• Bulletin of the Korean Chemical Society
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• 제8권6호
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• pp.449-453
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• 1987

The temperature dependence of the vibrational relaxation of NO(= 2) by NO(v = 0) has been investigated over the temperature range 100-3000 K. We have assumed that the deexcitation of NO(2) by NO(0) undergoes vibration-to-vibration (VV) energy exchange with the transfer of the energy mismatch ${\Delta}$E through rotation (R) and translation(T). The relaxation rate constants are calculated by solving the time-dependent Schrodinger equation. The sum of V-V, T, and V-V, R contributions shows very weak temperature dependence and is in reasonable agreement with observed data over the temperature range 300-3000 K.

• 한국응용곤충학회:학술대회논문집
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• 한국응용곤충학회 2002년도 합동 춘계 학술발표회
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• pp.95-95
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• 2002

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1814-1822
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• 2013

By using density functional theory calculations, we have performed a systemic study on the electronic structures and topological properties of interactions between N-butylpyridinium nitrate ($[BPY]^+[NO_3]^-$) and thiophene (TS), benzothiophene (BT), dibenzothiophene (DBT), naphthalene (NAP). The most stable structure of $[BPY]^+[NO_3]^-$ ion pair indicates that hydrogen bonding interactions between oxygen atoms on $[NO_3]^-$ anion and C2-H2 on pyridinium ring play a dominating role in the formation of ion pair. The occurrence of hydrogen bonding, ${\pi}{\cdots}$H-C, and ${\pi}{\cdots}{\pi}$ interactions between $[BPY]^+[NO_3]^-$ and TS, BT, DBT, NAP has been corroborated at the molecular level. But hydrogen bonding and ${\pi}{\cdots}{\pi}$ interactions between $[BPY]^+[NO_3]^-$ and NAP are weak in terms of structural properties and NBO, AIM analyses. DBT is prior to adsorption on N-butylpyridinium nitrate ionic liquid.

• 한국대기환경학회지
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• 제16권4호
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• pp.309-316
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• 2000

Chemical compositions of air pollutants with fine particles (<2.5 ${\mu}{\textrm}{m}$, PB2.5) were evaluated at background site. Kangwha. in Korea during the winter season. The data set was obtained for seventeed days with 24-hour sampling from December 11 to 16, 1996 and from January 9 to 1997. The chemical species have been measured {{{{ {SO }`_{4 } ^{2- } }}}}, {{{{ { NO}`_{3 } ^{- } }}}}, {{{{ { NH}`_{4 } ^{+ } }}}}. OC and EC in the particulate phase, NH3 HNO3, HCl and SO2 in the gas phase using the three stage filter pack method. Mean concentration ($\mu\textrm{g}$/m3) of this study were : 35.42 for PM2.5 8.78 for organic carbon (OC) 7.25 for nss {{{{ {SO }`_{4 } ^{2- } }}}}, 4.94 for {{{{ { NO}`_{3 } ^{- } }}}}, 3.58 for {{{{ { NH}`_{4 } ^{+ } }}}} and 1.48 for elemental carbon (EC) respectively. Contributive rates of major particulate components in PM2.5 were OC (25%) nss- {{{{ {SO }`_{4 } ^{2- } }}}}(20%) ,{{{{ { NO}`_{3 } ^{- } }}}}(14%) {{{{ { NH}`_{4 } ^{+ } }}}}(10%) and EC (4%) respectively and these components could be accounted for 73% of PM2.5 mass. Reactive forms of {{{{ { NH}`_{4 } ^{+ } }}}} were considered as NH4HO3 and NH4{{{{ {SO }`_{4 } ^{2- } }}}} during the sampling periods. {{{{ { NO}`_{3 } ^{- } }}}}/({{{{ { NO}`_{3 } ^{- } }}}} + HNO3) and {{{{ {SO }`_{4 } ^{2- } }}}}/({{{{ {SO }`_{4 } ^{2- } }}}} + SO2) were calculated 0.8 and 0.9 respectively. Most of these compounds might be formed in partiiculate phase in the air. Correlation coefficient between OC and EC was 0.866 which might have the same sources during the sampling periods,.

• 한국분말재료학회지
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• 제12권1호
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• pp.56-63
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• 2005

Ag powder was prepared from $AgNO_3$ by wet chemical reduction method using various reduction agent system involving $AgNO_3$, $AgNO_2$(AgCl) and Ag complex ion aqueous solution. The pure Ag powder could be prepared regardless of reaction system but the particle shape and distribution were affected very much according to the kind of reduction agents and reaction systems. The optimum reaction system for the preparation of the silver powder having the uniform particle shape and size distribution was Ag complex ion aqueous solution-reduction agent system and in particular, $H_2O_2$ and $C_6H_8O_6$as a reduction agent leaded the more uniform particle shape and size distribution.

• Korean Chemical Engineering Research
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• 제56권2호
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• pp.240-244
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• 2018

There is growing concern about cross infection among the patients to patients, patients to staffs, and tools to patients in healthcare facilities, especially in dentistry. In this study, the most widely used dental impression materials were prepared and the synergy effect of Chlorhexidine and essential oil on antimicrobial activity was examined in the impression materials. Chlorhexidine concentration of 0.1 wt% and 0.5 wt% showed no antimicrobial activity on Escherichia coli (E. coli) and Candida albicans. At 1.0 wt% Chlorhexidine, 0% of E. coli and 34.7% of Candida albicans were survived. Bergamot (Essential oil) concentration of 0.5 wt% and 1.0 wt% showed no antimicrobial activity on E. coli. At 2.0 wt% Bergamot oil, 71.9% of E. coli were survived. Tea tree oil (Essential oil) of 0.5 wt% showed no antimicrobial activity on E. coli. At 1.0 wt% Tea tree oil, 11.2% of E. coli was survived. At 2.0 wt% Tea tree oil, no E. coli was survived. However, no E. coli was survived at the concentration of 0.8 wt% Bergamot with 0.3 wt% Chlorhexidine. At the concentration of 0.8 wt% Tea Tree oil with 0.3 wt% Chlorhexidine, 1.3% of E. coli were survived. The experimental results showed that the synergy effects between Chlorhexidine and essential oils on antimicrobial activity were prominent.

• 공업화학
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• 제18권2호
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• pp.173-177
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• 2007

PVA 농도, $AgNO_3$ 농도, IPA의 농도, 그리고 전자빔의 조사량 등의 다양한 조건에서 PVA 매트릭스에서 은입자를 생성하기 위하여 전자 빔을 이용하였다. PVA 농도, $AgNO_3$ 농도, 그리고 IPA의 농도가 증가하고 전자빔의 조사량이 증가함에 따라서 생성된 은입자의 분포도가 증가함을 알 수 있었다. 그리고 $AgNO_3$ 농도, IPA의 농도, 그리고 전자빔의 조사량은 은입자의 생성에 중요한 변수가 됨을 확인하였다. 이러한 결과들을 XRD, UV, 그리고 TEM 등으로 확인하였다. XRD로부터 생성된 입자가 은임을 확인하였다. 생성된 은입자의 분포 및 크기 등을 연구하기 위하여 UV와 TEM을 사용하였다.

• 공업화학
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• 제28권3호
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• pp.299-305
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• 2017

활성탄소섬유가 전사선 조사에 의해 표면 개질되었고, NO가스 감지 능력에 미치는 영향을 살펴보기 위하여 이를 가스센서 전극으로 이용하였다. XPS 분석결과는 전자선에 의하여 표면처리된 활성탄소섬유의 산소 성분이 감소하였으며 표면의 $sp^2$ 결합탄소가 증가한 것을 보여주었다. 이러한 결과는 전자빔 조사에 따른 활성탄소섬유 표면의 구조적 변형때문으로 사료된다. 100 kGy의 전자빔이 조사된 활성탄소섬유 전극의 NO가스 민감도는 약 4%에서 약 8%로 크게 증가하였고, 그 감지 시간 또한 약 360 s에서 120 s로 의미 있게 향상되었다. 이러한 결과는 활성탄소섬유의 전자빔 조사에 의하여 $sp^2$ 탄소 결합의 증가때문에 기인한 것으로, 이는 NO가스 센싱에 대한 전극저항 변화에 상당히 영향을 주었다.

• 한국대기환경학회지
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• 제24권5호
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• pp.512-522
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• 2008

Ammonia is a major compound of odor in livestock house. To enhance the performance of ammonia oxidation (decomposition). the gas-liquid, two phase photocatalytic oxidation system was designed and prepared in this study. Commercial P-25 as $TiO_2$ catalyst was used for ammonia decomposition. V/P-25 catalyst prepared by sol gel method was also used for the removal of by-producted $NO_x$ in $NH_3$ oxidation reaction. When $TiO_2$ was used as a photocatalyst, the conversion to $N_2$ in ammonia decomposition reached above 90% until 200hr (The air flow rate of 4L/min with the ammonia concentration up to 25ppm.). However, considerable amounts of NO and $NO_2$ were formed as a result of $NH_3$ oxidation (as a by-product). Therefore, we added Vanadia impregnated $TiO_2$(P-25) catalyst for the removal of $NO_x$ at the end of reaction trail. The results of a pilot-scale operation were successful to achieve the simultaneous removal of $NH_3\;and\;NO_x$ about 81 and 87%, respectively.

• Korean Chemical Engineering Research
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• 제56권5호
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• pp.752-760
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• 2018

경유자동차에서 배출되는 탄소 입자상 물질 연소 온도구간을 낮추는 것은 미세먼지 배출 저감과 내연기관 자동차의 고연비 저배출 성능 구현이라는 측면에서 매우 중요한 기술적 과제 중 하나이다. 본 논문에서는 탄소 입자상 물질의 산화를 위해 오존을 산화제로 이용하고 백금계 산화촉매를 동시에 적용했을 때 관찰되는 $150^{\circ}C$ 부근 저온영역에서의 탄소 입자상 물질 연소반응에 관하여 논했다. 백금계 산화촉매를 적용했을 때 오존에 의한 탄소 입자상 물질의 산화속도를 크게 개선시키지 못했지만 연소반응의 이산화탄소 선택도를 향상시켰으며, 탄소 입자상 물질의 선택적 산화를 위해 고려된 NO의 $NO_2$로의 사전 전환($NO_2$-rich 조건)은 $NO_2$와 오존의 상호 상승작용에 의해 $150^{\circ}C$ 부근 온도영역에서의 탄소상 입자물질 연소성능을 높이는데 효과가 있었다.