• Title/Summary/Keyword: newtonian flow

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Studies on The Flow Properties of Semi-Solid Dosage Forms (II) : Temperature-Dependent Flow Behavior of Vaseline (반고형제제의 유동특성에 관한 연구 (제2보) : 바셀린의 온도의존성 유동거동)

  • Kim, Jeong-Hwa;Song, Ki-Won;Jang, Gap-Shik;Lee, Jang-Oo;Lee, Chi-Ho
    • YAKHAK HOEJI
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    • v.41 no.1
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    • pp.38-47
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    • 1997
  • Using a concentric cylinder type, rheometer. the steady shear flow properties of vaseline were measured over the temperature range of 20~70${\circ}$C. In this paper, the shea rate and temperature dependencies of its flow behavior were investigated and the validity of some flow models was examined. In addition, the flow characteristics over a wide temperature range were quantitatively evaluated by calculating the various material parameters. Main findings obtained from this study can be summarized as follows: (1) At relatively lower temperature range, vaseline is a plastic fluid with a yield stress and its flow behavior shows shear-thinning characteristics. (2) As the temperature increases, the value of a yield stress and the degree of shear-thinning become smaller, consequently, the Newtonian flow behavior occurs at a lower shear rate range. (3) At temperature range lower than 45${\circ}$C, the flow behavior shows much stronger temperature dependence, and a larger activation energy is needed for flow. (4) The Herschel-Bulkley model is the most effective one g$^3$ to predict the flow behavior of vaseline having a yield stress. The validity of the Bingham and Casson models becomes more available with increasing temperature. The flow behavior of vaseline at temperature range higher than 45${\circ}$C can be perfectly described by the Newton model.

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The effects of drag reducing polymers on flow stability : Insights from the Taylor-Couette problem

  • Dutcher, Cari S.;Muller, Susan J.
    • Korea-Australia Rheology Journal
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    • v.21 no.4
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    • pp.213-223
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    • 2009
  • Taylor-Couette flow (i.e., flow between concentric, rotating cylinders) has long served as a paradigm for studies of hydrodynamic stability. For Newtonian fluids, the rich cascade of transitions from laminar, Couette flow to turbulent flow occurs through a set of well-characterized flow states (Taylor Vortex Flow, wavy Taylor vortices, modulated wavy vortices, etc.) that depend on the Reynolds numbers of both the inner and outer cylinders ($Re_i$ and $Re_o$). While extensive work has been done on (a) the effects of weak viscoelasticity on the first few transitions for $Re_o=0$ and (b) the effects of strong viscoelasticity in the limit of vanishing inertia ($Re_i$ and $Re_o$ both vanishing), the viscoelastic Taylor-Couette problem presents an enormous parameter space, much of which remains completely unexplored. Here we describe our recent experimental efforts to examine the effects of drag reducing polymers on the complete range of flow states observed in the Taylor-Couette problem. Of particular importance in the present work is 1) the rheological characterization of the test solutions via both shear and extensional (CaBER) rheometry, 2) the wide range of parameters examined, including $Re_i$, $Re_o$ and Elasticity number E1, and 3) the use of a consistent, conservative protocol for accessing flow states. We hope that by examining the stability changes for each flow state, we may gain insights into the importance of particular coherent structures in drag reduction, identify simple ways of screening new drag reducing additives, and improve our understanding of the mechanism of drag reduction.

Rheological Studies of Greases (潤滑油의 粘性學的 硏究)

  • Shao Mu Ma;Tai Kyu Ree
    • Journal of the Korean Chemical Society
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    • v.20 no.3
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    • pp.173-184
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    • 1976
  • A steel capillary viscometer was built for the study of rheological properties of greases. Bentone greases with thickener concentration of 2.0, 4.0, 6.0, 8.0, and 10.0 weight percent and lime-soap greases with soap concentrations of 2.4, 7.0, 9.3, 12.1 and 15.2 weight percent were studied. Capillaries with various radii R and lengths L were used to study the resident-time effect on the flow properties of lime soap greases. Detailed studies on bentone greases were conducted using a capillary with a fixed size. The results were analyzed by using Ree-Eyring flow equation. The factors appearing in the latter, ($X_1{\beta}_1/{\alpha}_1$ for Newtonian units, $X_2/{\alpha}_2$ and ${\beta}_2$ both for non-Newtonian units), were studied in order to investigate how they change with thickener concentrations and temperatures. Through this analysis, we have found that TEX>${\Delta}H_1^{\neq}$ and ${\Delta}H_2^{\neq}$, the activation enthalpies for flow of type-1 unit and of type-2 unit, respectively, are approximately equal to that of the base oil, the solvent. From this fact, it is concluded that these type units flow into the holes which were produced by the movement of solvent molecules. For bentone greases, the ${\beta}_2$ is about constant independent of concentration at a given temperature as found in the literature. The resident-time effect has not been clearly demonstrated in this research; this is due partly to the nature of the greases used in our research and partly to the small values of L/R of our capillaries, the resident time being proportional to the value L/R.

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Modeling on Rheological Behavior of Cement Paste under Squeeze Flow (압축 유동하에 있는 시멘트 페이스트의 유변학적 거동에 관한 모델링)

  • Min, Byeong-Hyeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.9
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    • pp.405-413
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    • 2020
  • The normal stress of cement paste measured under squeeze flow is divided into an elastic solid region at strains between 0.0003 and 0.003 and a strain-hardening region at strains of 0.003 and 0.8. A modeling equation at the strain-hardening region was proposed. First, from the viewpoint of fluid behavior, the power-law non-Newtonian fluid model, with a power-law consistency (m) of 700 and a power index (n) of 0.2, was applied. The results showed good agreement with the experimental results except for an elastic solid region. Second, from the viewpoint of ductile yielding solid behavior, the force balance model was applied, and the friction coefficient between the sensor part measuring the load and the surface of the cement paste was derived as a polynomial of the normal strain by applying the half-interval search method to the experimental data. The results showed good agreement with the experimental results only in the middle normal strain region at strains between 0.003 and 0.3. The rheological behavior of the cement paste under squeeze flow was more consistent with the experimental results from the viewpoint of power-law non-Newtonian fluid behavior than from the viewpoint of ductile yielding solid behavior in the strain-hardening region.

Self Diffusions and Rheological Properties of Polyamide Polymer Materials in Various Solvents (용매 환경에서의 폴리아미드 고분자 재료의 자체확산과 유변학적인 특성)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1050-1059
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    • 2019
  • The self diffusion, hole volume, and flow thermodynamic parameters of polyamide fibers were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. The stress relaxation of polyamide filament fibers were carried out in air and various solvents at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model. It was observed that the rheological parameters of these polyamide filament fibers are directly related to the relaxation spectra, self diffusion, viscosities, and activation energies of flow segments.

Three-Dimensional Flow Analysis for Compression Molding of Unidirectional Fiber-Reinforced Polymeric Composites with Slip Between Mold and Material (섬유강화 플라스틱 복합재의 압축성형에 있어서 이방성과 금형-재료계면의 미끄럼을 고려한 3차원 유한요소해석)

  • Yoon, Doo-Hyun;Jo, Seon-Hyung;Kim, E-Gon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.23 no.7 s.166
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    • pp.1075-1084
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    • 1999
  • The family of unidirectional continuous fiber reinforced polymeric composites are currently used in automotive bumper beams and load floors. The material properties and mechanical characteristics of the compression molded parts are determined by the curing behavior, fiber orientation and formation of knit lines, which are in turn determined by the mold filling parameters. In this paper, a new model is presented which can be used to predict the 3-dimensional flow under consideration of the slip of mold-composites and anisotropic viscosity of composites during compression molding of unidirectional fiber reinforced thermoplastics for isothermal state. The composites is treated as an incompressible Newtonian fluid. The effects of longitudinal/transverse viscosity ratio A and slip parameter $\alpha$ on the buldging phenomenon and mold filling patterns are also discussed.

Numerical analysis of internal flow and mixing performance in polymer extruder II: twin screw element

  • Kim, Nak-Soo;Kim, Hong-Bum;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.18 no.3
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    • pp.153-160
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    • 2006
  • We analyzed the non-Newtonian and non-isothermal flow with Carreau-Yasuda viscosity model in co-rotating and counter-rotating twin screw extruder systems. The mixing performances with respect to the screw speed, the screw pitch, and the rotating direction have been investigated. The dynamics of mixing was studied numerically by tracking the motions of particles. The extent of mixing was characterized in terms of the deformation rate, the residence time distribution, and the average strain. The results showed that the high screw speed decreases the residence time but increases the deformation rate. Small screw pitch increases the residence time. It is concluded that the high screw speed increases the dispersive mixing performance, while the small screw pitch increases the distributive mixing performance. Co-rotating screw extruder has the better conveying performance and the distributive mixing performance than counter-rotating screw extruder with the same screw speed and pitch. Co-rotating screw extruder developed faster transport velocity and it is advantageous the flow characteristics to the mixing that transfers polymer melt from one barrel to the other barrel.

Small and Large Deformation Rheological Behaviors of Commercial Hot Pepper-Soybean Pastes

  • Choi, Su-Jin;Kang, Kyoung-Mo;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.15 no.6
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    • pp.871-876
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    • 2006
  • Rheological behavior of commercial hot pepper-soybean paste (HPSP) was evaluated in small amplitude oscillatory and steady shear tests. Storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) as a function of angular frequency (${\omega}$), and shear stress (${\sigma}$) as a function of shear rate (${\gamma}$) data were obtained for 5 commercial HPSP samples. HPSP samples at $25^{\circ}C$ exhibited a non-Newtonian, shear-thinning flow behavior with high yield stresses and their flow behaviors were described by power law, Casson, and Herschel-Bulkley models. Time-dependent flow properties were also described by the Weltman, Hahn, and Figoni & Shoemaker models. Apparent viscosity over the temperature range of $5-35^{\circ}C$ obeyed the Arrhenius temperature relationship with activation energies (Ea) ranging 18.3-20.1 kJ/mol. Magnitudes of G' and G" increased with an increase in ${\omega}$, while ${\eta}^*$ decreased. G' values were higher than G" over the most of the frequency range (0.63-63 rad/sec), showing that they were frequency dependent. Steady shear viscosity and complex viscosity of the commercial HPSP did not fit the Cox-Merz rule.

A Total Shape Factor for Determining Three-Dimensional Screw Characteristics of Extrusion Process (압출공정 스크류특성 결정을 위한 전체 형상계수)

  • 김시조;권태헌
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2533-2542
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    • 1994
  • This paper suggests a simple approach to determining the screw characteristics for a three0dimensional flow in a channel with a finite aspect ratio(ratio of a width to a depth, W/H) by introducing a Total Shape Factor($F_t$) to correct a two-dimensional flow analysis for a channel with an infinite aspect ratio. In the present study, the Total Shape Factor($F_t$) was defined as a ratio of a net flow rate obtained by the three-dimensional analysis to that by the two-dimensional analysis. In the proposed approach, the quantity, $ \frac{{\partial}F_t}{\partial(H/W)}$ turns out to be almost constant and to play an important role in understanding the effects of the flights. Therefore, $ \frac{{\partial}F_t}{\partial(H/W)}$ are extensively reported in this paper in terms of several dimensionless parameters. This simple approach with such database will be very useful for extruder designers to predict the screw characteristics.

3-D Flow Analysis for Compression Molding of Fiber-Reinforced Polymeric Composites with Ratio of Extensional & Shear Viscosity (인장 및 전단점성비를 고려한 섬유강화 플라스틱 복합재의 압축성형에 있어서 3차원 유한요소해석)

  • 조선형;윤두현;김형철;김이곤
    • Composites Research
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    • v.12 no.1
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    • pp.11-18
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    • 1999
  • The compression molding is widely used in the automotive industry to produce products that are large, thin, lightweight and stiff. The molded product is formed by squeezing a fiber-reinforced plastic composites. During a molding process of fiber reinforced thermoplastic composites, control of filling patterns in mold, orientation and distribution of fibers are needed to predict the effects of molding parameters on the flow characteristics. It is the objective of this paper to develop an isothermal compression molding simulation that can handle both thin and thick charges and motion of the flow front, and can predict pressure distributions and accurate velocity gradients. The composites are treated as an incompressible Newtonian fluid. The effects of slip parameter $\alpha$ and extensional/shear viscosity ratio $\zeta$ on the mold filling parameters are also discussed.

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