• Journal of the Korean Electrochemical Society
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• v.12 no.3
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• pp.203-218
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• 2009

The development of lithium-ion battery (LIB) technologies and their application in the field of large-scale power sources, such as electric vehicles (EVs), hybrid EVs, and plug-in EVs require enhanced reliability and superior safety. The main components of LIBs should withstand to the inevitable heating of batteries during high current flow. Carbonate solvents that contribute to the dissociation of lithium salts are volatile and potentially combustible and can lead to the thermal runaway of batteries at any abuse conditions. Recently, an interest in nonflammable materials is greatly growing as a means for improving battery safety. In this review paper, novel approaches are described for designing highly safe electrolytes in detail. Non-flammability of liquid electrolytes and battery safety can be achieved by replacing flammable organic solvents with thermally resistive materials such as flame-retardants, fluorinated organic solvents, and ionic liquids.

• Journal of the Society of Disaster Information
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• v.12 no.3
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• pp.286-291
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• 2016

In this study, we conducted about the manufacture of a non-combustible inorganic insulation by replacing the binder type for satisfaction of thermal conductivity for developing a lightweight inorganic insulation. Thermal conductivity was measured using a machine of HFM-436. We made samples are inorganic insulation by using SH-1(liquid) of S company and SH-2(solids). By Mixing Pearlite and SH-4(Liquid) was produced as insulation sample 2. Each was shaped into a binder and pearlite in the frame. After complete drying, thermal conductivity was measured by using HFM-435. The thermal conductivity was determined using two different binder. We analyzed the effect on thermal conductivity in binder.

• Journal of the Korean Society for Marine Environment & Energy
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• v.4 no.2
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• pp.43-51
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• 2001

Now our ocean environment pollution is very serious. Its harm hinders in marine breeding and the safe navigation of ships at the coast. We have used an assembly system for a measure taken against environment pollution like this. But, here are some problems awaiting solution. First, most of combustible materials among ocean waste are high polymer, so it is necessary some special equipment to incinerate them. In the process we can't overlook air pollution by exhaust gas. Also, when we reclaim these wastes, we remember that they can't be decomposed naturally and leaking water may pollute soil. Thus now a days new treatment method has been developed, it recycles and doesn't product secondary pollution materials by recovering oil from pyrolysis. For it, this study investigated chemicalㆍphysical properties of wastes. And it found condition of recovering the most oil. Also it probed that the variation of temperature raising speed affects the weight reduction characteristics of wastes. Also, while studying recovered oil by waste pyrolysis and the rate of non-condensing gas in accordance with the variation of temperature raising speed. Finally we had confidence the development of pyrolysis oil recovery would succeed because we carried out evaluation at an economic point of view about it.

• Journal of the Society of Disaster Information
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• v.15 no.4
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• pp.634-647
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• 2019

Purpose: Currently, many chemicals are used in industrial and real life, and many substances are used in the form of a single substance, but most of them are used in the form of a mixture, and there is a need for a criterion for judging the danger of these substances. Method: Therefore, this study aims to confirm the risk criteria of the mixture through experimental studies on flammable mixtures in order to secure the effectiveness of the details of the existing Dangerous Goods Safety Management Act angerous Goods Judgment Criteria and to ensure the reliability and reproducibility of the dangerous goods judgment. Result: Experimental results show that alcohol flash point is mixed with water, which is a non-flammable liquid. Similar flash point trends occurred around 60% on an alcohol basis. In addition, in the case of flammable-combustible mixtures, there was little change in flash point if the flash point difference of the two materials was not large, and if the flash point difference of the two materials was low, the flash point tended to increase with the increase of the high flash point material. Conclusion: In the future, the test results may provide reference data on the experimental criteria for the flammable liquids that are cracked at the fire site.

• Journal of the Society of Disaster Information
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• v.18 no.1
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• pp.182-193
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• 2022

Purpose: By measuring and evaluating the risk of biodiesel through non-volatile residue (NVR) and flash point and explosion limit measurement at a specific temperature according to ASTM test standards, the risk of chemical fire causative substances is identified and a universal evaluation method By derivation and securing the risk-related data of the material, it can be used for the identification and analysis of the cause of the fire, and it can be applied to the risk assessment of other chemical substances Method: In order to measure the risk of biodiesel, it was measured using the non-volatile residue(NVR) measurement method, which measures how much flammable liquid is generated at a specific temperature. Heating was tested by applying KS M 5000: 2009 Test Method 4111. In addition, the flash point was measured using the method specified in ASTM E659-782005, and the energy supply method was measured using the constant temperature method. In addition, the explosion limit measurement was conducted in accordance with ASTM E 681-04 「Standard test method for concentration limits of flammability of chemicals(Vapors and gases)」 test standard. Result: As a result of checking the amount of combustible liquid by the non-volatile residue (NVR)measurement method, the non-volatile residue(NVR) of general diesel when left at 105±2℃ for 3 hours was about 30% (70% of volatile matter) and about 4% of biodiesel. In addition, similar results were obtained for the non-volatile residue(NVR)heating temperature of 150±2℃, 3 hours and 200±2℃ for 1 hour, and white smoke was generated at 200℃ or higher. In addition, similar values were obtained as a result of experimentally checking the explosion (combustion) limits of general diesel, general diesel containing 20% biodiesel, and 100% biodiesel. Therefore, it was confirmed that the flammability risk did not significantly affect the explosion risk. Conclusion: The results of this study suggested the risk judgment criteria for mixtures through experimental research on flammable mixtures for the purpose of securing the effectiveness, reliability, and reproducibility of the details of the criteria for determining dangerous substances in the existing Dangerous Materials Safety Management Act. It will be possible to provide reference data for the judgment criteria for flammable liquids that are regulated in the field. In addition, if the know-how for each test method is accumulated through this study, it is expected that it will be used as basic data in the research on risk assessment of dangerous substances and as a basis for research on the determination of dangerous substances.

• Fire Science and Engineering
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• v.24 no.4
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• pp.12-17
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• 2010

The purpose of this study is to determine how effectively waste tire recycled material mixed with flame retardant work in combating fire. As discovered in the previous study, waste tire mixed with cement mortar has more insulation capacity. However, this mortar is weak against fire. Therefore flame retardant, with a specific proportional mix, will be added to increase its fire prevention capacity. Tests will be made in accordance with ISO 5657 procedures for measuring fire ignition time, flame and shape variation of test pieces at the Building Material Test Institute. The test piece will be set up with horizontal levels having a constant radiation heat of $1{\sim}5W/cm^2$. Temperature transfers and increases from the surface into the interior. Combustible gases result due to pyrolysis, and regular contact is maintained between the fire source and the center of the test piece for assessment purposes. Ignition has not been occurred without adding retardant meaning that there is almost no possibility of ignition of waste tire particle. This fact can be considered as fire load to appreciate a volume of combustion materials. Flame is not occurred due to heat-absorbing effect by adding non-organic series retardant into waste tire particle. Conclusions have been summarized as follows; 1) Combustion of building material can be decreased by adding retardant to waste tire-mixing mortar. But compressive strength and insulation capacity of the material should be measured later. 2) Firing prevention and ignition are main points of building fire. Reasonable fire engineering assessment of interior material should be made for establishing effective disaster prevention system.