• 한국가구학회지
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• 제26권1호
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• pp.22-30
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• 2015

In order to prevent decay, distortion, bending, twist on wood products such as wooden furnitures, variety of coating materials were developed and used so far. The coating materials for wood finishing can be synthesized by natural resource or petroleum. However, these coating materials can cause contamination of indoor air quality due to emission of volatile organic compounds (VOCs). In this study, commercialized coating materials for wood finishing such as varnish, coat, and stain were evaluated on emission characteristics of VOCs. Among the varnish, eco-friendly products had about 15~46% lower TVOC emission ($1,042{\mu}g/m^2h{\sim}3,257{\mu}g/m^2h$, respectively, than typical product ($7,100{\mu}g/m^2h$). Natural resource based coating material showed lowest TVOC emission level. However, one of natural resource based waterborne stain showed higher TVOC emission level because waterborne stain already contained higher amount of natural VOC. Oil-based stain might not be suitable for indoor use on interior wall and furniture due to exceed amount of TVOC. Based on results, natural resource based coat or waterborne stain are recommenced to use on wood products.

• Journal of the Korean Wood Science and Technology
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• 제26권3호
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• pp.73-80
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• 1998

In order to reconstruct the traditional technology of Korean golden varnish coatings, this study was carried out to separate and determine some main coloring components of the exudates of D. morbifera and its traditionally refined golden varnishes using a process of solvent extractions, chromatographies and spectrometries. The results obtained are as follows: 1. The exudate and its traditional-refined golden varnishes appear to have a kind of natural polyacetylenes because it has some triple bond peaks in FT-IR spectrometry. 2. Some yellowing spots of the polar-solvent extrats from the exudates and refined varnishes separated on TLC appeared under natural drying condition, but those of non-polar solvent extract such as hexane did not. 3. A traditional refining method for reconstructing a Korea golden varnishes was thought to be better than solvent separation because the former had higher triple-bond peaks than the latter in FT-IR spectrometry. 4. One of main conponents in the hexane-extracts of the traditional-refined varnishes and the exudates had the same molcular weighr of 204, but the fragmentation patterns was a little different between the exudate and the refined. in LC-MS soectrometry.

• Journal of the Korean Wood Science and Technology
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• 제49권5호
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• pp.471-481
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• 2021

This study investigated the hygroscopicity and UV deterioration characteristics of 3 domestic and 4 imported woods using natural oil, stain, and varnish paints. In terms of hygroscopicity, it was found that the hygroscopicity of the painted wood was lower than that of the unpainted wood, and that as the number of coatings increased, the hygroscopicity decreased. In terms of anti-absorption, oil-based chemical paints showed higher resistance than water-based paints, and natural oils showed results comparable to oil-based paints. As for the UV deterioration, the amount of color change of the painted wood was lower than that of the unpainted wood, and there was no significant difference according to the number of times of painting. The amount of color change was found to be low in oil-based paints and hardwoods. Through this study, we confirmed effective moisture blocking and small color changes during painting using paints, and it is believed that wood can be protected from internal and external defects through selective and efficient painting based on data for excellent painting performance.

• 대한치과보철학회지
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• 제32권2호
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• pp.181-194
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• 1994

The purpose of this study was to compare the retention and fitness of crown treated with various desensitizing agents on natural teeth. Varnish, dentin primer, bonding agent and potassium oxalate treated groups and control group with no treatment were used. The retention test was executed with the Instron test machine(Instron Co.,U.S.A.) on 24 hours after cementation with zinc phosphate cement. After retention test, the teeth and crowns were washed and recemented. The cemented crowns were embedded in clear resin and sectioned with a diamond saw. The occlusal and marginal fitnesses, were measured indirectly with a stereomicroscopic photographs. The result of this study were obtained as follows : 1. The retention of control group was higher than any other desensitizing agent treated group. 2. The differences of retention among varnish, dentin primer, bonding agent and potassium oxalate treated groups were not statistically significant. 3. There were no statistically significant difference in fitness at occlusal surface and margin among control, varnish, dentin primer, bonding agent and potassium oxalate treated groups. According to these results, desensitizing agents used to protect the pulp from irritation of luting agents may adversely affect the retention of castings. Therefore, desensitizing agents should be used in limited areas carefully.

• Restorative Dentistry and Endodontics
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• 제19권1호
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• pp.124-134
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• 1994

The shade of restorative materials is very important for successful restoration esthetically harmonized with the natural tooth. The purpose of this study was to evaluate the color stability and the opacity change of conventional chemical setting and visible light curing glass-ionomer cements for restorative esthetic filling. Specimens of each brand (GC Fuji II and Fuji II LC) were uniformly prepared and divided into three groups: In group l(control group), the specimens received no surface treatment; in group 2, the specimens were coated with varnish and the excess gently blown off; and in group 3. the specimens were coated with light-cured bonding resin and irradiated by a visible light curing unit for 20 seconds on both sides. All specimens were stored in distilled water at $37^{\circ}C$ and checked after for 24 hours. 2 months. 4 months, 6 months. and 8 months. The color characteristics($L^*,\;a^*,\;b^*$) and the opacity(Y%) of all the samples were measured by a spectrocolorimeter and the total color differences(${\Delta}E^*$) and opacity changes(${\Delta}Y%$) were computed. The following results were obtained : 1. The total tolor differences in all groups increased with time. 2. The total color differences of the LC groups after immersion for 8 months in distilled water at $37^{\circ}C$ were lower than those of GC groups(p<0.01), and the total color differences of the varnish or the light-cured bonding resin coated groups were lower than those of the control group with glass-ionomer cements which had no surface treatment(p<0.01). 3. In all groups the translucency decreased with time. 4. In the control group and the varnish coating group. the opacity changes of the GC groups were lower than those of the LC groups(p<0.01) and in the light-cured bonding resin coated group, there was no significant difference between the GC group and the LC group. 5. The opacity changes of the varnish or the light-cured bonding resin coated groups were lower than those of the control group(p<0.01). These results suggest that color change and opacity of conventional chemical setting and light cured glass-ionomer cement were increased with time, and the color changes and the opacity changes of a control group after immersion for 8 months in distilled water at $37^{\circ}C$ were greater than those of the varnish or the light-cured bonding resin coated groups.

• 한국가구학회지
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• 제27권4호
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• pp.335-342
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• 2016

In previous study, volatile organic compounds (VOCs) emission characteristics were highly affected by coating materials for wood finishing. Natural based coating materials showed that about 15~46% lower TVOC emission than typical products. In this study, long-term changes of VOCs emission characteristics from pine panel with three types of coating treatments were determined. Non-treated pine panel emitted $604.7{\mu}g/m^2{\cdot}h$ of TVOC that contained 66% of NVOC ($399.7{\mu}g/m^2{\cdot}h$) at 0 month. After 10 month, TVOC reduced 88% and 93% reduction on NVOC was observed. Natural oil and waterborne stain treated pine panel showed 61% and 77% lower TVOC, respectively, than non-treated pine panel. However, TVOC from finished pine panels showed higher TVOC emission than non-treated pine panel. All samples satisfied the VOC emission regulation (below $4,000{\mu}g/m^2{\cdot}h$) by Korean Ministry of Environment. Toluene emission regulation (below $80{\mu}g/m^2{\cdot}h$) was passed on all sample without varnish treated pine panel at 0 month. According to HB qualification standard for construction materials by Korea Air Cleaning Association (KACA), wood is not qualified to get the best tag due to high TVOC emission. At the 10 months, only non-treated pine panel could get the best tag of HB from KACA.

• 한국산림과학회지
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• 제87권2호
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• pp.253-259
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• 1998

황칠나무 천연분포지에서 미생물의 감염으로 황칠의 분비가 촉진되는 것이 발견되었다. 황칠이 다량 분비되는 황칠나무의 상처 조직을 채취하여 배양한 결과 Sb1, Sb2, Sb3, Sb4의 4개의 균주가 분리되었으며, 황칠 분비 촉진에 관여하는 균주는 Sb3, Sb4의 2개의 균주였고 그중 Sb4 균주가 가장 우수한 균주로 선발되었다. Sb4 균주를 황칠나무에 접종한 결과 일반적인 칠액 채취 방법인 일(一)형처리 보다 흉고직경에 따라 3.4~7.7 배의 황칠 분비가 촉진되었다. Sb4 균주의 특성은 색깔이 회백색이고 균사가 구름모양의 둥근막을 형성하여 돌기를 이루며 생장하고 생장에 대한 온도의 영향은 $20^{\circ}C$ 이하에서는 거의 생장이 되지 않았고 $40^{\circ}C$ 이상에서는 생장이 급격히 떨어졌으며, 생장 최적 온도는 $30{\sim}35^{\circ}C$이었다. 생장 최적 pH는 6.5~7.0으로 나타났고 pH 5 이하와 pH 9 이상에서는 거의 생장하지 못하였다.

• Journal of the Korean Wood Science and Technology
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• 제38권4호
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• pp.333-340
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• 2010

한반도 남부 일대에서 자생하는 황칠나무(Dendropanax morbifera Lev.) 수액으로부터 추출한 천연 도료인 황칠도료(Korean Dendropanax lacquer)는 예로부터 귀중한 예술품이나 투구, 화살, 활 등의 전쟁도구를 찬란한 황금색으로 도장하는데 사용되어 왔다. 경화 후 황금색의 투명한 도막을 형성하여 우수한 색상특성을 지니고 있을 뿐만 아니라 내후성, 내수성, 내식성 등이 우수하여, 보호도장으로써도 훌륭한 가치를 지니고 있다. 그러나 이러한 많은 장점에도 불구하고, 현대적인 여러 적용분야에 사용되지 못하고 있는 이유는 황칠도료의 생산량이 적고, 이로 인하여 가격이 매우 고가이고, 장시간의 경화시간이 소요되는 문제도 큰 원인으로 작용하고 있다. 한편 황칠 내에 광중합이 가능한 conjugated diene을 포함한 모노머가 있으며, 이러한 모노머는 일광 조사 조건등에 의하여 짧은 시간에 단단하고 황금색을 띠는 도막을 형성할 수 있음이 보고된 바가 있다. 따라서 본 연구에 서는 전통적인 황칠도료의 경화방법을 개선하고 경화속도를 촉진하기 위하여, 열개시제를 도입하여 열경화를 촉진하는 방법과 열개시제 및 광개시제를 동시에 도입하고 이중경화(dual curing)에 의해서 경화속도를 촉진하고자 하였다. 이러한 경화 속도 및 경화 거동은 적외선분광분석기(FT-IR)을 이용하여 -C=C- 이중결합 특성피크의 변화를 관찰하거나, 진자경도계(pendulum hardness tester)를 이용하여 표면 경도의 변화를 관찰함으로써 평가하였다. 또한 강체진자물성측정기(RPT)에 spot UV curing 장비를 도입하여 이중경화에 의한 경화 속도 진을 평가하였다. 본 연구의 결과 열개시제에 의하여 열경화가 촉진될 수 있을 뿐만 아니라, 이중경화에 의하여 경화속도를 향상시킬 수 있음을 확인하였다. 또한 이러한 황칠도료 경화 속도 촉진 방법을 활용하여 전통적인 역에만 사용되어온 황칠도료를 현대적인 여러 적용분야에도 확대하여 사용할 수 있는 가능성을 제시하였다.

• Journal of the Korean Wood Science and Technology
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• 제34권2호
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• pp.58-67
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• 2006

The relationship between acoustic property and coating hardness of musical instruments was investigated using a sound level meter and a pendulum hardness tester. Urethane topcoat, oil stain, natural oil varnish, and UV-curable epoxy acrylate coatings were applied on four different substrates: Paulownia coreana, Pinus koraiensis, Castanea crenata var. dulcis and Pinus densiflora. The influence of the coating type on the acoustic properties was stronger than that of the substrate. In the case of an oil stain formed with tacky coating layer, the sound pressure level (SPL) and surface hardness decreased with increasing of coating thickness. In the other coatings, SPL decreased and hardness increased as the coating layer thickened. However, SPL began to increase again at coating thickness above $100{\mu}m$.

• 대한소아치과학회지
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• 제37권1호
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• pp.35-43
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• 2010

본 연구는 젤라틴과 메틸셀룰로오스를 기저재로 한 불소겔을 제작하고 이들의 높은 점조도와 표면에 흡착하는 능력이 치면에 불소를 오랜 시간 저류시켜 법랑질 탈회를 효과적으로 억제할 수 있는지 살펴보고자 시행되었다소의 전치로 시편 80개를 제작하였으며, (1) APF gel (2) $CavityShield^{TM}$, (3) Gelatin F gel (4) Methyl cellulose F gel 이렇게 4개의 군으로 분류하였다. 모든 시편을 인공우식용액에 72시간동안 보관하여 법랑질을 탈회시킨 후, 표면미세경도 측정법과 편광 현미경하에서 병소의 탈회 깊이를 측정하는 두 가지 방법을 사용하여 탈회정도를 측정하였다. 연구결과는 다음과 같다. 1) 불소를 처리한 experimental side와 처리하지 않은 control side간 미세경도의 차이는 APF를 적용한 제1군에서 71.82(VHN)로 가장 작은 것으로 나타났다(p<0.05). 2) $CavityShield^{TM}$를 도포한 제2군에서 148.24(VHN)로 가장 큰 차이를 보여 불소바니쉬의 탈회억제효과가 가장 큰 것으로 나타났다(p<0.05). 3) Gelatin과 methyl cellulose F gel을 도포한 3군과 4군에서 control side와 experimental side간 미세경도의 차이는 1군보다는 높고 2군보다는 낮았으나 3군과 4군간에 유의한 차이는 없었다(p>0.05). 4) 인공탈회병소의 깊이를 측정한 결과 APF를 처리한 제1군에서 control side와 experimental side간 병소의 깊이차이는 $16.69\;{\mu}m$로 가장 적게 나타났다(p<0.05). 5) 2,3,4군 에서는 병소깊이 측정을 통해 탈회억제효과가 APF군에 비해 우수하게 나타났으나(p<0.05) 각 군 간에 차이는 검증되지 않았다(p>0.05). 이상의 결과를 종합하여 보면 실험적으로 제조된 두 가지 불소겔은 APF gel에 비해 법랑질 탈회 억제효과가 우수하다고할 수 있으며 이는 APF gel에 비해 gelatin이나 methyl cellulose 의 높은 점조도가 불소를 더 장시간 치면에 접촉시킨 것으로 생각된다. 현재 가장 우수한 치면 잔류시간을 보이는 것으로 인정되는 불소바니쉬와 비교하여도 이들의 효과가 크게 떨어지지 않는 것을 알 수 있었으며 이는 향후 천연고분자 화합물을 이용한 다양한 불소제제의 개발 가능성을 보여주는 것이라 사료된다.