• Title/Summary/Keyword: non-linear calibration

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Application of Near Infrared Spectroscopy for Nondestructive Evaluation of Nitrogen Content in Ginseng

  • Lin, Gou-lin;Sohn, Mi-Ryeong;Kim, Eun-Ok;Kwon, Young-Kil;Cho, Rae-Kwang
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1528-1528
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    • 2001
  • Ginseng cultivated in different country or growing condition has generally different components such as saponin and protein, and it relates to efficacy and action. Protein content assumes by nitrogen content in ginseng radix. Nitrogen content could be determined by chemical analysis such as kjeldahl or extraction methods. However, these methods require long analysis time and result environmental pollution and sample damage. In this work we investigated possibility of non-destructive determination of nitrogen content in ginseng radix using near-infrared spectroscopy. Ginseng radix, root of Panax ginseng C. A. Meyer, was studied. Total 120 samples were used in this study and it was consisted of 6 sample sets, 4, 5 and 6-year-old Korea ginseng and 7, 8 and 9-year-old China ginseng, respectively. Each sample set has 20 sample. Nigrogen content was measured by electronic analysis. NIR reflectance spectra were collected over the 1100 to 2500 nm spectral region with a InfraAlyzer 500C (Bran+Luebbe, Germany) equipped with a halogen lapmp and PbS detector and data were collected every 2 nm data point intervals. The calibration models were carried out by multiple linear regression (MLR) and partial least squares (PLS) analysis using IDAS and SESAME software. Result of electronic analysis, Korean ginseng were different mean value in nitrogen content of China ginseng. Ginseng tend to generally decrease the nitrogen content according as cultivation year is over 6 years. The MLR calibration model with 8 wavelengths using IDAS software accurately predicted nitrogen contents with correlation coefficient (R) and standard error of prediction of 0.985 and 0.855%, respectively. In case of SESAME software, the MLR calibration with 9 wavelength was selected the best calibration, R and SEP were 0.972 and 0.596%, respectively. The PLSR calibration model result in 0.969 of R and 0.630 of RMSEP. This study shows the NIR spectroscopy could be applied to determine the nitrogen content in ginseng radix with high accuracy.

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Development of an Automated Diffusion Scrubber-Conductometry System for Measuring Atmospheric Ammonia

  • Lee, Bo-Kyoung;Lee, Chong-Keun;Lee, Dong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.2039-2044
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    • 2011
  • A semi-continuous and automated method for quantifying atmospheric ammonia at the parts per billion level has been developed. The instrument consists of a high efficiency diffusion scrubber, an electrolytic on-line anion exchange device, and a conductivity detector. Water soluble gases in sampled air diffuse through the porous membrane and are absorbed in an absorbing solution. Interferences are eliminated by using an anion exchange devises. The electrical conductivity of the solution is measured without chromatographic separation. The collection efficiency was over 99%. Over the 0-200 ppbv concentration range, the calibration was linear with $r^2$ = 0.99. The lower limit of detection was 0.09 ppbv. A parallel analysis of Seoul air over several days using this method and a diffusion scrubber coupled to an ion chromatography system showed acceptable agreement, $r^2$ = 0.940 (n = 686). This method can be applied for ambient air monitoring of ammonia.

Monitoring the Welding Gap/Profile with Visual Sensor (시각센서를 이용한 용접 Gap/Profile 모니터링)

  • Kim, Chang-Hyeon;Choe, Tae-Yong;Lee, Ju-Jang;Seo, Jeong;Park, Gyeong-Taek;Gang, Hui-Sin
    • Proceedings of the Korean Society of Laser Processing Conference
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    • 2005.06a
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    • pp.3-8
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    • 2005
  • The robot systems are widely used in the welding manufacturing. The essential tasks to operate the welding robot are the acquisition of the position and/or shape of the parent metal. For the seam tracking or the robot automation, many kinds of contact and non-contact of the system which monitors the shape of the welding part is described. This system uses the line-type structured laser diode and the visual sensor. It includes the correction of radial distortion which is often found in the image from the camera with short focal length. Direct Linear Transformation (DLT) is used for the camera calibration. The three dimensional shape of the parent metal is obtained after simple linear transformation. Therefore, the system operates in real time. Some experiments are carried out to evaluate the performance of the developed system.

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Finite element simulation of traditional and earthquake resistant brick masonry building under shock loading

  • Daniel, A. Joshua;Dubey, R.N.
    • Coupled systems mechanics
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    • v.4 no.1
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    • pp.19-36
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    • 2015
  • Modelling and analysis of a brick masonry building involves uncertainties like modelling assumptions and properties of local material. Therefore, it is necessary to perform a calibration to evaluate the dynamic properties of the structure. The response of the finite element model is improved by predicting the parameter by performing linear dynamic analysis on experimental data by comparing the acceleration. Further, a nonlinear dynamic analysis was also performed comparing the roof acceleration and damage pattern of the structure obtained analytically with the test findings. The roof accelerations obtained analytically were in good agreement with experimental roof accelerations. The damage patterns observed analytically after every shock were almost similar to that of experimental observations. Damage pattern with amplification in roof acceleration exhibit the potentiality of earthquake resistant measures in brick masonry models.

Near Infrared Reflectance Spectroscopy for Non-Invasive Measuring of Internal Quality of Apple Fruit

  • Sohn, Mi-Ryeong;Park, Woo-Churl;Cho, Rae-Kwang
    • Near Infrared Analysis
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    • v.1 no.1
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    • pp.27-30
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    • 2000
  • In this study, we investigated the feasibility of non-destructive determination of internal quality factors of Fuji apple fruit using near infrared(NIR) reflectance spectroscopy and developed the calibration models. As the reference methods, refractometer, titration and texture analyzer for sugar content, acidity and firmness were used, respectively. Samples were scanned from 1100∼2500nm with InfraAlyzer 500C spectrometer and SESAME software was used for data analysis. A multiple linear regression(MLR) analysis was performed to develop the calibrations. The correlation coefficient(R) and standard error of prediction(SEP) were as follows; 0.91, 0.41$^{\circ}$Brix for sugar content, 0.90, 0.04% for acidity and 0.84, 0.094 kg for firmness, respectively. This study shows that NIR spectroscopy can be used to evaluate the sugar content acidity and firmness of apple fruit with acceptable accuracy.

SiC filament Pyrometry in Near Extinction Diffusion Flame (SiC 필라멘트를 이용한 소염 직전의 확산화염 온도 계측)

  • Shim, Sung-Hoon;Shin, Hyun-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.11
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    • pp.1481-1487
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    • 2002
  • The thin SiC filament technique has been employed to identify the possibility of measuring flame temperature, and especially unstable near-extinction flame temperature in an oxidizer deficient ambience, by comparing the relative visible (non-IR) luminosities of SiC filaments with thermocouple measured temperature in co-flowing, laminar propane/air diffusion flames. The results show good agreement between the digitized relative visible luminosity profiles of the SiC filaments and temperature profiles measured using a thermocouple at temperatures above $700^{\circ}C$, although, a non-linear calibration is probably required far the whole temperature range. The highest radial peak temperature exists near to the nozzle exit. and the centerline temperatures were virtually unchanged with increasing flame height in an oxidizer deficient near-extinction flame.

A Non-contact Shape Measuring System Using an Artificial Neural Network

  • Jeong, Woo-tae;Lee, Myung-Chan;Koh, Duck-joon;Cho, Hyung-suck
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05a
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    • pp.399-404
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    • 1996
  • We developed a non-contact shape measuring device using computer image processing technology. We present a method of calibrating a CCD video camera and a laser range finder which is the most important step toward making an accurate shape measuring system. An artificial neural network is used for the calibration. Our measurement system is composed of a semiconductor laser. a CCD video camera, a personal computer, and a linear motion table. We think that the developed system could be used for measuring the change in shape of the spent nuclear fuel rod before and after irradiation which is one of the most important tasks for developing a better nuclear fuel. A radiation shield is suggested for the possible utilization of the range finder in radioactive environment.

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CHALLENGING APPLICATIONS FOR FT-NIR SPECTROSCOPY

  • Goode, Jon G.;Londhe, Sameer;Dejesus, Steve;Wang, Qian
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.4112-4112
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    • 2001
  • The feasibility of NIR spectroscopy as a quick and nondestructive method for quality control of uniformity of coating thickness of pharmaceutical tablets was investigated. Near infrared spectra of a set of pharmaceutical tablets with varying coating thickness were measured with a diffuse reflectance fiber optic probe connected to a Broker IFS 28/N FT-NIR spectrometer. The challenging issues encountered in this study included: 1. The similarity of the formulation of the core and coating materials, 2. The lack of sufficient calibration samples and 3. The non-linear relationship between the NIR spectral intensity and coating: thickness. A peak at 7184 $cm^{-1}$ was identified that differed for the coating material and the core material when M spectra were collected at 2 $cm^{-1}$ resolution (0.4 nm at 7184 $cm^{-1}$). The study showed that the coating thickness can be analyzed by polynomial fitting of the peak area of the selected peak, while least squares calibration of the same data failed due to the lack of availability of sufficient calibration samples. Samples of coal powder and solid pieces of coal were analyzed by FT-NIR diffuse reflectance spectroscopy with the goal of predicting their ash content, percentage of volatile components, and energy content. The measurements were performed on a Broker Vector 22N spectrometer with a fiber optic probe. A partial least squares model was constructed for each of the parameters of interest for solid and powdered sample forms separately. Calibration models varied in size from 4 to 10 PLS ranks. Correlation coefficients for these models ranged from 86.6 to 95.0%, with root-mean-square errors of cross validation comparable to the corresponding reference measurement methods. The use of FT-NIR diffuse reflectance measurement techniques was found to be a significant improvement over existing measurement methodologies in terms of speed and ease of use, while maintaining the desired accuracy for all parameters and sample forms.(Figure Omitted).

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Camera Motion and Structure Recovery Using Two-step Sampling (2단계 샘플링을 이용한 카메라 움직임 및 장면 구조 복원)

  • 서정국;조청운;홍현기
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.40 no.5
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    • pp.347-356
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    • 2003
  • Camera pose and scene geometry estimation from video sequences is widely used in various areas such as image composition. Structure and motion recovery based on the auto calibration algorithm can insert synthetic 3D objects in real but un modeled scenes and create their views from the camera positions. However, most previous methods require bundle adjustment or non linear minimization process [or more precise results. This paper presents a new auto' calibration algorithm for video sequence based on two steps: the one is key frame selection, and the other removes the key frame with inaccurate camera matrix based on an absolute quadric estimation by LMedS. In the experimental results, we have demonstrated that the proposed method can achieve a precise camera pose estimation and scene geometry recovery without bundle adjustment. In addition, virtual objects have been inserted in the real images by using the camera trajectories.

Parameter Calibration of Storage Function Model and Flood Forecasting (1) Calibration Methods and Evaluation of Simulated Flood Hydrograph (저류함수모형의 매개변수 보정과 홍수예측 (1) 보정 방법론과 모의 홍수수문곡선의 평가)

  • Song, Jae Hyun;Kim, Hung Soo;Hong, Il Pyo;Kim, Sang Ug
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.1B
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    • pp.27-38
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    • 2006
  • The storage function model (SFM) has been used for the flood forecasting in Korea. The SFM has a simple calculation process and it is known that the model is more reasonable than linear model because it considers non-linearity of flood runoff. However, the determination of parameters is very difficult. In general, the trial and error method which is an manual calibration by the decision of a model manager. This study calibrated the parameters by the trial and error method and optimization technique. The calibrated parameters were compared with the representative parameters which are used in the Flood Control Centers in Korea. Also, the evaluation indexes on objective functions and calibration methods for the comparative analysis of simulation efficiency. As a result, the Genetic Algorithm showed the smallest variation in objective functions and, in this study, it is known that the objective function of SSR (Sum of Squared of Residual) is the best one for the flood forecasting.