• 제목/요약/키워드: non-halogen

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Manufacture of Environmentally-friendly Flame-retardant Paper with Polyethylene Terephthalate (PET) Short Cut Fiber (PET 섬유를 사용한 친환경 난연지 제조방법에 대한 연구)

  • Kim, Ji-Seop;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.14-20
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    • 2012
  • In this paper, the flame-retardant wall paper was successfully prepared with recycled polyethylene terephthalate (PET) short cut fiber with flame-retardant property and wood pulp using polyvinyl alcohol (PVA) as binder followed by treatment of non-halogen flame retardant. Physical properties such as formation index, tensile strength, elongation, and burst strength increased as defibrillation increased except tear strength. Bulk increased but formation index, tensile strength, elongation and burst strength decreased along with addition of PET short cut fiber. It was also found that tear strength rose significantly up to 30% of PET short cut fiber and then declined (fell) rapidly. As addition level of PVA increased tensile strength, elongation and burst strength increased, but tear strength decreased slightly. Addition of 20% of PET short cut fiber and 13% of PVA provided the flame-retardant wall paper with both improved flameproofing and physical properties.

Influence of light intensity and photo-bioreactor design for photo biological hydrogen production by Rhodobactor sphaeroides (Rhodobactor sphaeroides의 수소생산에 미치는 광세기 및 광합성 배양기 영향)

  • Kim, Mi-Sun;Baek, Jin-Sook
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.2
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    • pp.166-174
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    • 2004
  • Purple non-sulfur bacteria, Rhodobacter sphaeroides KD131 grew to reach the maximum cell concentration in 45 hrs of incubation in the synthetic media containing (NH4)2SO4, L-aspartic acid and succinic acid as the carbon and nitrogen sources, respectively, at 30oC under 8 klux irradiance using halogen lamp. The strain produced hydrogen from the middle of the logarithmic growth phase and continued until the cell growth leveled out. The strain grew and produced hydrogen under the irradiance of 3-30 klux, but cell growth was inhibited over 100 klux. In addition, anaerobic/light culture condition was better than the aerobic/dark on the hydrogen production. Among various photo-bioreactors examined, the flat-vertical reactor manufactured using clear acrylic plastic material showed the best hydrogen production rate at the given culture condition.

Design on illumination of structures for lighthouse in Korea

  • Han, Ju-Seop;Yu, Yong-Su;Kim, Jong-Uk
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.10
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    • pp.1327-1332
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    • 2014
  • This paper presents information about the examples of the design on Illumination of Structures(LED Light Pipe for lighthouse) in Korea. We have applied illumination by flood-lighting or facade-lighting in place of the 57 lighthouses (offshore structures) and 4 beacons. The ways of illumination of structures are using direct illumination with LED, halogen lamps and metal halide lamps, and indirect illumination with LED non-neon lamps. The illumination of structures helps a observer to identify the Aids to Navigation and w aterway. The fabricated LED Light Pipe is a transparent acrylic round bar and easy to install. The Light Pipe is arranged in two rows of L ED (78ea). It can be connected in series. It has 4 colours(Red, Green, Yellow, White). We analyzed and the horizontal divergence angle of the LED light pipe is defined as the range with 50% of maximum luminous intensity. Also, we evaluated the conspicuity on the origin al lantern and LED Light pipe for lighthouse. The field experiment was conducted in 'Yeosuguhang lighthouse' in Yeosu-city (Korea). F rom the experimental results, it was confirmed that the fabricated LED Light Pipe is clearly distinguished.

Characterization of a Membrane Interface for Analysis of Air Samples Using Time-of-flight Mass Spectrometry

  • Jang, Yu-Mi;Oh, Jun-Sik;Park, Chang-Joon;Yang, Sang-Sik;Jung, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2791-2796
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    • 2010
  • In the present study, we constructed a membrane inlet assembly for selective permeation of volatile airborne organic compounds for subsequent analysis by time-of-flight mass spectrometry. The time-dependent diffusion of analytes through a $75\;{\mu}m$ thick polydimethylsiloxane membrane was measured by monitoring the ion signal after a step change in the sample concentration. The results fit well to a non-steady-state permeation equation. The diffusion coefficient, response time, and sensitivity were determined experimentally for a range of polar (halogenated) and nonpolar (aromatic) compounds. We found that the response times for several volatile organic compounds were greatly influenced by the alkyl chain length as well as the size of the substituted halogen atoms. The detection limits for benzene, ethylbenzene, and 2-propanol were 0.2 ppm, 0.1 ppm, and 3.0 ppm by volume, respectively, with a linear dynamic range greater than three orders of magnitude. These results indicate that the membrane inlet/time-of-flight mass spectrometry technique will be useful for a wide range of applications, particularly for in situ environmental monitoring.

Optimization of Various Organic Acids on Photo-Fermentative Hydrogen Production using Rhodobacter sphaeroides KD131 (Rhodobacter sphaeroides KD131에 의한 유기산 광합성 발효 최적화)

  • Son, Han-Na;Kim, Mi-Sun
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.2
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    • pp.136-142
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    • 2010
  • Photobiological $H_2$ production was compared using purple non-sulfur bacteria Rhodobacter sphaeroides KD131 in the medium containing various organic acids as the carbon source and electron doner under illumination of $110\;W/m^2$ using halogen lamp at $30^{\circ}C$. The organic acids used were 0~120 mM acetate, butyrate, lactate and malate. Initial pH 7.0 and cell concentration 1.0 at 660nm were increased to pH 8 and 4.4~5.1, respectively during 24hrs of photo-fermentation when lactate and malate were used. However, acetate and butyrate increased pH to 9 and cell concentration to 3.2~3.9 of malate at the same experimental conditions. Optimum ranges of organic acids concentration and carbon/nitrogen ratio were 30~60 mM and 10~20, respectively. When malate was used as the substrate, maximum $H_2$ production 1.1 ml $H_2$/ml broth, which is equivalent to 1.97 mol $H_2$/mol malate was observed.

Optical Properties of Metal Halide Perovskite Nanocrystals with Addition of Metal Bromide (금속 브롬화물의 첨가에 따른 금속 할라이드 페로브스카이트 나노결정의 광학적 특성 변화)

  • Yun, Seokjin;Choi, Jihoon
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.334-341
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    • 2019
  • Organometal halide perovskite materials have attracted much attention in the photovoltaic and light emitting devices due to the compositional flexibility with AMX3 formula (A is an organic amine cation; M is a metal ion; X is a halogen atom). The addition of homovalent or heterovalent metal cations to the bulk organohalide perovskites has been performed to modify their energy band structure and the relevant optoelectronic properties by ligand-assisted ball milling. Here, we report CH3NH3Pb1-xMxBr3 nanocrystals substituted by metallic cations (M is Sn2+, In3+, Bi3+; x = 0, 0.01, 0.02, 0.05, 0.1, 0.2). Photoluminescence and quantum yield was significantly reduced with increasing metallic cations content. These quenching effect could be resulted from the metal cations that behave as a non-radiative recombination center.

Synthesis and Flame Retardant Characteristics of Melamine Cyanurate Treated with Silane Agent (실란이 처리된 멜라민 시아누레이트의 합성과 난연특성)

  • Park, Tae-Hun;Kang, Kuk-Hyoun;Lee, Jin-Hwa;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.300-309
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    • 2010
  • Melamincyanurate(MC), as an non halogen flame retardant are used as the polymer and plastic materials. In this study, melamine and cyanuric acid were used for the synthesis of MC. The optimum condition of synthetic MC were controlled by different molar ratio of melamine to cyanuric acid. MC was modified by coupling reaction with four different agents. The influences of modified MC were based on the coupling agent types. Preparation methods are available to offer the prospect of improved morphology control deposit stability in polyol. The results reveal that glycidoxypropyltrimethoxysilane(GDS) has the best storage stability. The best properties were obtained with melamine and cyanuric acid from 1:1 molar ratio. Modification of MC through coupling agent can efficiently enhanced the deposit stability in polyol up to 30 %.

Thermography-based coating thickness estimation for steel structures using model-agnostic meta-learning

  • Jun Lee;Soonkyu Hwang;Kiyoung Kim;Hoon Sohn
    • Smart Structures and Systems
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    • v.32 no.2
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    • pp.123-133
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    • 2023
  • This paper proposes a thermography-based coating thickness estimation method for steel structures using model-agnostic meta-learning. In the proposed method, a halogen lamp generates heat energy on the coating surface of a steel structure, and the resulting heat responses are measured using an infrared (IR) camera. The measured heat responses are then analyzed using model-agnostic meta-learning to estimate the coating thickness, which is visualized throughout the inspection surface of the steel structure. Current coating thickness estimation methods rely on point measurement and their inspection area is limited to a single point, whereas the proposed method can inspect a larger area with higher accuracy. In contrast to previous ANN-based methods, which require a large amount of data for training and validation, the proposed method can estimate the coating thickness using only 10- pixel points for each material. In addition, the proposed model has broader applicability than previous methods, allowing it to be applied to various materials after meta-training. The performance of the proposed method was validated using laboratory-scale and field tests with different coating materials; the results demonstrated that the error of the proposed method was less than 5% when estimating coating thicknesses ranging from 40 to 500 ㎛.

Adsorption of MX (3-chloro-4 (dichloromethyl)-5-hydroxy-2-(5H)-furanone) on amphiphilic mesoporous silica in aqueous solution (양쪽성 메조 포러스 실리카에 의한 수용액 속의 MX의 흡착)

  • Yoo, Eun-Ah;Chung, Kang-Sup
    • Analytical Science and Technology
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    • v.24 no.2
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    • pp.94-104
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    • 2011
  • Mesoporous silica was synthesized in a water solvent and in an ethanol solvent with the non and cationic cetyltrimethyl ammonium chloride (CTAC) by varying the amount of the amphiphilic acrylic urethane oligomer (AAU) and the pH of the solution. The adsorption of the MX (3-chloro-4 (dichloromethyl)-5-hydroxy-2-(5H)-furanone) in drinking water was studied using the synthesized mesoporous silica as an adsorbent. The most appropriate silica was synthesized in acidic conditions in the water solvent and in alkali conditions in the ethanol solvent. The average pore sizes of the synthesized mesosilica were 3 nm and more. The mesoporous silica synthesized by the addition of the AAU oligomer showed excellent adsorption characteristics. With respect to the co-surfactant, the best adsorption characteristics were obtained when the P64,a non-ionic surfactant with a high molecular weight, was used to synthesize the silica than when other co-surfactants were used. The adsorption rate decreased as the MX concentration in the water increased. Different adsorption equilibrium conditions were reached depending on the adsorbate MX concentration in the adsorbent and the solution. It was seen that perfect adsorption does not occur due to such equilibrium conditions.

Fast Defect Detection of PCB using Ultrasound Thermography (초음파 서모그라피를 이용한 빠른 PCB 결함 검출)

  • Cho Jai-Wan;Seo Yong-Chil;Jung Seung-Ho;Kim Seungho;Jung Hyun-Kyu
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.55 no.2
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    • pp.68-71
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    • 2006
  • Active thermography has been used for several years in the field of remote non-destructive testing. It provides thermal images for remote detection and imaging of damages. Also, it is based on propagation and reflection of thermal waves which are launched from the surface into the inspected component by absorption of modulated radiation. For energy deposition, it use external heat sources (e.g., halogen lamp or convective heating) or internal heat generation (e.g., microwaves, eddy current, or elastic wave). Among the external heat sources, the ultrasound is generally used for energy deposition because of defect selective heating up. The heat source generating a thermal wave is provided by the defect itself due to the attenuation of amplitude modulated ultrasound. A defect causes locally enhanced losses and consequently selective heating up. Therefore amplitude modulation of the injected ultrasonic wave turns a defect into a thermal wave transmitter whose signal is detected at the surface by thermal infrared camera. This way ultrasound thermography(UT) allows for selective defect detection which enhances the probability of defect detection in the presence of complicated intact structures. In this paper the applicability of UT for fast defect detection is described. Examples are presented showing the detection of defects in PCB material. Measurements are performed on various kinds of typical defects in PCB materials (both Cu metal and non-metal epoxy). The obtained thermal image reveals area of defect in row of thick epoxy material and PCB.