• Title/Summary/Keyword: natural adhesives

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Utilization of Pyrolysis Oil from Pine Wood as Thermosetting Wood Adhesive Resins

  • Kim, Jae-Woo;Myers, Deland J.;Brown, Robert C.;Kuo, Monlin
    • Journal of the Korean Wood Science and Technology
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    • 제35권2호
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    • pp.51-60
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    • 2007
  • In this study, the possibility of using pyrolysis oil as wood adhesives was explored. Especially, adhesives were formulated by reacting pyrolysis oil and formaldehyde and also partially replacing phenol with pyrolysis oil in phenol-formaldehyde (PF) adhesive and soy hydrolizate/PF adhesive formulation. The pine wood was fast pyrolyized and the oils were obtained from a series of condensers in the pyrolysis system. The oils from each condenser were first reacted with formaldehyde to explore potential use of the oil itself as adhesive. The lap-shear bond strength test results indicated that the oil itself could be polymerized and form bonds between wood adherends. The oils from each condenser were then mixed together and used as partial replacement of phenol (25, 33, and 50% by weight) in phenol-formaldehyde adhesive. The bond strength of the oil containing PF adhesives was decreased as percent phenol replacement level increased. However, no significant difference was found between 25 and 33% of phenol replacement level. The oil-contained PF resins at 25, 33, and 50% phenol replacement level with different NaOH/Phenol (Pyrolysis oil) molar ratio were further formulated with soy hydrolizate to make soy hydrolizate/pyrolysis oil-phenol formaldehyde adhesive at 6:4 weight (wt) ratio and used for fiberboard manufacturing. Surface internal bond strength (IB) of the boards bonded with 33% replacement at 0.3 NaOH/Phenol (Pyrolysis oil) molar ratio performed better than other replacement levels and molar ratios. Thickness swelling after 24 hr cold water soaking and after 2 hr in boiling water was increased as % replacement of pyrolysis oil increased.

도마뱀 인공섬모 구조물의 접착 특성에 금속코팅이 미치는 영향 (Effects of Metal Coatings on Adhesive Characteristics of Gecko-like Micro Structures)

  • 김규혜;안태창;황희윤
    • 대한기계학회논문집A
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    • 제39권11호
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    • pp.1099-1103
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    • 2015
  • 자연계에 존재하는 다양한 생명체 중 몇몇은 벽이나 천장을 자유자재로 걸어다닌다. 이러한 생명체 중 대표적으로 Gecko는 발가락 표피에 수십억개의 주걱모양의 나노헤어를 가지고 있으며, 이러한 구조로 인하여 높은 접착력을 가진다. 본 연구에서는, 도마뱀 발바닥 섬모와 같은 미세 마이크로 구조물에 금속코팅을 하여 접착특성을 향상시키는 것을 제안한다. 도마뱀 모방 인공섬모 구조물을 DRIE공법으로 준비된 몰드를 이용하여 PDMS로 제조하였다. 그리고, 인공섬모의 금속 코팅은 플라즈마 스퍼터링을 사용하여 수행하였다. 접착력과 내구성은 실험을 유리에 반복 접착 실험으로 평가 하였다. 접착성 및 내구성 실험을 통하여 인공섬모 구조물에 금속코팅이 미치는 영향에 대해 관찰하였다.

합판 접착제의 첨가제로서 폴리에틸렌의 이용 (Use of Polyethylene as an Additive in Plywood Adhesive)

  • 오용성
    • Journal of the Korean Wood Science and Technology
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    • 제26권1호
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    • pp.14-18
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    • 1998
  • A low density polyethylene(LDPE) was examined as an additive in phenol-formaldehyde(PF) resin adhesive for bonding radiata pine plywood. The LDPE was supplied by the commercial manufacturer. The LDPE was compared to a commercial filler commonly used in structural plywood adhesives in the United States. The adhesive mixes were made by following the recommended procedure of Georgia-Pacific Resins Inc.. using plywood-type PF resin. A total of 48 three-ply plywoods. 6.3 mm nominal thickness and 30 by 30 em in size, were made at two press times (4 and 5 min). two press temperatures (150 and $160^{\circ}C$) and 30 minute assembly times for four adhesive mixing types. Evaluations of the LDPE addition were carried out by performance tension shear tests after two cycle boil aging tests on plywood per the U.S. Product Standard PS I-83. After accelerated-aging tests. plywoods were exhibited no delamination. The test results included tension shear strength and estimated wood failure values. The plywood test results support the use of polyethylene as an additive in plywood adhesives.

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충전제의 종류가 합판용 페놀수지 접착제에 미치는 효과 (Effect of Filler Types on Phenol-Formaldehyde Resin Adhesive for Plywood)

  • 오용성
    • Journal of the Korean Wood Science and Technology
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    • 제26권3호
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    • pp.48-52
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    • 1998
  • Residues such as walnut, pinenut and peanut shells were used as a filler in adhesive for bonding radiata pine plywood. The nutshell residues were prepared by simply drying to 8% moisture content and grinding the dry material using a laboratory Wiley mill with a $75{\mu}m$ (200 mesh) screen. The nutshells residues were compared to a commercial filler commonly used in adhesives by the structural plywood and laminated veneer lumber industry in the United States. The adhesive mixes were made by following the recommended procedure of Georgia-Pacific Resins, Inc., using phenol-formaldehyde resin. For each filler type, three-ply plywoods, 6 mm nominal thickness and 30 by 30 cm in size, were fabricated at two press times (4 and 5 min) and around 30 minute assembly time. Evaluations of the nutshell residues were carried out by tension shear tests after cyclic boil tests on plywood. The results of the performance test included tension shear strength and wood failure. All plywoods made with the nutshell fillers were comparable to those made with the control filler. These results indicate that nutshell residues would be suitable as filler for plywood adhesives.

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제진재가 삽입된 바닥 구조의 진동특성 (Vibration Characteristics of the Floor Structures inserted with Damping Materials)

  • 정영;유승엽;전진용;박준홍
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2005년도 추계학술대회논문집
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    • pp.377-380
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    • 2005
  • Damping materials encompass a broad range of materials, including, but not limits to, pressure sensitive adhesives, epoxies, rubbers, foams, thermoplastics, enamels and mastics. Their common characteristic is that their modulus is represented by a complex quantity, possessing both a stored and dissipative energy component. Loss factor of damping material analyzed more than 2 times than rubber to 1.5 $\sim$ 2.3, could know that Damping layer has excellent attenuation performance in side of vibration reduction. Measurements of vibration using accelerometers by adhesion of Damping layer, square Plate by Separation of Damping layer is less binding of Damping layer, analyzed low loss factor and Natural Frequency by free Vibration of Square Plate.

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Capability of Thermal Field-Flow Fractionation for Analysis of Processed Natural Rubber

  • 이성호;은철훈
    • Bulletin of the Korean Chemical Society
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    • 제21권1호
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    • pp.69-74
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    • 2000
  • Applicability of Thermal field flow fractionation (ThFFF) was investigated for the analysis of masticated natural rubber (NR) adhesives produced bya hot melt mastication process. An optimum ThFFF condition for NR analysis was found by using tetrahydrofuran (THF) as a solvent/carrier and a field-programming. Low flowrate (0.3 mL/min) was used to avoid stopping the flow for the sample relaxation. Measured molecular weight distribution was used to monitor degradation of rubber during the mastication process. Rubber samples collected at three different stages of the mastication process and were analyzed by ThFFF. It was found that in an anaerobic process rubber degradation occurs at the resin-mixing (compounding) zone as well as in the initial break-down zone, while in an aerobic process most of degradation occurs at the initial breakdown zone. It was also found that E-beam radiation on NR causes a slight increase in the NR molecular weight due to the formation of a branched structure.

옻과 옻에 아교를 배합한 천연접착제의 자외선에 의한 노화 특성 연구 (Study of UV Degradation of Lacquer and Natural Adhesives Using Lacquer Mixed with Animal Glue)

  • 안선아;김은경;장성윤
    • 보존과학회지
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    • 제32권4호
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    • pp.501-510
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    • 2016
  • 생칠(L), 정제칠(TL), 생칠과 아교를 배합한 천연접착제(LG), 우루시올과 아교를 배합한 천연접착제(UG)의 자외선에 의한 노화 특성을 비교 분석하기 위해 도막 시편에 자외선을 조사하고 광택도, 주사전자현미경분석, 적외선분광분석, 인장전단 접착강도 측정을 수행하였다. 천연접착제 LG, UG의 광택 저하 속도는 생칠보다 다소 느렸고 손실률도 생칠보다 낮았다. 또한 생칠 도막의 표면은 자외선 노출 시간에 따라 다당류 층이 드러나 구형이 손상되면서 크랙이 발생한 것으로 관찰되었고 천연접착제 LG와 UG는 매끄러운 표면이 계속 유지됨을 관찰하였다. FT-IR 분석 결과 생칠과 정제칠 도막에서 자외선 조사 시간이 증가할수록 전체적으로 피크 세기가 감소하였고 천연접착제 LG는 변화가 없는 것으로 나타났다. 천연접착제 UG에서는 일부 피크가 사라졌고 전체적으로 세기가 감소했다. 생칠의 인장전단 접착강도는 자외선 노출 600시간 이후로 강도 값이 크게 떨어지는 것에 비해 천연접착제 LG와 UG의 접착강도는 다소 감소하거나 유지되었다. 선행연구 결과와 비교하면 옻과 아교를 이용한 천연접착제는 생칠에 비해 고온 고습에서도 큰 변화를 나타내지 않았고 자외선 조건에서도 물성을 유지하므로 생칠에 비해 내구적인 것으로 나타났다.

어린이집의 친환경적 공간요소에 대한 학부모요구에 관한 기초연구 (A Basic Study on the Demand of the Parents of Students in Eco-Environmental Space at Child Care Center)

  • 한혜련;박영기
    • 한국실내디자인학회논문집
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    • 제16권5호
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    • pp.47-54
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    • 2007
  • The change of modern society arouse the issue of the family structure and the demand of upbringing. According to the issue, the need of the upbringing is the big interest in society. This study is on the demand of the parents of students in eco-environmental space in child care center. The purpose of the study makes the suggestion the need of the eco-environmental space in child care center. The study progressed with looking up and giving questionaires in six child care centers which have eco-environmental space in Seoul. 210 questionaires were given out to parents and taken away 180 questionaires. The result of the study, parents required strongly to have the eco-environmental space in child care center. The natural interior materials, nature experimental outdoor ground and exterior garden were preferred overriding. The use of the woods and stones and eco-environmental adhesives are required as the natural Interior materials. And the natural light source can be imported in sky light, side window and atrium. Upcoming study would be directed in child care center without eco-environmental spaces. The next suggestion would be made in the needs of the eco-environmental space in child care center.

Polysaccharides Obtained from Vegetables: an effective source of alternative excipient

  • Ananta Choudhury;Satyabrat Sarma;Snehashis Sarkar;Madhusmita Kumari;Biplab Kumar Dey
    • 대한약침학회지
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    • 제25권4호
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    • pp.317-325
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    • 2022
  • Polymers are the major constructive material of pharmaceutical formulations that play a prime role in designing effective drug-delivery systems and releasing drugs at their sites of application. Polymers are composed of multiple repeating units of high molecular mass components with attendant properties. Most synthetic polymers are non-biocompatible, expensive, and extremely inclined to deliver adverse impacts. Meanwhile, edible polymers obtained from natural sources have gained remarkable recognition for their promising use in modern medicine. Moreover, polymers derived from natural sources are generally preferred due to certain of their unique features such as abundant availability, biocompatibility, nontoxicity, economical, safe, and effective functions that fit the purpose. Polysaccharides including starch, cellulose, hemicellulose, pectin, and mucilage are identified as a major class of naturally obtained molecules that have a substantial role as functional polymers. This review summarizes the potential role of polysaccharides derived from vegetable sources such as adhesives, anticaking agents, binders, disintegrants, emulsifiers, film-framing agents, and thickeners. This is simply an opportunity to abandon synthetic excipients that hurt our bodies and think back to nature from where we originate.