• Title/Summary/Keyword: nitrogen ratio

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Changes of Nitrogen Fixation Activity and Heavy Metal Accumulation of Vicia amoena Community from Kumho Riverside (금호강유역 갈퀴나물군락의 중금속 축적과 질소고정 활성의 변화)

  • 박태규;박용목;송은주;송승달
    • The Korean Journal of Ecology
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    • v.22 no.3
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    • pp.131-137
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    • 1999
  • This study was carried out to investigate the activity of nitrogen fixation and accumulation of heavy metal and inorganic matter in Vicia amoena community at lower region in Kumho riverside, including Youngchon, Chimsangyo, Paldalgyo, Talseochon and Kumhogyo. The contents of inorganic matter and heavy metal of Kumho riverside soil increased in the down stream in each organ of the plant growing in the riverside. Generally, V. amoena community showed rapid growth of shoot and high value of Top/Root ratio. V. amoena community showed higher water content of shoot at late growth stage and higher chlorophyll content. The root nodule of V. amoena community appeared in April and increased by 0.30, 0.27, 0.24, 0.06 and 0.14 g/plant, and nitrogen fixation activity of nodule attained 20.1, 16.8, 15.4, 8.5 and 5.3 μmol·C₂H₄·g fw nodule/sup -1/·h/sup -1/ for non-contaminated area Youngchon, Chimsangyo, Paldalgyo, Talseochon and Kumhogyo, respectively, in June:. Nodule formation and nitrogen fixation activity were reduced in the down stream by the soil contamination and heavy metal accumulation and showed minimum values. at Talseochon and Paldalgyo. V. amoena showed growth adaptation against heavy metal toxicity by restricting heavy metal such as Pb, Cu, Zn, Fe from transport, and by accumulating high Ca ion in shoot, nitrogen and phosphorus in root at late growth stage than those at early one, respectively, but total heavy metal per plant showed higher values in shoot than those in root by high T/R ratio of plant growth.

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Characteristics of Marine Environment and Primary Productivity of Phytoplankton in the Seaweed Bed of Northwestern Coast of Jeju Island During Autumn 2014 (2014년 추계 제주 북서부 해조장에서 해양환경과 식물플랑크톤의 일차생산력 특성)

  • KWON, HYEONG KYU;YANG, HAN SOEB;YOON, YANG HO;CHOI, OK IN;CHOI, IM HO;OH, SEOK JIN
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.20 no.4
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    • pp.180-191
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    • 2015
  • Marine environmental characteristics and primary productivity of phytoplankton were investigated in seaweed bed of northwestern coast of Jeju Island during Autumn, 2014. The trophic state based on dissolved inorganic nitrogen and phosphorus was mesotrophic. The Redfield ratio was less than 16, indicating that nitrogen was the limiting factor for the growth of phytoplankton. Dissolved organic nitrogen and phosphorus accounts for 63 and 46% of the dissolved total nitrogen and phosphorus, respectively. Light utilization efficiency (${\alpha}$) and maximum photosynthetic capacity ($P_m{^B}$) were highest in the Donggwi (third-year marine forest), followed by Gonae (one-year marine forest), Biyangdo (natural seaweed bed) and Geumneung (whitening area). The primary productivity of phytoplankton in the Donggwi, Gonae and Biyangdo also was higher than that in the Geumneung. Although nitrogen is the limiting factor, enriched dissolved organic nitrogen might play an important role to maintain primary productivity. In addition, phytoplankton community through photosynthesis could produce about 14% of phytoplankton carbon in one hour. These results will be able to use the important information for material cycle and ecological valuation of seaweed bed.

Improved Electrical Properties by In Situ Nitrogen Incorporation during Atomic Layer Deposition of HfO2 on Ge Substrate (Ge 기판 위에 HfO2 게이트 산화물의 원자층 증착 중 In Situ 질소 혼입에 의한 전기적 특성 변화)

  • Kim, Woo-Hee;Kim, Bum-Soo;Kim, Hyung-Jun
    • Journal of the Korean Vacuum Society
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    • v.19 no.1
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    • pp.14-21
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    • 2010
  • Ge is one of the attractive channel materials for the next generation high speed metal oxide semiconductor field effect transistors (MOSFETs) due to its higher carrier mobility than Si. But the absence of a chemically stable thermal oxide has been the main obstacle hindering the use of Ge channels in MOS devices. Especially, the fabrication of gate oxide on Ge with high quality interface is essential requirement. In this study, $HfO_xN_y$ thin films were prepared by plasma-enhanced atomic layer deposition on Ge substrate. The nitrogen was incorporated in situ during PE-ALD by using the mixture of nitrogen and oxygen plasma as a reactant. The effects of nitrogen to oxygen gas ratio were studied focusing on the improvements on the electrical and interface properties. When the nitrogen to oxygen gas flow ratio was 1, we obtained good quality with 10% EOT reduction. Additional analysis techniques including X-ray photoemission spectroscopy and high resolution transmission electron microscopy were used for chemical and microstructural analysis.

Hybrid MBE Growth of Crack-Free GaN Layers on Si (110) Substrates

  • Park, Cheol-Hyeon;O, Jae-Eung;No, Yeong-Gyun;Lee, Sang-Tae;Kim, Mun-Deok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.183-184
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    • 2013
  • Two main MBE growth techniques have been used: plasma-assisted MBE (PA-MBE), which utilizes a rf plasma to supply active nitrogen, and ammonia MBE, in which nitrogen is supplied by pyrolysis of NH3 on the sample surface during growth. PA-MBE is typically performed under metal-rich growth conditions, which results in the formation of gallium droplets on the sample surface and a narrow range of conditions for optimal growth. In contrast, high-quality GaN films can be grown by ammonia MBE under an excess nitrogen flux, which in principle should result in improved device uniformity due to the elimination of droplets and wider range of stable growth conditions. A drawback of ammonia MBE, on the other hand, is a serious memory effect of NH3 condensed on the cryo-panels and the vicinity of heaters, which ruins the control of critical growth stages, i.e. the native oxide desorption and the surface reconstruction, and the accurate control of V/III ratio, especially in the initial stage of seed layer growth. In this paper, we demonstrate that the reliable and reproducible growth of GaN on Si (110) substrates is successfully achieved by combining two MBE growth technologies using rf plasma and ammonia and setting a proper growth protocol. Samples were grown in a MBE system equipped with both a nitrogen rf plasma source (SVT) and an ammonia source. The ammonia gas purity was >99.9999% and further purified by using a getter filter. The custom-made injector designed to focus the ammonia flux onto the substrate was used for the gas delivery, while aluminum and gallium were provided via conventional effusion cells. The growth sequence to minimize the residual ammonia and subsequent memory effects is the following: (1) Native oxides are desorbed at $750^{\circ}C$ (Fig. (a) for [$1^-10$] and [001] azimuth) (2) 40 nm thick AlN is first grown using nitrogen rf plasma source at $900^{\circ}C$ nder the optimized condition to maintain the layer by layer growth of AlN buffer layer and slightly Al-rich condition. (Fig. (b)) (3) After switching to ammonia source, GaN growth is initiated with different V/III ratio and temperature conditions. A streaky RHEED pattern with an appearance of a weak ($2{\times}2$) reconstruction characteristic of Ga-polarity is observed all along the growth of subsequent GaN layer under optimized conditions. (Fig. (c)) The structural properties as well as dislocation densities as a function of growth conditions have been investigated using symmetrical and asymmetrical x-ray rocking curves. The electrical characteristics as a function of buffer and GaN layer growth conditions as well as the growth sequence will be also discussed. Figure: (a) RHEED pattern after oxide desorption (b) after 40 nm thick AlN growth using nitrogen rf plasma source and (c) after 600 nm thick GaN growth using ammonia source for (upper) [110] and (lower) [001] azimuth.

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Biological Nitrification and Denitrification for Landfill Leachate Containing High Concentration of Ammonium-Nitrogen by using MLE Process (MLE 공정을 이용한 고농도 NH4+-N 함유 침출수의 생물학적 질산화/탈질)

  • Won, Jong-Choul;Namkoong, Wan;Bae, Young-Shin;Lee, Kyung-Shin;Park, Ki-Hyuk;Song, Su-Sung;Yoon, Cho-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1027-1035
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    • 2000
  • This study was carried out to investigate the treatability of landfill leachate having high concentration of ammonium nitrogen with/without the circulation of media in pilot-scale($48m^3basis$) process. Total nitrogen removal efficiency was relatively increased in the media added process (influent ; $1.230{\sim}2,000mg{\cdot}l^{-1}$, effluent ; $120{\sim}250mg{\cdot}l^{-1}$) compared with the control process. The difference of nitrogen removal efficiency between these processes may be due to that stable growth of nitrifiers attached to the media could be achieved 99.3% of ammonium-nitrogen removal efficiency(without ; 98.2%) and 88.5% of total nitrogen removal efficiency(without ; 85.8%) were shown in media added process, respectively. Also, optimum BOD/ $NH_4{^+}$-N ratio was relatively decreased in the media process compared with the control process. Sludge settleability, on the other hand. was shown better in media added process than in control process. This outstanding sludge settleability in the media added process indicates the compatibility of media(zeolite) to the microorganism and the possibility of using media of biofilm process.

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Quality Properties of Commercial Chungkukjang in Korea (국내 시판 청국장의 품질 및 특성)

  • Ko, Yu-Jin;Son, Yong-Hwi;Kim, Eun-Ja;Seol, Hui-Gyeong;Lee, Gyeong-Ran;Kim, Dong-Hyeon;Ryu, Chung-Ho
    • Journal of agriculture & life science
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    • v.46 no.1
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    • pp.177-187
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    • 2012
  • This study aimed to improve the quality with acomparison of quality characteristics by collecting Chungkukjang in the market, and to establish the foundation data for starter, which support to manufacture standardized Chungkukjang products. Firstly, Chungkukjang was collected from the industrial company and home-made production which located in the several regions of Korea. Moisture contents of collected Chungkukjang were ranged from 56.3 to 62.1% and salinity was 0.23 to 11.51%. Total nitrogen and amino nitrogen contents of Chungkukjang ranged from 5.82 to 8.76% and 173.71 to 2,700.66 mg%, respectively. Nitrogen degradation ratio, which means the proportion of amino nitrogen to total nitrogen, was 2.88~26.93%. Collected Chungkukjang AG and Z have predominant value in histamine and tyramine contents as 755.40 and 1913.51 mg/kg, respectively, and viable cells count in collected Chungkukjang, maximum was $9.6{\times}10^9CFU/g$. As a result, most products showed various properties in flavor and nutrition, and it is supposed to be caused on use of different soybean species and unstandardized fermentation process.

Gas Exchange Ratio (R) Nomogram (가스 교환비(R)를 구하는 노모그람)

  • Whang, Ki-Jun
    • The Korean Journal of Physiology
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    • v.1 no.1
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    • pp.73-76
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    • 1967
  • A nomogram of gas exchange ratio (R) in air breathing subjects ,was porposed which enables a simple and rapid determination of R value using the fractional concentrations of nitrogen and carbon dioxide in the expired or alveolar gas. The readable limit of R value seems less than 1/100 of R unit and the average difference between the values from the nomogram and the actually calculated values is less than 0.005 of R unit. The usefulness of this nomogram for rapid and frequent determinations of the oxygen uptake is also suggested.

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Fuel Dilution Effects for Stratified Premixed Flames (성층화된 예혼합화염에 대한 희석제 첨가의 영향)

  • Ahn, Taekook;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.73-76
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    • 2013
  • The inert gas dilution effect for the stability of a stratified propane premixed flame has been experimentally studied. The addition of inert gases to a stratified premixed flame, which used to be very stable without dilution, makes a flame unstable. The lower equivalence ratio on the outer premixed flame and the lower fuel flow rate through the inner nozzle were observed to be the more stable conditions for the stratified premixed flame with nitrogen or argon dilution. It has been interpreted with the flame structure change such as shift of stoichiometric ratio region in a flame.

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Estimation of Amino-nitrogen Content in Salt-fermented Sand Lance Sauce (까나리액젓 중의 아미노태질소 측정)

  • Cho, Young-Je;Song, Min-Woo;Im, Yeong-Sun;Choi, Yeung-Joon
    • Journal of Fisheries and Marine Sciences Education
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    • v.12 no.2
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    • pp.213-223
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    • 2000
  • In order to establish the exact determination method of amino nitrogen in fish sauces, we compared the amino-nitrogen content in salt-fermented sand lance sauces according to the measuring methods and investigated influencing factors on the procedure of measuring. Amino-nitrogen content was increased in both sand lance sauce during fermentation periods and commercial sand lance sauces. Amino-nitrogen in fermented sand lance sauces for 12 months occupied 88.7% and 75.2% for the trinitrobenzene sulfonic acid(TNBS) method and the Copper-salt method, compare to the Formol method. The ratio of amino-nitrogen/total nitrogen in fermented sand lance sauce for 12 months was higher than in commercial sand lance sauces. The determination of amino-nitrogen by the TNBS method was influenced by concentration of salt in sand lance sauce. The amino-nitrogen content was the highest in the Formol method and followed by the TNBS method and the Copper-salt method without the influence of heating time and monosodium glutamate(MSG) concentration. We concluded that the determination of amino nitrogen in fish sauces was correct to measure with the TNBS method.

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An Assessment on the Behavior of Nitrogenous Materials during the First High-rate Phase in Composting Process (퇴비화 공정의 1차 발효단계에서 질소성 물질의 거동 평가)

  • Jeong, Yeon-Koo;Kim, Jin-Soo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.3
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    • pp.81-88
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    • 2000
  • Composting of N-rich wastes such as food waste and wastewater sludges can be associated loss of with substantial gaseous N, which means loss of an essential plant nutrient but may also lead to environmental pollution. We investigated the behavior of nitrogenous materials during the first high-rate phase in composting of food waste. Air dried food waste was mixed with shredded waste paper or wood chip and reacted in a bench scale composting reactor. Samples were analyzed for pH, ammonia, oxidized nitrogen and organic nitrogen. The volatilized ammonia nitrogen was also analyzed using sulfuric acid as an absorbent solution. Initial progress of composting reaction greatly influenced the ammonification of organic nitrogen. A well-balanced composting reaction with an addition of active compost as an inoculum resulted in the promoted mineralization of organic nitrogen and volatilization of ammonia. The prolongation of initial low pH period delayed the production of ammonia. It was also found that nitrogen loss was highly dependent on the air flow supplied. With an increase in input air flow, the loss of nitrogen as an ammonia also increased, resulted in substantial reduction of ammonia content in compost. The conversion ratio of initial nitrogen into ammonia was in the range of 28 to 38% and about 77~94% of the ammonia produced was escaped as a gas. Material balance on the nitrogenous materials was demonstrated to provide an information of importance on the behavior of nitrogen in composting reaction.

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