• Title/Summary/Keyword: nitrogen model

Search Result 908, Processing Time 0.029 seconds

Realistic pore structure of Portland cement paste: experimental study and numerical simulation

  • Ma, Hongyan;Li, Zongjin
    • Computers and Concrete
    • /
    • v.11 no.4
    • /
    • pp.317-336
    • /
    • 2013
  • In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.

Comparison of a Microbiological Model Simulation with Microcosm Data

  • Lee, Jae-Young;Tett, Paul;Jones, Ken
    • Journal of the korean society of oceanography
    • /
    • v.39 no.4
    • /
    • pp.222-233
    • /
    • 2004
  • Using nitrogen as the limiting nutrient, the default version of a microplankton-detritus model linked chlorophyll concentration to the autotroph nitrogen. However, phosphorus dynamics were added to simulate the results of a microcosm experiment. Using standard parameter values with a single value of microheterotroph fraction in the microplankton taken from the observed range, the best simulation successfully captured the main features of the time-courses of chlorophyll and particulate organic carbon, nitrogen and phosphorus, with root-mean-square error equivalent to 29% of particulate concentration. A standard version of microbiological model assumes complete internal cycling of nutrient elements; adding a term for ammonium and phosphate excretion by microheterotrophs did not significantly improve predictions. Relaxing the requirement for constant microheterotroph fraction resulted in an autotroph-heterotroph model AH, with dynamics resembling those of a Lotka-Volterra predator-prey system. AH fitted the microcosm data worse than did MP, justifying the suppression of Lotka-Volterra dynamics in MP. The paper concludes with a discussion of possible reasons for the success of the simple bulk dynamics of MP in simulating microplankton behaviour.

Modeling of Nonlinear SBR Process for Nitrogen Removal via GA-based Polynomial Neural Network (유전자 알고리즘 기반 다항식 뉴럴네트워크를 이용한 비선형 질소제거 SBR 공정의 모델링)

  • 김동원;박장현;이호식;박영환;박귀태
    • Journal of Institute of Control, Robotics and Systems
    • /
    • v.10 no.3
    • /
    • pp.280-285
    • /
    • 2004
  • This paper is concerned with the modeling and identification of sequencing batch reactor (SBR) via genetic algorithm based polynomial neural network (GA-based PNN). The model describes a biological SBR used in the wastewater treatment process fur nitrogen removal. A conventional polynomial neural network (PNN) is applied to construct a predictive model of SBR process fur nitrogen removal before. But the performances of PNN depend strongly on the number of input variables available to the model, the number of input variables and type (order) of the polynomials to each node. They must be fixed by the designer in advance before the architecture is constructed. So the trial and error method must go with heavy computation burden and low efficiency. To alleviate these problems, we propose GA-based PNN. The order of the polynomial, the number of input variables, and the optimum input variables are encoded as a chromosome and fitness of each chromosome is computed. Simulation results have shown that the complex SBR process can be modeled reasonably well by the present scheme with a much simpler structure compared with the conventional PNN model.

Simulation of Nitrogen Movement in the Rainfall Event at an Upland Agricultural Watershed (임야지에서 강우사상시 질소거동 모의에 관한 연구)

  • Kim, Sang-Hyeon;Kim, Geon-Mok
    • Journal of Korea Water Resources Association
    • /
    • v.34 no.5
    • /
    • pp.521-532
    • /
    • 2001
  • The propagation patterns of nitrogen during rainfall events are unsteady and heterogeneous due to the characteristics of generation and transport mechanisms. A simulation of non point source pollution was performed using GRASS-AGNPS to examine efficient management methods for diffusive pollution. Digital Elevation Model(DEM) was prepared to estimate the impact of topography on the transport pattern of diffusive pollutant Hanjaechon watershed on the Kyungbook province was selected as a study ares. Water quality samples were collected and analyzed for the calibration of the model. A heuristic approach was employed to improve the model performance. The model could successfully produce spatial distributions of nitrogen. The constructed map-layers may help to decision makers to determine the best management practices.

  • PDF

Nitrogen-Oxygen Separation Characteristics by Polyimide Membrane System for Controlled Atmosphere Storage (CA저장을 위한 폴리이미드 막 시스템의 질소-산소 분리특성)

  • 이호원;현명택;고정삼
    • Food Science and Preservation
    • /
    • v.5 no.3
    • /
    • pp.239-246
    • /
    • 1998
  • Polyimide membrane system was designed for manufacturing nitrogen-enriched gas, and basic technical data was suggested for appling this system to controlled atmosphere storage. The permeability characteristics of pure oxygen and nitrogen could be explained by dual-mode sorption model. There was substantial decrease in the permeation rates of oxygen, which is the more permeable gas, through the polyimide membrane due to the presence of nitrogen in comparison with pure oxygen. However, the permeation rates of nitrogen was increased by the presence of oxygen. The ideal separation factor was in the range of 5 to 6 in the range of temperature and pressure difference studied, and the separation factor of air was lower than the ideal separation factor. The increase of ideal separation factor with increasing temperature is due to the fact that the activation energy for oxygen is larger than that for nitrogen. Nitrogen concentration decreased rapidly with increasing product recovery, and it was found that this is a major operating factor to obtain nitrogen concentration required for controlled atmosphere storage. A relation equation, by which nitrogen concentration in storehouse can be predicted, was suggested under the establishment of a hypothetical model for controlled atmosphere storage process using polyimide membrane system.

  • PDF

Nitrogen Dynamics and Growing of Shrimp (Fenneropenaeus chinensis) in the High Density Aquaculture Ponds (고밀도 축제식 양식장의 질소역학과 대하 (Fenneropenaeus chinensis) 성장)

  • KANG Yun Ho;YOON Yang Ho
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.37 no.1
    • /
    • pp.24-32
    • /
    • 2004
  • A mathematical model is used to investigate nitrogen dynamics in the intensive aquaculture ponds in the western coast of Korea. Parameters associated with water quality, sediments and growing of shrimp (Fenneropenaeus chinensis) are measured to calibrate the model for feeding ponds A and B and storage ponds. The model describes the fate of nitrogen including loadings of ammonia from feeds, phytoplankton assimilation, nitrification, sedimentation, volatilization and discharge. The model obtains good agreements with the measured values of TAN $(NH_4,\;NH_3),\;NO(NO_2,\;NO_3)$ and Chl (chlorophyll a). Impacts of water exchange on TAN and Chl are investigated, showing that the range of 0.01-0.2 (/day) cannot effectively reduce TAN but reduces Chl. Nitrogen in the ponds A is removed by sedimentation $66\%,$ volatilization $8\%,$ discharge of particulate and dissolved $8\%.$ The pond B shows $56\%\;and\;26\%$ of sedimentation and volatilization, respectively, to yield $10\%.$ decrease and 8c/o increase compared to those in the pond A. While the pond A has larger area (1.02:0.66 ha) and same stocking density (0.025 md./L) at the beginning of culture, the pond B obtains higher stocking density (0.0065:0.0091 md./L), longer feeding period (103:121 day) and resultant higher shrimp production (1.15:2.13 t/ha/cycle) at harvest. This is possibly due to the hydraulic characteristics driven by paddlewheels. At low ratio of the low speed area and the pond area, the rate of sedimentation is high, while the rate of gas exchange is low. Thus, the measurement and model analysis suggest that water quality and shrimp production are positively correlated with the hydraulic characteristics in the shrimp ponds.

Adsorption of nitrate onto nitrogen-doped activated carbon fibers prepared by chemical vapor deposition

  • Yoo, Pyunghwa;Amano, Yoshimasa;Machida, Motoi
    • Korean Journal of Chemical Engineering
    • /
    • v.35 no.12
    • /
    • pp.2468-2473
    • /
    • 2018
  • Nitrogen-doped activated carbon fibers (ACFs) were prepared by chemical vapor deposition using melamine powder and acetonitrile for introducing quaternary nitrogen on the commercial ACFs, subsequently heated at $950^{\circ}C$ and activated by steam. Adsorption experiments of nitrate in aqueous solution were also conducted to evaluate adsorption capacity of the prepared ACFs using ion chromatography. The amount of introduced nitrogen content and nitrogen species on activated carbon fibers was examined by CHN elemental analyzer and X-ray photoelectron spectroscopy, respectively. As a result, adsorption capacity of quaternary nitrogen-doped ACF (ST-ML-AN-ST) was 0.75 mmol/g, indicating ca. two-times higher than that of untreated ACF (0.38 mmol/g). According to the adsorption data, the Langmuir isotherm model was the best fit. The prepared samples were also regenerated using hydrochloric acid. After regeneration, the adsorption capacity of the nitrogen-doped ACF (ST-ML-AN-ST) showed ca. 80% on average, implying that a portion of nitrates was adsorbed on the prepared ACFs irreversibly.

Development of Machine Learning Models Classifying Nitrogen Deficiency Based on Leaf Chemical Properties in Shiranuhi (Citrus unshiu × C. sinensis) (부지화 잎의 화학성분에 기반한 질소결핍 여부 구분 머신러닝 모델 개발)

  • Park, Won Pyo;Heo, Seong
    • Korean Journal of Plant Resources
    • /
    • v.35 no.2
    • /
    • pp.192-200
    • /
    • 2022
  • Nitrogen is the most essential macronutrient for the growth of fruit trees and is important factor determining the fruit yield. In order to produce high-quality fruits, it is necessary to supply the appropriate nitrogen fertilizer at the right time. For this, it is a prerequisite to accurately diagnose the nitrogen status of fruit trees. The fastest and most accurate way to determine the nitrogen deficiency of fruit trees is to measure the nitrogen concentration in leaves. However, it is not easy for citrus growers to measure nitrogen concentration through leaf analysis. In this study, several machine learning models were developed to classify the nitrogen deficiency based on the concentration measurement of mineral nutrients in the leaves of tangor Shiranuhi (Citrus unshiu × C. sinensis). The data analyzed from the leaves were increased to about 1,000 training dataset through the bootstrapping method and used to train the models. As a result of testing each model, gradient boosting model showed the best classification performance with an accuracy of 0.971.

Insulation Characteristics of the Model Cable for 22.9 kV Class HTS Power Cable

  • Kim, Hae-Jong;Seong, Ki-Chul;Cho, Jeon-Wook;Kwag, Dong-Soon;Cheon, Hyeon-Gweon;Kim, Sang-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.07a
    • /
    • pp.542-543
    • /
    • 2005
  • In this paper, describes the fabrication and dielectric insulation characteristics experimental results of the model cable for the 22.9kV class HTS power cable. The model cable were tested with partial discharge(PD), AC and impulse withstand voltage in liquid nitrogen($LN_2$) and liquid nitrogen pressure. In these test results, PD inception stress and AC, impulse breakdown strength increase as the pressure of the liquid nitrogen increases.

  • PDF

Determination of the Amino Acid Requirements and Optimum Dietary Amino Acid Pattern for Growing Chinese Taihe Silky Fowls in Early Stage

  • Li, Guanhong;Qu, Mingren;Zhu, Nianhua;Yan, Xianghua
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.16 no.12
    • /
    • pp.1782-1788
    • /
    • 2003
  • A mathematical model has been constructed to estimate the amino acid requirements for growing Taihe silky fowls in early stage. A requirement was taken as the sum of the needs for maintenance, for gain in carcass weight without feathers, and for the feathers. The maintenance requirement was considered to be the sum of the needs for replacing skin and intestinal losses and for the obligatory creatinine excretion in the urine. A comparative slaughter trial and nitrogen balance trials with growing and adult Taihe silky fowls, respectively, were conducted to estimate the parameters in the model. The amino acid requirements were then calculated with the constructed models. The results showed as following: the replacement needs for skin nitrogen loss was determined at 213.41 mg/d for adult male fowls (body weight 1.60 kg); creatinine excretion in these birds was 4.04 mg/d. when fed an nitrogen-free diets, the adult male fowls with body weight 1.60 kg excreted a total of 246.10 mg/d endogenous nitrogen. The net protein requirement for maintenance was estimated at $11.24mg/w_g{^{0.75}}/d$Per gram of body weight gain contained 27.18 mg carcass nitrogen for growing birds in early stage, but feathers nitrogen in per gram of body weight gain increased with age. The amino acid requirements for growing Taihe silky fowls were slightly higher than for starting and growing pullets, but lower than that of broiler chicks. The amino acid requirements patterns changed with weeks of age.