• The Journal of the Korea Contents Association
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• v.18 no.5
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• pp.105-114
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• 2018

Ninhydrin traditionally used to develop fingerprints on paper is often limited in its use depending on background color and its enhancement effect differs depending on reagent reaction condition. Recently 1,2-indanedione(1,2-IND), etc. which has no limitation of background color has been used to visualize the fingermark on paper. Therefore, this study was carried out for enhancement of fingerprints after 1,2-IND/Zn treatment on paper treated with ninhydrin. Comparison between 1,2-IND/Zn reaction after ninhydrin treatment and single ninhydrin reaction were conducted under various methods. Result shows the fingerprints were enhanced when ninhydrin-treated fingerprints were treated with 1,2-IND/Zn, and their enhancement was observed even after 6 months.

• Analytical Science and Technology
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• v.20 no.4
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• pp.339-346
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• 2007

To search the ninhydrin derivatives that have high chromogenic and fluorogenic properties, molecular holographic quantitative structure property relationship (HQSPR) models on the reactivity between glycine and ninhydrin analogues as latent fingerprint detector were derived and investigated quantitatively. The ${\varepsilon}LUMO$ (e.v.) energy of ninhydrin molecule was an important factor to reactivity of ninhydrin. And, it is suggested that the nucleophilic reaction by orbital-controlled reaction from the frontier molecular orbital (FMO) interaction between glycine and ninhydrin derivatives was more superior than that of electrophilic reaction by charged controlled reaction. The analytical results in atomic contribution maps also shows that the reactivity of ninhydrin was increased by meta-substituents as strong electron withdrawing groups on the benzo ring. Therefore, it is sugested by HQSPR and QSPR model that the 5,6-dinitroninhydrin molecule would increase the reactivity as much as three times as compared to none substituted ninhydrin molecule.

• Journal of Sensor Science and Technology
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• v.31 no.6
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• pp.428-432
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• 2022

In this study, we describe the improvement of the resolution of a paper-based sensor by fabricating a high-concentration ninhydrin part using a low-temperature drying method to detect proline with high resolution. In the conventional paper-based sensor for detecting proline, the ninhydrin part is fabricated at room temperature, and in this process, the ninhydrin solution spreads around the ninhydrin part. Therefore, the concentration of the ninhydrin part becomes lower than that of the applied solution, lowering the resolution of the sensor. The proposed paper-based sensor better improved the sensitivity of the sensor compared to the existing sensor by fabricating a high-concentration ninhydrin part through drying the ninhydrin solution using a low-temperature drying method. Owing to the experiment, the intensity of the green color of the paper-based sensor with the integrated ninhydrin part fabricated at 10 ℃ is approximately 20% lower than the paper-based sensor with an integrated ninhydrin part fabricated at room temperature, indicating better sensor resolution. Therefore, the paper-based sensor with an integrated ninhydrin part fabricated at a high concentration could be useful for diagnosing drought.

• Journal of Microbiology and Biotechnology
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• v.11 no.2
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• pp.199-203
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• 2001

A simple quantitative method to measure the degree of silanization was developed, based on the reaction of ninhydrin with the silanization reagent (3-aminopropyltriethoxysilane, 3-APTES). At low concentrations (0.001-0.005%, v/v) of 3-APTES, a good linearity was obtained when 3-APTES reacted with undiluted ninhydrin for 30 min. On the other hand, at high levels of 3-APTES, a linearity was obtained when 3-APTES reacted with 3-fold diluted ninhydrin for 20 min. The reliability of regression curves mentioned above was expressed as a regression coefficient ($R^2$) of more than 0.99. Immobilization of different enzymes was introduced via silanization by using the 3-APTES in order to confirm the validity of the ninhydrin method. When yield for each step in the immobilizatio process were compared, yields of both glutaraldehyde and protein were founc to have the same tendency to silanization. These results shw that the ninhydrin method was suitable for quatitative analysis of silanization and that yields of immobilization could be pre-estimated by measuring silanization levels using the ninhydrin method.

• The Journal of the Korea Contents Association
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• v.16 no.9
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• pp.247-253
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• 2016

Some previous studies had proven that ninhydrin or its analogues are not effective in developing fingermarks on some types of paper. This study has evaluated the efficiency of four reagents for detecting latent fingermarks on six unusual paper surfaces. Among the six types of paper surfaces, none of the reagents worked on the newspaper. The 1,2-IND/Zn developed fingermarks on most of the surfaces tested.

• Journal of the Korea Convergence Society
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• v.11 no.6
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• pp.75-82
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• 2020

We identify the enhancement effects of zinc chloride and liquid nitrogen on low quality ninhydrin-developed fingerprint and we wanted to find out another cooling methods available for ninhydrin/Zn fingerprint enhancement besides the liquid nitrogen, which is hard to access. Artificial sweat was used to make the same level of fingerprints, and fingerprints developed by each technique were evaluated by SWGFAST standard and compared the average score and standard deviation. As a result of the experiment, ninhydrin/Zn-liquid nitrogen got 3.2 and 3.3 as average scores that enough to identify an individual such as 1,2-IND/Zn or DFO. Also, experiments using dry ice instead of liquid nitrogen as a way of the ninhydrin/Zn-developed fingerprints enhancement resulted in 3.0 and 2.9 as average scores, therefore, it was confirmed that dry ice is also a sufficient cooling method to be considered in practice in the field of forensic science.

• Bulletin of the Korean Chemical Society
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• v.24 no.4
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• pp.507-510
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• 2003

• Analytical Science and Technology
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• v.20 no.2
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• pp.155-163
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• 2007

Porosity paper evidence is encountered in case of forgery, kidnapping, fraud and terrorist activity. The present study was designed to evaluate the effect of three chemical reagents (Ninhydrin, 1,8-diazafluoren-9-one (DFO), Iodine fuming) to the quality of developed latent fingerprints on porosity printing papers and newspaper. In case of printing papers, print quality was better with Iodine fuming method than Ninhydrin and DFO treatment to developing latent fingerprints. Developing latent fingerprint on newspapers was achieved with Iodine fuming processing. The processing of Iodine fuming followed by DFO and by using blue light (orange red filter) exhibited better results with Iodine fuming. Enhancement of latent fingerprint detection image using Digital Imaging System was achieved.

• Korean Journal of Microbiology
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• v.23 no.4
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• pp.241-247
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• 1985

The objectives of this study were to isolate and identify ninhydrin positive substande(s) produced in the culture broth of Pseudomonas fluorescens. It was found that the NPS could stimulate bioconversion of furfural into furoic acid. In order to isolate the NPS from the culture broth, cell free filtrate was subjected to ion-exchange chromatography, gel-permeation and finally to cellulose column chromatography. The purified NPS was white amorphous power and very soluble in water, slightly soluble in methanol and very insoluble in organic solvents. UV, and IR absorption spectra. $^H$ and $^{13}C-NMR$ were measured in order to identify the chemical structure of the NPS.

• Bulletin of the Korean Chemical Society
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• v.25 no.4
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• pp.569-572
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• 2004