The removal of Nitrate-nitrogen from ground water by electrodialysis

전기투석을 이용한 지하수 중의 질산성질소 제거

  • 민지희 (명지대학교 환경생명공학과) ;
  • 김한승 (명지대학교 환경생명공학과)
  • Received : 2008.03.04
  • Accepted : 2008.05.15
  • Published : 2008.06.15

Abstract

In this study, the effects of applied voltage, solution pH and coexistence of other ions such as sulfate ion (${SO_4}^{2-}$) and chloride ion ($Cl^-$) were investigated on the removal of nitrate-nitrogen ($NO_3{^-}-N$) from ground water by electrodialysis. The examined operating conditions were evaluated for optimizing the removal efficiency of $NO_3{^-}-N$. Real ground water samples taken from a rural area of Yongin city and artificial ones with components similar to the real ground water were tested for the study, which contained $NO_3{^-}-N$ concentration of 17mg/L that exceeds current drinking water quality standard of 10 mg/L. The increase in the removal rate of $NO_3{^-}-N$ was observed as the applied voltage increased from 5V to 30V, while no significant increase in the removal rate appeared at the applied voltage beyond 20V during a given operating time. The removal rate appeared to get lower at both acidic and basic condition, compared to neutral pH. Coexistence of of ${SO_4}^{2-}$and $Cl^-$ demanded much longer operating time to achieve a given removal rate or to meet a certain level of treated water concentration. When nitrate ion was combined with ${SO_4}^{2-}$and $Cl^-$, the removal rate was reduced by 4.29% and 10.83%, respectively.

Keywords

Acknowledgement

Supported by : 경기지역환경기술개발센터

References

  1. 김현정 (2005) "지하수 중 질산성질소의 연차적변화 및 분포특 성", 보건환경연구원보, 15권, p190-196
  2. 배병욱 (2000) "지하수 내 질산성질소 제거를 위한 이온교환공정의 적용", 대전대학교 산업기술연구소 논문집, 11(2), p149-159
  3. 심주현, 서형준, 서재희, 김대환 (2006) "이온교환과 전기투석 을 이용한 니켈회수의 비교연구", 대한환경공학회지, 28(6), p640-647
  4. 연경호, 문승현 (1999) "전기투석과 전기탈이온법에 의한 음용 수에서의 질산성질소 제거", 대한환경공학회지, 21(1), p87-99
  5. 이병철, 박재규 (2000) "전기투석에 의한 금속이온 분리에 관한 연구", 홍익대 산업기술, p643-650
  6. 장대익, 추광호, 김은수, 남미연, 안재희, 쟝리리, 정지현, 김학 석 (2006) "하수처리수 재이용을 위한 전기투석공정에서의 막 오염 현상 연구", 한국막학회 2006년 춘계 학술발표회, p89- 92
  7. 화학공업일보 (2000) "질산성질소제거 시스템개발", 해외과학 기술동향, 432호
  8. del Pino, M. P. and Durham, B (1999) "Wastewater reuse through dual-membrane processes: opportunities for sustainable water resources", Desalination, 124, p271-277 https://doi.org/10.1016/S0011-9164(99)00112-5
  9. Elmidaoui, A., Elhannouni, F., Menkouchi Sahli, M. A., Chay, L., Elabbassi, H., Hafsi, M. and Largeteau, D. (2001) "Pollution of nitrate in Moroccan ground water: removal by electrodialysis", Desalination, 136, p325-332 https://doi.org/10.1016/S0011-9164(01)00195-3
  10. Elmidaoui, A., Elhannouni, F., Taky, M., Chay, L., Menkouchi Sahli, M. A., Echihabi, L. and Hafsi, M. (2002) "Optimization of nitrate removal operation from ground water by electrodialysis", Separation and Purification Technology, 29, p235-244 https://doi.org/10.1016/S1383-5866(02)00092-8
  11. Eyal, A. and Kedem (1988) "Nitrate-selective anion exchange membrane", J. of membrane Sci., 38, p101-111 https://doi.org/10.1016/S0376-7388(00)80873-X
  12. Martin, C., Kartinen Jr., E. O. and Condon, J. (1995) "Examination of processes for multiple contaminant removal from groundwater", Desalination, 102, p35-45 https://doi.org/10.1016/0011-9164(95)00039-5
  13. Oldami, M., Killer, E. and Miguel, A. and Schock, G. (1992) "On the nitrate and monovalent cation selectivity of ion exchange membranes used in drinking water purification", J. of Membrane Sci., 75, p265-275 https://doi.org/10.1016/0376-7388(92)85068-T