliptical galaxies assuming an age similar to that of old GCs in the Milky Way.

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Purification and Characterization of a Lectin from Arisaema tortuosum Schott Having in-vitro Anticancer Activity against Human Cancer Cell Lines

  • Dhuna, Vikram;Bains, Jagmohan Singh;Kamboj, Sukhdev Singh;Singh, Jatinder;Shanmugavel;Saxena, Ajit Kumar
    • BMB Reports
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    • v.38 no.5
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    • pp.526-532
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    • 2005
  • A lectin with in-vitro anticancer activity against established human cancer cell lines has been purified by affinity chromatography on asialofetuin-linked amino activated silica beads from the tubers of Arisaema tortuosum, popularly known as Himalayan Cobra lily, a monocot plant from the family Araceae. The bound Arisaema tortuosum lectin (ATL) was eluted with glycine-HCl buffer, pH 2.5. ATL was effectively inhibited by asialofetuin, a complex desialylated serum glycoprotein as well as by N-acetyl-D-lactosamine, a disaccharide. It gave a single band corresponding to a subunit molecular weight of 13.5 kDa in SDS-PAGE, pH 8.8 both under reducing and non reducing conditions. When subjected to gel-filtration on Biogel P-200, it was found to have a molecular weight of 54 kDa, suggesting a homotetramer structure, in which individual polypeptides are not bound to each other with disulfide bonds. ATL is a glycoprotein with 0.9% carbohydrate content, stable up to $55^{\circ}C$ and at pH 2 to 10. The lectin had no requirement for divalent metal ions i.e. $Ca^{2+}$ and $Mn^{2+}$ for its activity. However, as reported for other monocot lectins, ATL gave multiple bands in isoelectric focusing and Native PAGE, pH 8.3. The lectin was found to inhibit in vitro proliferation of human cancer cell lines HT29, SiHa and OVCAR-5.

Induction Heating Device for Dental Implant Removal (인공치아의 임플란트 탈착을 위한 유도가열장치 연구)

  • Lee, Sang-Myung;Seo, Young;Song, Chang-Woo;Lee, Seung-Yop
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.5
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    • pp.305-311
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    • 2016
  • Induction heating is the process in which an electrically conducting object (usually a metal) is heated by electromagnetic induction through heat generated in the object by eddy currents. The main advantage of an induction heating device is the generation of the heat inside the target object itself. Hence, non-contact and safe heating devices are widely used in many industrial and medical fields. Recently, a new dental implant system was developed using a shape-memory alloy, wherein an artificial tooth could be easily removed from the dental implant by heating. This paper discusses the development of an induction-heating device to remove the dental crown in the new implant system. First, the finite element simulation of electromagnetic and thermal coupling analysis was implemented to obtain the temperature distributions of the target object for various frequencies, input currents, and coil shapes. Based on the simulation results, experiments were conducted by using prototypes, and an induction heating device was developed to remove the dental crown from the implant.

Evaluation of Nutritional Characteristics of Different Sources of Food Residues in Autumn and Comparisons with NRC Nutrient Requirements for Swine (가을철 배출원별 남은 음식물의 사료 영양적 특성 및 돼지 영양소 요구량과의 비교 평가)

  • Kwak, W.S.;Kang, J.S.;Chung, J.D.
    • Journal of Animal Environmental Science
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    • v.8 no.2
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    • pp.87-98
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    • 2002
  • This study was conducted to determine nutritional values of different sources of food residues(FR) released in autumn and to compare them with nutrient requirements on NRC standard feeding system of swine. Hospital or cafeteria FR contained more cooked rice and side dishes residues and less vegetable residues and fruit peel, resulting in higher energy and lower fiber contents, compared to apartment complex FR, which had opposite patterns to these results. Chemical composition between hospital and cafeteria FR was almost similar. Salt(NaCl) content was more than 9 folds of NRC swine requirement, but much lower than the maximum tolerant level. Essenial and non-essential amino acids profile was similar among FR sources. Hospital or cafeteria FR protein had a similar pepsin digestibility to soybean meal protein. Apartment complex FR protein, however, had a much lower pepsin digestibility. When NRC nutrient requirements are considered, FR in swine diets could satisfy requirements of protein and all the essential amino acids, 75${\sim}$111% of digestible or metabolizable energy, and most of the major and minor minerals. All the FR contained extremely low levels of toxic heavy metals, indicating that they are completely safe from these toxic substances. It was concluded that hospital or cafeteria FR could be a nutritionally excellent and balanced feed source for swine.

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Aerodynamic and Structural Design for Medium Size Horizontal Axis Wind Turbine Rotor Blade with Composite Material (복합재를 이용한 수평축 풍력터빈 회전 날개의 공력 및 구조설계에 관한 연구)

  • 공창덕;방조혁;오동우;김기범;김학봉
    • Journal of the Korean Society of Propulsion Engineers
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    • v.1 no.2
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    • pp.12-21
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    • 1997
  • Nowadays, non-pollution energy sources have been strongly needed because of the exhaustion of fossil fuels and serious environmental problems. Because wind energy can be enormously obtained from natural atmosphere, this type of energy has lots of advantages in a economic and pollution point of view. This study has established the aerodynamic and structural design procedure of the rotor blade with an appropriate aerodynamic performance and structural strength for the 500㎾ medium class wind turbine system. The aerodynamic configuration of the rotor blade was determined by considering the wind condition in the typical local operation region, and based on this configuration aerodynamic performance analysis was performed. The rotor blade has the shell-spar structure based on glass/epoxy composite material and is composed of shank including metal joint parts and blade. Structural design was done by the developed design program in this study and structural analysis, for instance stress analysis, mode analysis and fatigue life estimation, was performed by the finite element method. As a result, a medium scale wind turbine rotor blade with starting characteristics of 4m/s wind speed, rated power of 500㎾ at 12m/s wind speed and over 20 years fatigue life has been designed.

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Physical Test and Finite Element Analysis of Elastomer for Steel Rack Tube Forming (일체형 랙 튜브 성형을 위한 고 탄성체 물성시험과 유한요소 해석)

  • Woo, C.S.;Park, H.S.;Lee, G.A.
    • Elastomers and Composites
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    • v.43 no.3
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    • pp.173-182
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    • 2008
  • Rubber-pad forming process for materials such as metal in which portions of the die which act upon the material is composed of a natural or synthetic rubber or elastomer material. This makes the rubber pad forming process relatively cheap and flexible, high accuracy for small product series in particular. In this study, we carried out the physical test and finite element analysis of elastomer such as natural rubber and urethane for steel rack rube forming. The non-linear property of elastomer which are described as strain energy function are important parameter to design and evaluate of elastomer component. These are determined by material tests which are uni-axial tension and bi-axial tension. This study is concerned with simulation and investigation of the significant parameters associated with this process.

Electromagnetic Survey in Korea (한국의 전자탐사 현황)

  • Cho, Dong-Heng
    • Economic and Environmental Geology
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    • v.39 no.4 s.179
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    • pp.427-440
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    • 2006
  • Electromagnetic(EM) survey has been in use for over a half century as a standard routine for, mineral exploration in many parts of the world. But EM survey work and serious research effort were initiated in Korea only as late as in early 1980s, largely inspired by four pioneers who did their graduate studies in the U.S.A. in 1970s. Nevertheless domestic achievements in the field of EM survey are remarkable in the last two decades: the field operations and related interpretational skills appear to have reached a global standard, even compared with the most advanced in other countries, virtually in a whole spectrum of the method which includes magneto-tellurics(MT), Controlled Source Audio-frequency Magneto-tellurics(CSAMT), geomagnetic sounding, small loop survey systems, Very Low Frequency(VLF), Ground Penetrating Radar(GPR), time domain surveys, and noise analysis. Besides mineral exploration, EM survey has been applied in Korea to hydrogeology, geotechnical engineering, non-destructive investigation of structures, unexplored ordnance(UXO) investigation, environmental monitoring, and archaeological investigation as well. Now that original contributions of several Korean geophysicists are found even in new frontiers such as high-frequency EM survey, investigation in time-domain EM field for buried metal objects and structures, and also modem data inversion scheme, it is duly hoped that they make some technical breakthrough to unravel still entangled knots of EM survey method in a forseeable future.

A Study on the Reactivity, Performance of 4HBA Modified High Solid Acrylic Polyurethane Paint (4HBA 변성 하이솔리드 아크릴 우레탄 도료의 반응성 및 물성 연구)

  • Seo, Seok-Hwan;Suh, Cha-Soo;Park, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.52-61
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    • 2009
  • In this study, TAPEH (t-amyl peroxy 2-ethyl hexanoate) was selected for the reaction initiator which is a core factor for developing acrylic polyol binder. Tone M100 (caprolactone acrylate), 4HBA (4-hydroxy butyl acrylate), and 2HEMA (2-hydroxy ethyl methacrylate) were used for hydroxy-monomers. To check the applicability of raw materials mentioned above into the binders of 2 components acrylic polyurethane paint and reduce the VOC, the reactivity and film performance by different kinds of aliphatic polyisocyanate hardeners which are already generalized were reviewed. As the Tin-based catalyst has been regulated, the comparison test of reactivity and performance between the conventional catalyst and non-toxic metal catalyst recommended as the alternative was conducted as well. As a result, we were able to obtain the basic data which are necessary for applying 2 components high solid polyurethane paint and also reached a conclusion that it can be applied for developing new paints in terms of high performance, workability and environmental care.