• Advances in Computational Design
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• 제3권2호
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• pp.147-163
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• 2018

Cementitious composites are multiphase heterogeneous materials with distinct dissimilarity in strength under compression and tension (high under compression and very low under tension). At macro scale, the phenomenon can be well-explained as the material contains physical heterogeneity and pores. But, it is interesting to note that this dissimilarity initiates at molecular level where there is no heterogeneity. In this regard, molecular dynamics based computational investigations are carried out on cement clinkers and calcium silicate hydrate (C-S-H) under tension and compression to trace out the origin of dissimilarity. In the study, effect of strain rate, size of computational volume and presence of un-structured atoms on the obtained response is also investigated. It is identified that certain type of molecular interactions and the molecular structural parameters are responsible for causing the dissimilarity in behavior. Hence, the judiciously modified or tailored molecular structure would not only be able to reduce the extent of dissimilarity, it would also be capable of incorporating the desired properties in heterogeneous composites. The findings of this study would facilitate to take step to scientifically alter the structure of cementitious composites to attain the desired mechanical properties.

• 한국건축시공학회지
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• 제20권1호
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• pp.1-9
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• 2020

외부로부터 시멘트 복합체 내부로 침투되는 염소이온은 주로 농도차로 인한 확산을 통해 이동한다. 확산하는 염소이온 중 일부는 일반적으로 내부 수화물과의 반응을 통해 고정되는데, 최근의 몇몇 연구는 음이온 교환 수지(AER) 분말이 혼입된 시멘트 복합체의 염소이온 침투 저항성 및 고정능력에 관한 연구결과를 보여주었다. 본 연구에서는 AER이 분쇄되는 과정에서 염소이온 흡착능력이 상실하는지를 확인하고자 한다. AER 분말의 염소이온 흡착능력은 증류수와 포화수산화칼슘 수용액 조건에서 분석되었고, AER 비드의 염소 이온 흡착능력에 관한 기존의 연구결과와 비교되었다. 추가로, AER 분말이 포틀랜드 시멘트의 일부 치환된 모르타르의 압축강도 측정, 염소이온 확산계수 도출(NT Build 492 시험방법 이용), 염소이온 침투 프로파일링(전자현미분석 이용)을 수행하였다. 본 연구의 실험 결과는 분쇄과정으로 인한 AER 분말의 염소이온 흡착능력 저하가 거의 없음을 보여 주었다. 그리고 AER 분말은 모르타르 내에서도 염소이온을 빠르게 흡착할 수 있었고, 시멘트 수화물보다 우수한 염소이온 흡착성능을 보여주었다.

• Restorative Dentistry and Endodontics
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• 제13권1호
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• pp.53-67
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• 1988

An investigation was carried out to compare the pulp responses against a few type of composite and streptococcus mutans contamination under the zinc oxide eugenol cement, and also confirmed pulpal responses of various composites with or without base. Seventy eight teeth from 6 dogs were employed and divided into 6 groups. Class V cavities were prepared on each tooth routinely with low speed dental engine. Paper disc about 0.3mm thick was immersed in the BHI broth in which streptococcus mutans had been enriched and the disc was inserted on the cavity floor prior to filling. Scotch bond puls Silux as Bis-GMA system composite resin and Helimolar as urethane system composite resin were adopted. Control group: Zinc-Oxide Eugenol cement filling Experimental groups: Group 1. Scotch bond + Silux filling with Dycal base Group 2. Heliomolar filling with Dycal base Group 3. Scotch bond + Silux filling without base Group 4. Heliomolar filling without base Group 5. Streptococcus mutans application. All cavities were sealed with thick ZOE cement to avoid marginal leakage. Postoperative intervals of 1, 2, 3, 4, 5 and 6 weeks teeth were carefully extracted, processed and stained with Hematoxylin and Eosin. The results were as follows: 1. S. mutans application group and composites without any base showed more severe pupal response than control group and dyca based groups. 2. The experimental group of S. mutans application showed severe response in the early stage compared to the two groups of composite resin without base, but no significant difference was found following periods. 3. The difference of pulpal response is not significant between Bis-GMA system and urethane system. 4. Streptococcus mutans application group and composites without base groups showed the evidence of histologic recovery at the six week cases and the large amount of reparative dentin was the prominent feature. 5. Pulp responses against every material were inclined to normal according to the time elapsed.

• Restorative Dentistry and Endodontics
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• 제37권1호
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• pp.41-49
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• 2012

Objectives: The internal adaptation of composite restorations with or without resin modified glass ionomer cement (RMGIC) was analyzed non-destructively using Microcomputed tomography (micro-CT). Materials and Methods: Thirty intact human teeth were used. The specimens were divided into 3 groups. In the control group, the cavities were etched with 10% phosphoric acid for 15 sec. Composite resin was filled into the cavity without adhesive. In group 1, light cured glass ionomer cement (GIC, Fuji II LC, GC) was applied as a base. The cavities were then etched, bonded, light cured and filled with composites. In group 2, the cavities were then etched, bonded, light cured and filled with composites without base application. They were immersed in a 25% silver nitrate solution. Micro-CT was performed before and after mechanical loading. One-way ANOVA with Duncan analysis was used to compare the internal adaptation between the groups before or after loading. A paired t-test was used to compare internal adaptation before and after mechanical loading. All statistical inferences were made within the 95% confidence interval. Results: The silver nitrate solution successfully penetrated into the dentinal tubules from the pulp spaces, and infiltrated into the gap between restoration and pulpal floor. Group 2 showed a lower adaptation than the control group and group 1 (p < 0.05). There was no significant difference between the control group and group 1. For all groups, there was a significant difference between before and after mechanical loading (p < 0.05). Conclusions: The internal adaptation before and after loading was better when composites were bonded to tooth using adhesive than composites based with RMGIC.

• 한국건설관리학회논문집
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• 제1권2호
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• pp.63-70
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• 2000

시멘트복합체에 사용되는 혼화재료중 무기안료는 그 착색효과로 인해 건축구조물의 미적 가치를 한층 높일 수 있는 효과가 있으므로 최근들어 도시미관을 중요시하는 추세와 더불어 그 사용량이 더욱 늘어날 것으로 전망된다. 본 연구는 무기안료가 시멘트 모르터의 유동성에 미치는 영향을 파악하여 착색시멘트모르터의 건축적인 활용을 위한 기초적 자료로 활용하고자 무기안료를 혼입한 시멘트모르터의 배합비, 물시벤트비, 안료혼입률 등을 변화시켜 유동성 실험을 진행하여 다음과 같은 결과를 도출하였다. 적색모르터와 황색모르터의 경우 안료혼입률이 증가할수록 유동성이 급격히 감소하므로 적절한 유동성을 확보하기 위해서는 혼합수의 증가 또는 유동화제의 사용이 필요하다. 그러나 녹색모르터의 경우에는 $-2.4{\~}6.9{\%}$의 플로변화율로 유동성의 변화가 거의 없었으며, 흑색모르터의 경우에도 유동성을 고려할 필요가 없는 것으로 판단되었다.

• 한국건설순환자원학회논문집
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• 제10권3호
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• pp.314-320
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• 2022

건축자재에서 사용되는 보강 섬유의 기능은 휨하중에 대한 저항력 유지, 건조 수축에 의한 균열 방지 기능 등을 목적으로 하고 있다. 고밀도 섬유 시멘트 복합체는 주로 선형의 판재에 사용되는 것으로 휨 저항력을 높이기 위하여 사용한다. 따라서, 인장성, 시멘트 수화물과의 결합력, 내알칼리성 등이 요구된다. 최근 불연성능 기준이 강화되어 고온 가열 시 불꽃 발생을 최소화해야 하는 기능이 추가되었다. 따라서 유기 섬유의 사용이 제한되고 있다. 본 연구에서는 보강 섬유로 사용하는 폴리프로필렌 섬유를 내열성이 우수한 마 섬유로 대체하여 사용하는 연구를 수행하였다. 마 섬유는 내열성이 우수하고 시멘트와의 친화력이 좋으며 알칼리 저항력 또한 우수하다. 기존의 배합에서 사용하는 폴리프로필렌 섬유의 부피 총량을 기준으로 마 섬유를 대체하여 사용하여 불연성능을 비교 평가하였으며, 휨강도 등 기본 물리적 특성 시험을 진행하였다. 길이 7 mm의 마 섬유를 질량비 2 %, 3 %를 사용하여 불연 및 물리적 특성 시험을 수행한 결과 불꽃의 잔존 시간은 전혀 없는 것으로 나타났으며, 휨강도는 기존 폴리프로필렌 섬유의 95 % 수준까지 확보가 가능한 것으로 확인되었다.

• Advances in concrete construction
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• 제13권 2호
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• pp.133-152
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• 2022

Ecological issues such as natural resource reduction and enormous waste disposals are increasingly leading in developing civilization toward sustainable construction. The two primary environmental issues are the depletion of natural resources and the disposal of trash in open landfills. Waste steel fiber (WSF) was investigated for usage as a cement-based concrete (CBC) constituent in this research. Recycling waste fibers both makes cement composites more long and cost-effective, also aids in pollution reduction. The objective of this study is to analyze the impacts of waste fiber on the fresh and mechanical features of concrete using recycled additives. A comparative research on the durability and mechanical qualities of fiber-reinforced concrete (FRC) constructed with natural aggregates was conducted for this aim. The obstacles to successful WSF recycling methods application in the building industry have been investigated, resulting that CBCs with these fibers make an economic and long lasting choice to deal with waste materials. The workability of fiber enhanced concrete was found to be comparable to that of normal concrete. Fibers have a considerable impact on the splitting tensile strength, flexural and compressive strength of recycled concrete. Fiber may enhance the water permeability. When the WSF content is 0.6 kg/m3, the water absorption is nearly half. Fibers would have no effect on its permeability.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문발표회
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• pp.57-60
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• 2003

Generally, normal concrete has the disadvantages of low tensile strength, low ductility and volume instability. To improve its performance, fiber reinforced cimentitious composite(FRCC) have been development. These composites are composed of cement, sand, water, a small amount of admixtures, and an optimal amount of fiber like synthetic fiber and steel fiber. This research investigates influence of sand, hybrid fiber and fiber volume fraction, and reports the test results of mechanical properties, fracture behavior and failure pattern of the FRCC. Our experiment was observed that sand mixed FRCC has lower compressive strength and higher bending strength than no sand mixed FRCC, and more steel fiber mixed FRCC has higher compressive strength and bending strength. Hybrid FRCC of steel and polypropylene had superior properties than FRCC of polypropylene only in same fiber volume fraction.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.615-618
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• 2004

The primary role of fibers in High performance fiber reinforced cement composites(HPFRCCs) is to improve the toughness, or energy absorption capacity, of the composite material, However, there is still no general agreement as to how this toughness should be characterized, or how it might be used in the design of structures containing HPFRCCs. In this paper, therefore, we focus on test techniques for measuring flexural toughness. For mechanical properties, HPFRCCs can be tested in the same way as fiber reinforced concrete(FRC). Both the significance and the limitations of somewhat different national and industrial standards of FRC are discussed. For flexural toughness, with depend on the presence of fibers, new test methods was developed and verified. We also suggest evaluation method of tensile toughness indices using the moment curvature relationship in flexural tests.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.941-944
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• 2008

PVA 섬유, 강섬유를 다량으로 혼입한 고인성 시멘트 복합체가 개발되고 이를 구조물에 활용하고자 하는 연구가 전 세계적으로 수행되고 있다. DFRCC는 경제적 효율성을 고려한다면 현재까지 구조물 전체 부분에 적용하기보다는 특별한 요소나 보수재료서 적용하는 것이 경쟁력이 있을 것으로 사료된다. 저자들은 DFRCC를 FRP-콘크리트 합성 바닥판과 습식 스프레이 보수공법에 적용하는 기술을 개발하고 있다. FRP-콘크리트 합성 바닥판에 적용할 경우에는 현장 적용하여 3개월 경과하더라도 구조성능 또는 내구성능이 저하되는 문제가 발생하지 않았고 매우 양호한 상태를 유지하였다. 그리고 국산 PVA 섬유 사용 DFRCC 보수 모르타르를 20년이 경과된 하수박스암거에 적용한 경우에는 한 결과, 일본산 PVA 섬유를 사용한 경우와 차이가 거의 없었다. 관련 규격인 KS F 4042의 압축 및 휨 강도기준을 모두 만족하는 것으로 나타났다. 이상과 같이 DFRCC를 구조물에 적용할 경우에는 구조물 종류에 따라서 경제적으로 성능 향상에 크게 기여할 수 있을 것으로 판단된다.