• Title/Summary/Keyword: nitrification process

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Comparison of Removal Characteristics of Organic Matter, Nitrogen and Phosphorus Between Suspended-Growth and Attached-Growth Biological Processes (부유 및 부착성장 미생물을 이용하는 공정의 유기물, 질소 및 인 제거 특성 비교)

  • Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.2
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    • pp.206-214
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    • 2005
  • This study was initiated to evaluate efficiencies of suspenced-growth processes(CAS; Conventional Activated Sludge, MLE; Modified Ludzack-Ettinger) and hybrid process(Modified-Dephanox) on removal of organic matter(C), nitrogen(N) and phosphorus(P) in municipal wastewater. M-Dephanox process was designed to improve the performance of Dephanox process on denitrification efficiency. As the results, removal efficiencies of total chemical oxygen demand(TCOD), total nitrogen(T-N) and total phosphorus(T-P) in M-Dephanox process, which is hybrid process, were 12,3, 18.6 and 28.2% higher than those in MLE, which is suspended-growth process. The better removal efficiencies of TCOD, T-N and T-P in M-Dephanox than those in MLE result that M-Dephanox is not only hybrid or multi-sludge process but also process using biosorption mechanism which is possible to use organics in denitrification, effectively. Ammonia removal efficiency in nitrification reactor of M-Dephanox was 96.7% at short hydraulic retention time(HRT) of 2 hr which was 3 hr more short HRT than that(HRT 5 hr) reported in other related papers. This indicates that M-Dephanox process can reduce HRT of whole process.

A Study on the Removal of Nitrogen and Phosphorus of Municipal Wastewater with Biological Coated Media (미생물 코팅 담체를 이용한 하수의 질소$\cdot$인 제거에 관한 연구)

  • Kim Young-Gyu;Cho Il-Hyoung
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.27-35
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    • 2006
  • This study was carried out to investigate the removal of nitrogen and phosphorus in municipal sewage depending on existence of biological coated media in BCM reactor. The reactor with biological coated media is the process combining $A_2/O$ process. The removal efficiencies for $COD_{Mn},\; BOD_5,\;SS$, T-N and T-P were $78\%,\;90.5\%,\;92.3\%,\;61.9\%,\;60.2\%$, respectively. The specific nitrification rate$(mgNO_3-N/gMLSS{\cdot}d)$ of Contact aeration basin was 52.2 and the specific denitrification rate$(mgNO_3N/gMLSS{\cdot}d)$ in anoxic basin was 95.1. Also, phosphorus release$(mgPO_4-P/gMLSS{\cdot}d)$ in Anaerobic basin was 71.8 and Phosphorus uptake$(mgPO_4-P/gMLSS{\cdot}d)$ in contact aeration was 27.1.

Effect of Loading Rate in the Operation of DEPHANOX and Modified-DEPHANOX Processes (유입부하가 DEPHANOX 및 Modified-DEPHANOX 공정에 미치는 영향)

  • Ryu, Hong-Duck;Min, Kyung-Kook;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.24-31
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    • 2004
  • This study was initiated to evaluate the efficiencies of DEPHANOX and Modified-DEPHANOX, which were devoloped to enhance nitrogen removal efficiency in municipal wastewater treatment. In the results, removal efficiency of organic matters was not affected much by increased loading rate of organic matters which is contained in influent. The nitrogen removal efficiencies according to the loading rate of influent TN was decreased drastically in conditions of over $0.2kg/m^3{\cdot}day$, which is T-N loading rate, and the DEPHANOX process was affected more sensitively than the M-DEPHANOX was. When the temperature was altered from $25^{\circ}C$ to $16^{\circ}C$ at HRT 6hrs, the removal efficiency of ammonia nitrogen was still over 90% and it was concluded that both DEPHANOX and M-DEPHANOX were strong enough to endure temperature variation. Moreover, both processes showed over 90% in ammonia removal efficiencies in over HRT 5hrs, so it was concluded that they were strong in HRT variation. M-DEPHANOX process showed a higher value than DEPHANOX did in T-N removal efficiency to the extent of 4~21 %, which resulted from differency of denitrification rates and the biosorption efficiency of organic matter in both processes. In the condition of HRT less than 4hrs, concentrations of ammonia nitrogen contained in effluents and nitrification reactors, might be sensitively affected by biosorption efficiency of organic matters in first separation tank. In the effect of effluent nitrate concentration in phosphorus removal, the more effluent nitrate concentration was decreased, the more phosphorus removal efficiency was increased. This result is related to the decrease of concentration of effluent nitrate which resulted from nitrification inhibition by decreased HRT.

GPS-X Based Modeling on the Process of Gang-byeon Sewage Treatment Plant and Design of Recycle Water Treatment Process (GPS-X 기반 모델링에 의한 강변사업소 처리효율 분석 및 반류수 처리 공정 설계)

  • Shin, Choon Hwan
    • Journal of Environmental Science International
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    • v.25 no.11
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    • pp.1493-1498
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    • 2016
  • The efficiencies of Gang-Byeon sewage treatment facilities, which are based on GPS-X modelling, were analysed and used to design recycle water treatment processes. The effluent of an aeration tank contained total kjeldahl nitrogen (TKN) of 1.8 mg/L with both C-1 and C-2 conditions, confirming that most ammonia nitrogen ($NH_3{^+}-N$) was converted to nitrate nitrogen ($NO_3{^-}-N$). The concentrations of $NH_3{^+}-N$ and $NO_3{^-}-N$ were found to be 222.5 and 227.2 mg/L, respectively, with C-1 conditions and 212.2 and 80.4 mg/L with C-2 conditions. Although C-2 conditions with higher organic matter yielded a slightly higher nitrogen removal efficiency, sufficient denitrification was not observed to meet the discharge standards. For the total nitrogen (T-N) removal efficiency, the final effluent concentrations of T-N were 293.8 mg/L with biochemical oxygen demand (BOD) of 2,500 mg/L, being about 1.5 times lower than that (445.3 mg/L) with BOD of 2,000 mg/L. Therefore, an external carbon source to increase the C/N ratio was required to get sufficient denitrification. During the winter period with temperature less than $10^{\circ}C$, the denitrification efficiency was dropped rapidly even with a high TKN concentration (1,500 mg/L). This indicates that unit reactors (anoxic/aerobic tanks) for winter need to be installed to increase the hydraulic retention time. Thus, to enhance nitrification and denitrification efficiencies, flexible operations with seasons are recommended for nitrification/anoxic/denitrification tanks.

Nutrient Removal Hybrid Process to Use Suspended and Attached Growth Microorganisms and Apply the Contact and Stabilization Process (부유 및 부착성장 미생물을 이용한 접촉안정형 영양염류처리 하이브리드 공정)

  • Kim, Man-Soo;Park, Jong-Woon;Lee, Sang-Ill;Park, Chul-Whi
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.4
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    • pp.452-459
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    • 2007
  • Nutrient removal hybrid process to use suspended and attached growth microorganisms and apply the contact and stabilization process was process obtaining good results to HRT within 6 hours to dominate nitrifier and to promote separation and growth of autotrophs and heterotrophs to pack with EPS(Expanded Poly-Styrene) media in nitrification reactor. An average effluent quality of this process was below 5.2 mg/L, 7.3 mg/L, 4.9 mg/L as $BOD_5,\;COD_{Mn}$, SS concentration and 6.8 mg/L, 0.6 mg/L as T-N, T-P concentration. Also, An average removal efficiency of this process was 94.6%, 79.8%, 94.9% as $BOD_5,\;COD_{Mn}$, SS and 70.8%, 76.9% as T-N, T-P. 16S-rRNA analysis result of microorganisms attached to EPS media was researched Nitrosomonas and Nitrosococcus blown to ammonia-oxidizing bacteria cluster to include Gallionella and these microorganisms were researched to involve about 6% of biofilm attached EPS media. Consequently, this process was treated below 10 mg/L and 1.0mg/L as T-N, T-P concentration at short hydraulic retention time(about 6 hr) to dominate nitrifier.

Evaluation of Affecting Factors on N and P removal in Biological SND (Simultaneous Nitrification and Denitrification) Process with NADH Sensor (NADH 센서를 이용한 생물학적 동시 탈질.질산화공정에서 질소, 인제거 영향인자 및 거동 평가)

  • Kim, Han-Lae;Lee, Si-Jin
    • Journal of Environmental Health Sciences
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    • v.34 no.5
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    • pp.374-381
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    • 2008
  • In this study, the factors affecting biological N and P removal using SND (simultaneous nitrification and denitrification) process were investigated and evaluated to examine the possibility of treating N and P through SND with NADH by surveying N and P traces in an aeration tank. Variations of $NH_4^+$-N+$NO_3^-$-N concentration were used to estimate the degree of SND in each point (P2, P3, P4, P5) of the aeration tank and these variations showed that denitrification efficiency in P2 (front zone), nitrification and denitrification efficiencies in P4 (middle zone) were 67%, 86% and 39%, respectively. When $PO_4^{-3}$-P concentration was analyzed in each point of the aeration tank, it was shown that $PO_4^{-3}$-P concentration coming into P2 was 1.25 mg/L, which increased to 2.22 mg/L by P release in P2 zone and then decreased to 0.74 mg/L by P uptake in P4. Consequently, we were able to estimate which high P removal efficiency observed in this study was caused by biological phosphorus removal. To determine the operating factors affecting effluent T-N, we analyzed the correlation among FN/M ratio, C/N ratio, Temp., SRT etc and these results showed that the correlation among FN/M ratio, C/N ratio and Temp was not high. However, the relationship of SRT and other parameters (effluent $NH_4^+$-N and effluent BOD) and the short SRT could have an affect on effluent $NH_4^+$-N and so effluent BOD could be increased. Thus, SRT operation should be controlled over 10 days. The results for analyzing the correlation between SRT and influent $NO_3^-$-N in order to investigate the operating factors affecting effluent T-P showed that T-P or $PO_4^{-3}$-P was not highly correlation with SRT, whereas $PO_4^{-3}$-P concentration increased along with increasing $NO_3^-$-N concentration into P2. Based on these results, we concluded, using regression analysis (R2=0.97), that effluent $PO_4^{-3}$-P concentration depends on $NO_3^-$-N concentration into P2.

The Influence of Some Soil-treated Herbicides on the Mineralization of Nitrogen Fertilizers II. In an upland soil (토양처리형 제초제가 질소비료의 무기화작용에 미치는 영향 II 밭 토양 조건)

  • Kim Moo Key
    • Korean journal of applied entomology
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    • v.16 no.3 s.32
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    • pp.149-154
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    • 1977
  • Effect of Simazine(2-chloro-4,6-bis (ethylamino)-s-triazine), Nitrofen (2, 4-dichloro-4' -nitrodi­phenylether), Propanil (:3, 4-dichloropropionanilide), and Butachlor (2-chloro-2, 6-diethyl N-(buthoxy­menthyl) acetanilide on urea hydrolysis and subsequent nitrification was investigated in an upland soil incubated at $20\pm1^{\circ}C$. 1. All the herbicides tested had no effect on the hydrolysis of urea to ammonia at the recommended rates. Butachlor, at ten and fifty times the recommended rate, and Nitrofen, at fifty times the recommeded rate, depressed urea hydrolysis, resulting in reduction of ammonia. But the depressive effects were temporary, disappearing soon. Simazine and Propanil had no detrimental effect on urea decomposition at all the treated rates. 2. Also, all the chemicals tested had no effect on the nitrification process at the recommended rates. At higher concentrations of ten and fifty times the recommended rate Butachlor and Nitrofen inhibited the oxidation of nitrite, and propanil long inhibited the oxidation of ammonium to nitrite, but was inactive against nitrite oxidizer. These inhibitive effects of the chemicals, however, disappeared in the later period of incubation. Simazine had no effect on the nitrification process at all the treated rates. 3. The trend of change in soil pH of both the treated and untreated plots well reflected the change of soil nitrogen forms during incubation. No direct effect of the chemicals on soil pH was obserbed.

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The experimental study for high ammonia nitrogen removal using Bardenpho process with Methanol addition (메탄올주입에 의한 Bardenpho공법에서의 고농도 암모니아성 질소 제거에 관한 실험적 연구)

  • Lee, Byonghi
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.2
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    • pp.34-40
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    • 1999
  • Aerobic night-soil treatment effluent containing high concentration of ammonia nitrogen was treated to remove nitrogen using Bardenpho process with Methanol addition. The objective of this study was to investigate the feasibility of complete nitrogen removal at three different HRTs such as 6.25d, 5d, and 3.75d, respectively. At each HRT, the nitrogen removal efficiencies are 92%, 99% and 97% and the required amount of methanol are 3.05gMeOH/gN, 2.75gMeOH/gN, and 3.38gMeOH/gN, respectively. Specific nitrification rates are decreased proportional to HRT and are $0.022gNH_4^+-N/g\;MLVSS{\cdot}day$, $0.0332gNH_4^+-N/g\;MLVSS{\cdot}day$ and $0.051gNH_4^+-N/g\;MLVSS{\cdot}day$ and specific denitification rate are decreased proportional to HRT and are $0.0210g\;N/gMLVSS{\cdot}day$, $0.0330g\;N/gMLVSS{\cdot}day$ and $0.0525g\;N/gMLVSS{\cdot}day$, respectively.

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Sewage Treatment using Moving Media Complete Mixing Activated Sludge/Solid Contact Process (회전매체를 가진 완전혼합 활성슬러지/Solid Contact 공법을 이용한 하수처리에 관한 연구)

  • 김홍태
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.35 no.4
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    • pp.67-75
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    • 1993
  • This study was carried out to investigate the applicability of Solid Contact Process for the improvement of Moving Media Complete Mixing Activated Sludge(MMCMAS) effluents. Laboratory MMCMAS Reactor and MMCMAS/Solid Contact were operated at the hydraulic loading of 122~340 L/m$^2$/d. The conclusions from this study were as follows ; The addition of Solid Contact tank to the MMCMAS reactor has increased the SCOD and SBOD removal efficiencies of 4 to 67% and 2 to 41%, respectively. In addition, the increments of nitrification rates were about 13 to 46%. It was also observed that the addition of Solid Contact tank has greatly increased the organic removal efficiencies at the higher hydraulic loading rates and also decrement of sludge production rates was 0.1 gVSS/gBODrem. It was therefore concluded that the addition of Solid Contact tank could have polished the effluent of MMCMAS at the higher hydraulic loading rates.

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Nitrogen Removal from ADEPT Effluent of Piggery Wastewater using Nitritation/Denitiritation System (ADEPT공정을 거친 돈사폐수의 아질산화-아탈질 공정을 이용한 질소제거)

  • Lee, Hwa-Sun;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.134-139
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    • 2006
  • Partial nitirification and denitrification process has been reported to be technically feasible and economically favorable, especially for wastewater treatment with high ammonium concentration or low Carbon/Nitrogen ratio. This research was performed to survey nitrite accumulation by nitritation in treating ADEPT effluent of piggery wastewater, which contains highly concentrated ammonia. To estimate the possibility of nitrite accumulation, DO concentration and SRT were investigated as key operational parameters. This result proved that nitritation to nitrite was steadily obtained under short sludge retention time. Oxygen limitation was proved to be just a subsidiary parameter. Energy efficiency of nitritation-denitritation process was higher than complete nitrification-denitrification because external carbon requirement for denitritation could be saved. Though the influent contained significant nonbiodegradable organic substrate, total nitrogen removal efficiency was more than 51% in nitritation-denitritation system.