• Title/Summary/Keyword: nitrogen ratio

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High-Rate Biological Nitrogen Removal from Plating Wastewater using Submerged MBR Packed with Granular Sulfur (황 충진 MBR을 이용한 도금폐수의 고효율 생물학적 질소 제거)

  • Kim, Dae-young;Moon, Jin-young;Baek, Jin-uk;Hwang, Yong-woo
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.2
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    • pp.200-208
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    • 2005
  • In this study, a new submerged membrane bioreactor process packed with granular sulfur (MBR-GS) was operated to identify the biological nitrogen removal behaviors with plating wastewater containing high-strength $NO_3{^-}$ concentration. The continuous denitrification was carried out at $20^{\circ}C$ with various nitrogen loading rates using synthetic wastewater, which composed of $NO_3{^-}$ and $HCO_3{^-}$, but also actual plating wastewater, which was collected from the effluent of the H metal plating company. As a result, high-rate denitrification in the range of $0.8kg\;NO_3{^-}-N/m^3\;day$ was accomplished at nitrogen loading rate of $0.9kg\;NO_3{^-}-N/m^3\;day$ using synthetic wastewater. Also, higher-rate denitrification with actual plating wastewater was achieved up to $0.91kg\;NO_3{^-}-N/m^3\;day$ at the loading rate of $1.11kg\;NO_3{^-}-N/m^3\;day$. Additionally, continuous filtration was possible during up to 30 days without chemical cleaning in the range of 20 cmHg of transmembrane pressure. On the basis of the proposed stoichiometry, ${SO_4}^{2-}$ production could be estimated efficiently, while observed alkalinity consumption was somewhat lower than theoretical value. Consequently, a new process, MBR-GS is capable of high-rate autotrophic denitrification by compulsive flux and expected to be utilized as an alternative of renovation techniques for nitrogen removal from not only plating wastewater but also municipal wastewater with low C/N ratio.

Research on the Efficient Manufacturing Method of Photocatalyst Concrete according to the Type and Mixing Ratio of Photocatalyst (광촉매 종류 및 혼입률에 따른 효율적 광촉매 콘크리트의 제조 방법에 관한 연구)

  • Park, Gi-Joon;Park, Jung-Jun;Kwak, Jong-Won;Kim, Sung-Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.69-77
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    • 2019
  • In this study, we evaluated the mechanical properties and nitrogen oxides removal characteristics according to the type and incorporation rate of the photocatalyst and investigated the method of separated placement for the production of economical and efficient photocatalyst concrete. As a result, when the photocatalyst incorporation rate was 5%, the highest compressive strength and elastic modulus were measured. As a result of evaluating the nitrogen oxides removal performance by the photocatalytic reaction, as the photocatalyst incorporation rate increased, the nitrogen oxide removal rate increased. At this time, the nitrogen oxides removal performance of photocatalyst P-25 was better than the NP-A. In consideration of economic efficiency, we have provided a method of separated placement for casting a constant thickness of concrete surface with photocatalyst concrete and evaluated the integrated performance at this time. As a result, it appears to be equal to or higher than mechanical performance and durability performance as compared with Plain, and it is judged that the integrated behavior is satisfied.

Evaluation of the Feasibility of Eliminating Non-point Source Pollution Using Waste Sewage Sludge Bio-blocks (하수슬러지를 이용한 Bio-block의 비점오염물질 제거 가능성 평가)

  • Han, Sang Moo;Kim, Do Hyeong;Jeong, Byung Gon
    • Journal of Korean Society on Water Environment
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    • v.37 no.5
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    • pp.363-368
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    • 2021
  • On the assessment results of the non-point source pollutant removability of bio-block using waste sewage sludge, at the reactor's initial operation stage, the removal efficiency of COD was slightly unstable. However, after the reactor was stabilized, the COD removal efficiency was higher in the reactor filled with bio-blocks compared to the reactor filled with broken stones. In terms of nitrogen and phosphorus, their removal efficiency was unstable at the initial stage of the reactor operation. This phenomenon was investigated through the bio-block elution experiments. Results indicated that nitrogen and phosphorus were eluted from the bio-blocks affecting their removal at the initial operation. Furthermore, based on elution tests conducted after the dry ashing of the waste sewage sludge, part of the nitrogen and phosphorus was eluted similar to the bio-block elution test results, although considerable amounts of nitrogen and phosphorus were reduced compared to the sludge cake. Prior to the use of the waste sewage sludge bio-blocks as a filter medium to remove non-point source pollutants, a stabilization period of 10 days was required. After the stabilization process, results showed similar characteristics as general aggregates. Moreover, to use the bio-block as a filter medium for the non-point pollutant removal, the filling ratio of 75% was the most suitable as it resulted in the highest nitrogen removal efficiency after the stabilization. The results of this study suggested that waste sewage sludge can be suitably recycled as a mixed raw material for the bio-blocks, with satisfactory application as a filter medium in artificial wetlands, stormwater runoff problems, stream water pollutants to eliminate non-point source pollutants.

Determination of the Optimum NH$_3$-N/NO$_2$-N Ratio by Anaerobic Batch Test in Anaerobic Ammonium Oxidation Process (혐기성 암모늄 산화공정에서 혐기성 회분식 실험에 의한 NH$_3$-N/NO$_2$-N의 최적비 산정)

  • Lee, Hwan-Hee;Kim, I-Jung;Jung, Jin-Young;Kim, Jee-Hyung
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.7
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    • pp.700-704
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    • 2008
  • Nitrite and free ammonia have been known as substrate inhibitors in anaerobic ammonium oxidation. To reduce inhibitory effect of these substrates, the NH$_3$-N/NO$_2$-N ratio in the influent could be properly controlled in anaerobic ammonium oxidation process. Five kinds of NH$_3$-N/NO$_2$-N ratio were assayed in batch to find optimum NH$_3$-N/NO$_2$-N ratio, curtailing substrate inhibition. As the results of batch test, the highest T-N removal efficiency of 88% was obtained at 1.00 : 1.30 of NH$_3$-N/NO$_2$-N ratio. In addition, rate constants for ammonium and nitrite in zero-order kinetics were found to be the highest values as 7.66 mg/L$\cdot$hr and 11.89 mg/L$\cdot$hr at 1.00 : 1.30 ratio, respectively. However, as for the specific anammox activity, the ratio of NH$_3$-N/NO$_2$-N ratio was recommended as 1 : 1.15 which can maintain the highest SAA during continuous operation and preclude the accumulation of nitrite in the reactor.

Effects of Influent Flow Distribution Ratio and HRT on Sewage Treatment Efficiency of the ASA Process (유입수 분배비와 체류시간이 ASA 공정의 가정오수 처리효율에 미치는 영향)

  • Yang, Eun-Gyoung;Sung, Il-Wha
    • Journal of environmental and Sanitary engineering
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    • v.24 no.1
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    • pp.13-24
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    • 2009
  • This study was performed to determine the effect of the influent flow distribution ratio and hydraulic retention time(HRT) on removal of organic matter, nitrogen and phosphorus when domestic sewage was treated by the advanced step aeration(ASA) process. Results of the experiment for the determination of the optimum influent flow distribution ratio between the anaerobic reactor and the anoxic reactor showed BOD removal efficiencies of above 92.0% at all influent flow distribution ratios from 9:1 to 4:6. The highest T-N removal efficiency was 82.6% at the influent flow distribution ratio of 6:4. On the other hand, the highest T-P removal efficiency was 67.8% at the influent flow distribution ratio of 9:1. Considering both the T-N and T-P removal efficiencies, the influent distribution ratio of 6:4 was considered the optimum. Results of the experiment for the determination of the optimum HRT at the optimum influent flow distribution ratio of 6:4 revealed BOD removal efficiencies better than 92.7% at all HRTs from 12hr down to 6hr. The highest T-N and T-P removal efficiency were 82.6% and 59.5%, respectively both at the HRT of 8hr. In conclusion, the optimum influent flow distribution ratio and HRT for treatment of domestic sewage by the ASA process were determined to be 6:4 and 8hr, respectively.

Components Related to Yield of CNU Glutinous Rice Lines on Two Nitrogen Levels (찰성벼 CNU계통에 대한 질소 수준별 주요 수량 관련 형질)

  • Choi, Yun-Pyo;Cha, Hui-Jeong;Bok, Tae-Gyu;Na, Seung-Yeon;Jeong, Jong-Tae;Lee, Hee-Bong
    • Korean Journal of Agricultural Science
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    • v.36 no.2
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    • pp.129-134
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    • 2009
  • Objectives of this study was to find the effect on two different nitrogen levels about agricultural characteristics of CNU rice lines developed at Crop Genetics and Breeding Laboratory, Chungnam Nat'l Univ.. Materials used were two black and one white glutinous rice lines, which were transplanted by hand with $30{\times}15cm$ at CNU paddy field on May 23, 2009. These lines was designed with two replication by two nitrogen levels as 7kg and 9kg per 10a. As the result; Culm length of all lines used were higher at 7kg than 9kg per 10a while panicle length was longer at 9kg nitrogen level. Tillers per plant of CNU 08-01 and CNU 08-02 lines except CNU 08-101 showed highly at 9kg level, but that of other leading varieties were not constant trends in spite of increasing nitrogen. Ripening ratio of CNU 08-01 and 08-02 lines were higher at 7kg but CNU 08-101 line was higher at 9kg. 1,000 grain weight and unhulled rice yield per 20 plants in all CNU lines were highly appeared at 9kg levels per 10a.

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Comparison Study of Nitrogen Dioxide and Asthma Doctor's Diagnosis in Seoul - Base on Community Health Survey 2012~2013 - (서울시 대기 중 이산화질소 농도와 천식증상의 비교 연구 - 2012~2013년 지역사회건강조사 자료를 중심으로 -)

  • Lee, Sang-Gyu;Lee, Yong-Jin;Lim, Young-Wook;Kim, Jung-Su;Shin, Dong-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.575-582
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    • 2016
  • Seoul city has high population density as well as high traffic congestion, which are vulnerable to exposure of environmental pollutions caused by car traffic. However, recent studies are only on local regions about road traffic and air pollution or health effect of road traffic on residents. Thus, comprehensive study data are needed in terms of overall Seoul regions. In this study utilized the nitrogen dioxide concentration through the national air pollution monitoring network data, 2012 to 2013. It also divided regions into high and low exposure districts via the Origin destination data developed by the Korea transport institute to quantify and evaluate the effect of transport policies and analyzed a correlation of asthma symptoms with high and low exposure districts through raw data of community health survey from the Korea centers for disease control and prevention. Based on the collected data, the pearson's correlation analysis was conducted between air pollution substance concentration and high exposure district and multiple logistic regression analysis was conducted to determine the effect of traffic environment and factors on asthma symptoms of residents. Accordingly, the following results were derived. First, the high exposure district was higher concentrations of nitrogen dioxide ($NO_2$) as per time compared to those of the low exposure district (p<0.01). Second, analysis on correlation between average daily environmental concentration in the air pollution monitoring network and road traffic showed that nitrogen dioxide had a significant positive correlation (p<0.01) with car traffic and total traffic as well as with truck traffic (p<0.05) statistically. Third, an adjusted odds ratio about asthma doctor's diagnosis in the high and low exposure districts was analyzed through the logistic regression analysis. With regard to an adjusted model 2 (adjusted gender, age, health behavior characteristics, and demographic characteristics) odds ratio of asthma doctor's diagnosis in the high exposure district was 1.624 (95% CI: 1.269~2.077) compared to that of the low exposure district, which was significant statistically (p<0.001).

Varietal Differences in Physiological Characteristics Focussed on N. P. K and Si Uptake under Cold Temperature at Seedling Stage (묘대기(苗垈期) 수도품종별(水稻品種別) N, P, K, Si 함량(含量)에 미치는 저온처리와 질소(窒素) 및 인산증시의 영향(影響))

  • Seok, Soon-Jong;Ryu, In-Soo;Ha, Ho-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.2
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    • pp.183-187
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    • 1983
  • The investigate the varietal differences is physiological characteristics related to nutrient uptake and response to nitrogen and phosphorus, a pot experiment was conducted in a temperature control chamber. Three varieties with different cold resistances were grown under normal ($23^{\circ}-25^{\circ}C$) and cold ($15^{\circ}C$) conditions with three nitrogen and phosphorus application levels. The cold temperature was treated for twelve days after thirty days from seeding. The results were summarized as follows: 1. Dry weight and nutrient contents were reduced in cold temperature treatment compared with control and the reduced ratio by low temperature were in order of dry weight 29.4% $P_2O_5$ 21.3%, N 15.3%, $K_2O$ 10.1%, $SiO_2$ 8.7%. 2. The reduced ratio of phosphorus contents of each varieties to normal condition were 13.5% in resistant, 19.5% in medium, 31.1% in susceptible variety, respectively. 3. The phosphorus and silicate contents of plants showed a good relationship with varietal differences in cold resistance but nitrogen and potassium didn't showed, therefore, phosphorus and silicate contents might be used as the index for physiological characteristics related with cold resistance. 4. Phosphorus content slightly increased with nitrogen application but silicate content decreased. Upon phosphorus application, nitrogen and silicate contents were increased.

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Influence of Organic, Inorganic Nitrogen Sources and Amino Acids on the Biosynthesis of Coenzyme $Q_{10}$ by Agrobacterium tumefaciens Mutant (Agrobacterium tumefaciens 변이주에 의한 Coenzyme $Q_{10}$ 생합성시 유기, 무기질소원과 아미노산의 영향)

  • Kim, Jeong-Keun;Won, Yong-Bae;Lee, Kang-Moon;Koo, Yoon-Mo
    • KSBB Journal
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    • v.24 no.1
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    • pp.75-79
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    • 2009
  • The effect of inorganic, organic nitrogen sources and amino acids on the coenzyme $Q_{10}$ production and coenzyme $Q_{10}$ component ratio was investigated. Among the nine organic nitrogen sources, CSP showed a remarkable enhancing effect on the production of coenzyme $Q_{10}$. But this enhancement was not observed in medium containing Bacto peptone, tryptone, casamino acid and soybean meal. These differences on the production of coenzyme $Q_{10}$ may be due to differences in kinds and amounts of component amino acids and peptides in the various organic nitrogen sources tested. In the addition of inorganic nitrogens, only $(NH_4)_2SO_4$ increase the coenzyme $Q_{10}$ production by 2.0 times compare to the control group. The addition of L-tyrosine to the medium containing Bacto tryptone, was also determined to be crucial for the coenzyme $Q_{10}$ production. But phenylalanin and tryptophan, other aromatic amino acids, had no stimulatory effect on the coenzyme $Q_{10}$ production. These results show that the production and components ratio of coenzyme $Q_{10}$ was greatly affected by the kinds and the concentration of inorganic, organic nitrogen sources as well as amino acids.

Effect of Outer Edge Flame on Flame Extinction in Counterflow Diffusion Flames (대향류 확산화염에서 에지화염이 화염소화에 미치는 영향)

  • Chung, Yong-Ho;Park, Dae-Geun;Park, Jeong;Yun, Jin-Han;Kwon, Oh-Boong;Keel, Sang-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.2
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    • pp.181-188
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    • 2012
  • The present study on nitrogen-diluted non-premixed counterflow flames with finite burner diameters experimentally investigates the important role of the outer edge flame in flame extinction. Flame stability diagrams mapping the flame extinction response of nitrogen-diluted non-premixed counterflow flames to varying global strain rates in terms of the burner diameter, burner gap, and velocity ratio are explored. There exists a critical nitrogen mole fraction beyond which the flame cannot be sustained, and also the curves of the critical nitrogen mole fraction versus the global strain rate have C-shapes in terms of burner diameter, burner gap, and velocity ratio. In flames with sufficiently high strain rates, the curves of the critical nitrogen mole fractions versus global strain rate collapse into one curve, and the flames can have the 1-D flame response of typical diffusion flames. Three flame extinction modes are identified: flame extinctions through the shrinkage of the outer edge flame with and without an oscillation of the outer edge flame prior to the extinction and flame extinction through a flame hole at the flame center. The measured flame surface temperature and a numerical evaluation of the fractional contribution of each term in the energy equation show that the radial conductive heat loss at the flame edge destabilizes the outer edge flame, and the conductive and convection heat addition to the outer edge from the trailing diffusion flame stabilizes the outer edge flame. The radial conductive heat loss at the flame edge is the dominant extinction mechanism acting through the shrinkage of the outer edge flame.