• Title/Summary/Keyword: nitrate(${NO_3}^-$)

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Treatment of wastewater containing nitrate using upflow sludge blanket process (USB 공법에 의한 $NO_3^--N$ 함유 폐수처리)

  • Kim, Hyeong-Seok;Eun, Jong-Keug;Park, Seung-Cho
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.87-87
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

Treatment of wastewater containing nitrate using upflow sludge blanket process (USB 공법에 의한 $NO_3^--N$ 함유 폐수처리)

  • Kim, Hyeong-Seok;Eun, Jong-Keug;Park, Seung-Cho
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.239-247
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

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Geochemical Characteristics and Assesment of Nitrate Nitrogen in Groundwater in Yanggu-Gun, Gangwon-Do in Korea

  • Choi, Won Gyu
    • Journal of Soil and Groundwater Environment
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    • v.24 no.6
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    • pp.26-32
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    • 2019
  • An analysis of groundwater quality is significant for monitoring and managing water contamination and groundwater system. For the purpose of those, the geochemical characteristics of groundwater were studied over the concern for water quality, water type and origin of nitrate nitrogen. Total colony counts were detected in 11 out of 20 samples, and the average value was 31.73 CFU/ml. Range and average of NO3-N concentrations were 0.9~24.0 mg/L and 8.3 mg/L. All groundwater types were found to be Ca2+-HCO3-. The range and average of NO3-N were 0.2~17.4 mg/L and 8.7 mg/L, and those of δ15N were 1.7~8.9‰, and 5.0‰. Careful consideration is required for evaluating the origin of nitrogen when NO3-N concentration is low. In general, noticeable difference between rockbed and alluvial water was not found. The ranges of nitrate origins by chemical fertilizer, livestock manure and domestic sewage, and natural soil were 29.6~76.4%, 14.2~58.9% and 2.6~7.0%, and the average values of those were 57.4%, 37.4%, and 5.3%, respectively. Origin of nitrate was affected by more chemical fertilizer than the other parameters. Rockbed water was more affected by chemical fertilizer than alluvial water.

Effect of Alkali Metal Nitrates on the Ru/C-catalyzed Ring Hydrogenation of m-Xylylenediamine to 1,3-Cyclohexanebis(methylamine)

  • Kim, Young Jin;Lee, Jae Hyeok;Widyaya, Vania Tanda;Kim, Hoon Sik;Lee, Hyunjoo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1117-1120
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    • 2014
  • Ru/C-catalyzed hydrogenation of m-xylylene diamine into 1,3-cyclohexanebis(methylamine) was greatly accelerated by the presence of $LiNO_3$, $NaNO_2$, or $NaNO_3$. It was found that the effect of the nitrate salt was significantly affected by the size of cation. The promoting effect of the nitrate salt increased with the decrease of the cation size: $LiNO_3$ ~ $NaNO_2$ > $KNO_3$ > $CsNO_3$ >> [1-butyl-3-methylimidazolium]$NO_3$. XRD analysis of the recovered catalysts after the hydrogenation reactions showed that $LiNO_3$ and $NaNO_2$ were completely transformed into LiOH and NaOH, respectively, along with the evolution of $NH_3$, while $KNO_3$ and $CsNO_3$ remained unchanged.

Optimum Level of Nitrogen Fertilizer Based on Content of Nitrate Nitrogen for Growing Chinese Cabbage in Green House (시설조건(施設條件)의 배추 재배(栽培) 토양(土壤)에서 질산태질소(窒酸態窒素) 검정(檢定)에 의한 질소실비량(窒素施肥量) 결정(決定))

  • Park, Hyo-Taek;Hong, Soon-Dal
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.384-392
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    • 2000
  • To establish N fertilizer recommended scheme for the Chinese cabbage cultivation in green house based on the soil test of nitrate nitrogen, relationship among the content of soil nitrate and fertilizer effects and fertilizer N use efficiency were investigated from nine soils which differed amount of nitrate nitrogen from $14mg\;kg^{-1}$ to$226mg\;kg^{-1}$. The amount of nitrate nitrogen in soil showed a positive correlation with the dry weight of chinese cabbage in the plot of no fertilization. When the fertilizer effects were calculated by difference between the plots of fertilization and no fertilization in the dry weight and the amount of N uptake, a negative correlation was obtained between the amount of nitrate nitrogen in soils and the fertilizer effects. There was also a negative correlation between the amount of nitrate nitrogen in soils and fertilizer use efficiency. Recommendation of application rate of nitrogen fertilizer based on content of $NO_3-N$ in soils was evaluated by the regression equation among the content of soil nitrate, fertilizer effects and fertilizer N use efficiency. Incase the content of $NO_3-N$ nitrogen in soil is more than $200mg\;kg^{-1}$, No N fertilization is recommended; However, The standard N fertilization($320kg\;ha^{-1}$) is recommended for the soils with less than $50mg\;kg^{-1}$. For the soils ranged from $50mg\;kg^{-1}$ to $200mg\;kg^{-1}$ in the amount of nitrate nitrogen, an equation has been developed in order to calculate the recommended amount of fertilizer N.

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The removal of Nitrate-nitrogen from ground water by electrodialysis (전기투석을 이용한 지하수 중의 질산성질소 제거)

  • Min, Ji-Hee;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.307-314
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    • 2008
  • In this study, the effects of applied voltage, solution pH and coexistence of other ions such as sulfate ion (${SO_4}^{2-}$) and chloride ion ($Cl^-$) were investigated on the removal of nitrate-nitrogen ($NO_3{^-}-N$) from ground water by electrodialysis. The examined operating conditions were evaluated for optimizing the removal efficiency of $NO_3{^-}-N$. Real ground water samples taken from a rural area of Yongin city and artificial ones with components similar to the real ground water were tested for the study, which contained $NO_3{^-}-N$ concentration of 17mg/L that exceeds current drinking water quality standard of 10 mg/L. The increase in the removal rate of $NO_3{^-}-N$ was observed as the applied voltage increased from 5V to 30V, while no significant increase in the removal rate appeared at the applied voltage beyond 20V during a given operating time. The removal rate appeared to get lower at both acidic and basic condition, compared to neutral pH. Coexistence of of ${SO_4}^{2-}$and $Cl^-$ demanded much longer operating time to achieve a given removal rate or to meet a certain level of treated water concentration. When nitrate ion was combined with ${SO_4}^{2-}$and $Cl^-$, the removal rate was reduced by 4.29% and 10.83%, respectively.

Effects of $NO_3^-$ Gradients on Nitrogen Fixation, Nitrate Reduction and Ureide Content of Soybean (대두의 공소개정, 공산환원 및 Ureide함량에 미치는$NO_3^-$의 영향)

  • 추연식
    • Journal of Plant Biology
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    • v.30 no.3
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    • pp.205-213
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    • 1987
  • Soybean, inoculated with effective Rhizobium japonicum 110, were grown by sand culture with nutrient solution containing either of 0, 1, 3, 10 or 30mM NO3-/l, and analyzed growth characteristics, NR activity, N2-fixation activity, and changes of ureide contents during the growing period. The amount of nodule formation decreased abruptly by nitrate treatment, the maximum nodule dry weight was 1.59, 1.05, 0.78, 0.09 and 0.008 g plant-1, respectively for each treatment on the 98th day. Specfic activity of N2-fixation showed the maximum rates of 140, 101, 37, 5 and 2.2 nM dw.mg-1.hr-1, respectively for each treatment in the earlier growth period. The maximum acetylene reduction activity on the 98th day after sowing was 81.5, 35.3, 14.3, 0.1 and 0.0045 $\mu$M C2H4 plant-1.hr-1, respectively for 0, 1, 3, 10 and 30 mM of NO3- gradients. Nitrate reduction activity increased along with nitrate gradients, and decreased abruptly with age. Relative abundance of ureides in plant organs was high in reproductive growth, and showed the maximum value in fully symbiotic dependent plant. Relative abundance of ureides in stem is a useful indication for the evaluation of nitrogen fixation in nodules of symbiotic plant.

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Synthesis of Ni-YSZ cermets for SOFC by glycine nitrate process (Glycine nitrate process에 의한 SOFC용 Ni-YSZ cermets 제조)

  • Lee, Tae-Suk;Ko, Jung-Hoon;Kim, Bok-Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.6
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    • pp.289-294
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    • 2010
  • Ni-YSZ (Yttria Stabilized Zirconia) composite powders for SOFC were fabricated by glycine nitrate process. $ZrO(NO_3)_2{\cdot}2H_2O$, $Y(NO_3)_3{\cdot}6H_2O$, $Ni(NO_3)_2{\cdot}6H_2O$ and glycine were chosen as the starting materials. The structural properties of the sintered Ni-YSZ cermets have been investigated with respect to the volume contents of Ni. A porous microstructure consisting of homogeneously distributed Ni and YSZ phases together with well-connected grains was observed. The sintered Ni-YSZ cermets showed a porous microstructure consists of homogeneously distributed Ni and YSZ phases and the grains were well-connected. It was found that the open porosity is sensitive to the volume content of Ni. The Ni-YSZ cermet containing 35 vol% Ni seems to be suitable for the electrode material of SOFC since it provides sufficient open porosity higher than 30%.

Sequential Anoxic/Aerobic Biofilm Reactors and MF Membrane System for the Removal of Perchlorate and Nitrate (무산소/호기생물막반응조와 MF막의 연속처리에 의한 퍼클로레이트와 질산염 제거)

  • Choi, Hyeoksun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.5
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    • pp.301-306
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    • 2013
  • This research was conducted to investigate whether sequential anoxic/aerobic biofilm reactors and microfilteration (MF) membrane system can be used as a direct treatment for the removal of perchlorate and nitrate in groundwater. The biofilm process consisted of an anoxic first stage to remove perchlorate and nitrate and aerobic second stage to remove remaining acetate used as a carbon source for dissimilatory reduction of perchlorate and nitrate. In final stage, hollow fiber MF membrane was used to remove turbidity. In this research, perchlorate was reduced from the influent concentration of 102 ${\mu}/L$ to below the IC detection level (5 ${\mu}/L$) and nitrate was reduced from 61.8 mg/L (14 mg/L $NO_3$-N) to 4.4 mg/L (1 mg/L $NO_3$-N). Acetate used as a carbon source was consumed from 179 mg/L $CH_3COO-$ to 117 and 11 mg/L $CH_3COO^-$ in effluents from anoxic and aerobic biofilm reactors, respectively. Turbidity was reduced from 3.0 NTU to 1.5, 0.3, and 0.2 NTU in effluents from anoxic/aerobic biofilm reactors and MF membrane, respectively. It is expected that the sequential anoxic/aerobic biofilm reactors and MF membrane system can efficiently remove perchlorate and nitrate in surface water or groundwater.

Characterization of Nitrate Contamination and Hydrogeochemistry of Groundwater in an Agricultural Area of Northeastern Hongseong (홍성 북동부 농촌 지역 지하수의 질산성 질소 오염과 수리지구화학적 특성)

  • Ki, Min-Gyu;Koh, Dong-Chan;Yoon, Heesung;Kim, Hyun-Su
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.33-51
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    • 2013
  • Spatial and temporal characteristics of nitrate contamination and hydrogeochemical parameters were investigated for springs and surficial and bedrock groundwaters in northeastern part of Hongseong. Two field investigations were conducted at dry and wet seasons in 2011 for 120 sites including measurement of field parameters with chemical analyses of major dissolved constituents. Nitrate concentrations were at background levels in springs while 45% of bedrock groundwater and 49% of surficial groundwater exceeded the drinking water standard of nitrate (10 mg/L as $NO_3$-N). The difference in nitrate concentrations between surficial and bedrock groundwater was statistically insignificant. Cumulative frequency distribution of nitrate concentrations revealed two inflection points of 2 and 16 mg/L as $NO_3$-N. Correlation analysis of hydrogeochemical parameters showed that nitrate had higher correlations with Sr, Mg, Cl, Na, and Ca, in surficial groundwater in both dry and wet season. In contrast, nitrate had much weaker correlations with other hydrogeochemical parameters in bedrock groundwater compared to surficial groundwater and had significant correlations only in wet season. Temporally, nitrate and chloride concentrations decreased and dissolved oxygen (DO) increased from dry season to wet season, which indicates that increased recharge during the wet season affected groundwater quality. Aerobic conditions were predominant for both surficial and bedrock groundwater indicating low natural attenuation potential of nitrate in the aquifers of the study area.